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中国腐蚀与防护学报  2010, Vol. 30 Issue (5): 391-395    
  研究报告 本期目录 | 过刊浏览 |
显微组织对低碳钢耐蚀性的影响
米丰毅1,2,王向东2,汪兵2,陈小平2,彭云2
1. 昆明理工大学材料与冶金工程学院 昆明 650093
2. 钢铁研究总院结构材料研究所 北京 100081
INFLUENCE OF MICROSTRUCTURE ON THE CORROSION RESISTANCE FOR LOW CARBON STEEL
MI Fengyi1,2, WANG Xiangdong2, WANG Bing2,CHEN Xiaoping2, PENG Yun2
1. Institute of Material and Metallurgy Engineering, Kunming University of Science and Technology, Kunming 650093
2. Division of Structural Materials, Central Iron and Steel Research Institute,Beijing 100081
全文: PDF(1413 KB)  
摘要: 用不同热处理工艺得到铁素体+珠光体与马氏体两种不同组织的低碳钢,通过周浸试验和扫描电镜(SEM)、电化学和X射线衍射(XRD)等手段分析两者的耐蚀性能差异表明,在周浸试验条件下,组织均匀的马氏体钢的耐蚀性明显优于由铁素体和珠光体组成的复相钢;马氏体组织的自腐蚀电位较高,阳极腐蚀电流密度较小,形成的锈层更加致密,且主要由性质稳定的α-FeOOH构成。
关键词 低碳钢显微组织马氏体锈层    
Abstract:Two kinds of carbon steels of different microstructures(ferrite-pearlite and martensite) with the same chemical composition were obtained by different heat treatment processes. The difference in corrosion resistance of the steels with these two kinds of microstructures was investigated by cyclic immersion corrosion test as well as scanning electron microscopy (SEM) observation, electrochemical measurement, and X-ray diffraction (XRD) analysis. The results showed that the martensitic steel exhibited a higher corrosion resistance than the steel with the microstructure consisting of ferrite and pearlite. Martensitic steel had a higher self-corrosion potential and a lower anodic corrosion current. The rust layer of martensitic steel was more compact and mainly composed of α-FeOOH.
Key wordslow carbon steel    microstructure    martensite    rust layer
收稿日期: 2009-05-15     
ZTFLH: 

TG174

 
基金资助:

国家重点基础研究发展计划资助项目(2004cb619101)

通讯作者: 王向东     E-mail: wangxiangdong@nercast.com
Corresponding author: WANG Xiangdong     E-mail: wangxiangdong@nercast.com
作者简介: 米丰毅,男,1984生,博士生,研究方向为钢铁腐蚀

引用本文:

米丰毅,王向东,汪兵,陈小平,彭云. 显微组织对低碳钢耐蚀性的影响[J]. 中国腐蚀与防护学报, 2010, 30(5): 391-395.
MI Feng-Yi, WANG Bing, PENG Yun, CHEN Xiao-Beng, YU Xiang-Dong. INFLUENCE OF MICROSTRUCTURE ON THE CORROSION RESISTANCE FOR LOW CARBON STEEL. J Chin Soc Corr Pro, 2010, 30(5): 391-395.

链接本文:

https://www.jcscp.org/CN/      或      https://www.jcscp.org/CN/Y2010/V30/I5/391

[1] Li C Y, Wang X D, Jiang S M,et al. Study of the effect of rare earths on corrosion resistance of mild steels [J]. Rare Earth, 2005,12(6): 23-28     (李春艳, 王向东, 江社明等.稀土对低碳钢耐大气腐蚀性能影响的研究 [J]. 稀土, 2005, 12(6): 23-28) [2] Wang B, Liu Q Y, Jia S J, et al. Effect of grain size on the atmospheric corrosion resistance of carbon steel in industrial environment [J]. J. Chin. Soc. Corros. Prot., 2007, 27(4): 193-196     (汪兵, 刘清友, 贾书君等. 晶粒尺寸对普碳钢耐工业环境下大气腐蚀性能的影响 [J]. 中国腐蚀与防护学报, 2007, 27(4): 193-196) [3] Guo J, Yang S W, Shang C J, et al.Influence of carbon content and microstructure on corrosion behaviour of low alloy steels in a Cl$^-$ containing environment [J].Corros. Sci., 2008, 51(2): 242-251 [4] Sarkar P P, Kumar P, Manna M K, et al. Microstructural influence on the electrochemical corrosion behavior of dual-phase steel in 3.5 % NaCl solution [J]. Mater. Lett., 2005, 59(19-20): 2488-2491 [5] Dong J, Cui W F, Zhang S X, et al. Effects of different microstructures of CuPCr alloy steel on its marine immersion corrosion behavior [J]. J. Northeastern Univ. (Nat. Sci.), 2007, 12(9):1294-1296     (董杰, 崔文芳, 张思勋等. CuPCr钢显微组织对全浸海水腐蚀行为的影响 [J]. 东北大学学报(自然科学版), 2007, 12(9):1294-1296) [6] Fu G Y, Liu Q, Men B J, et al. Effect of microstructure on hot corrosion of Ni-Cr alloys [J]. Rare Met. Mater. Eng., 2007, 36(4): 695-699     (付广艳,刘群,门冰洁等. 显微组织对Ni-Cr合金热腐蚀行为的影响 [J]. 稀有金属材料与工程, 2007, 36(4): 695-699) [7] Yang X Z,Yang W. Thermodynamics of Metal Corrosion Electrochemistry-Electric Potential-pH Chart and Its Application [M]. Beijing: Chemical Industry Press, 1991     (杨熙珍, 杨武. 金属腐蚀电化学热力学--电位-pH图及其应用 [M].北京:化学工业出社,1991) [8] Yamashita M, Miyuki H, Matsuda Y, et al. The long term growth of the protective rust layer formed on weathering steel by atmospheric corrosion during a quarter of a century [J]. Corros. Sci., 1994,. 36(2): 283-299 [9] Mizoguchi T, Ishii Y, Okada T, et al. Magnetic property based characterization of rust on weathering steels [J]. Corros. Sci., 2005,47(10): 2477-2497 [10] Stratmann M, Bohnenkamp K, Engell H J. An electrochemical study of phase-transitions in rust layers [J].Corros. Sci., 1983, 23(9): 969-985 [11] Hoerl S, Mazaudier F, Dillmann P, et al. Advances in understanding atmospheric corrosion of iron. (II). Mechanistic modelling of wet-dry cycles [J]. Corros.Sci., 2004, 46(6): 1431-1465
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