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中国腐蚀与防护学报  2023, Vol. 43 Issue (5): 929-947     CSTR: 32134.14.1005.4537.2022.275      DOI: 10.11902/1005.4537.2022.275
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铝植物缓蚀剂的研究进展与展望
李树丽1, 邓书端2, 李向红1()
1.西南林业大学化学工程学院 西南地区林业生物质资源高效利用国家林业和草原局重点实验室 昆明 650224
2.西南林业大学材料科学与工程学院 昆明 650224
Research Progress and Prospects of Plant Corrosion Inhibitors for Aluminum
LI Shuli1, DENG Shuduan2, LI Xianghong1()
1.Key Laboratory of State Forestry and Grassland Administration on Highly-Efficient Utilization of Forestry Biomass Resources in Southwest China, College of Chemical Engineering, Southwest Forestry University, Kunming 650224, China
2.Faculty of Materials Science and Engineering, Southwest Forestry University, Kunming 650224, China
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摘要: 

对植物缓蚀剂的研究方法、缓蚀机理和提取方法做了总结,综述了2008年至今酸性、碱性及其它介质中植物缓蚀剂对Al缓蚀作用的研究现状,并对未来植物缓蚀剂的研究方向和重点科学问题进行了展望。

关键词 植物缓蚀剂Al吸附研究进展展望    
Abstract

Aluminum is one of the most widely used non-ferrous metallic materials, while it is an active amphoteric metal and can be easily corroded. Adding corrosion inhibitors in corrosive media is an important strategy to prevent or slow down the corrosion of aluminum, which has been widely used in the chemical industry. With the improvement of environmental awareness and the implementation of sustainable development strategy, it is urgent to develop cheap, efficient and environmentally friendly corrosion inhibitors. Plant corrosion inhibitors are one of the hotspots in the field of corrosion inhibitor research due to their outstanding advantages such as abundant resources, biodegradability and environmental friendliness. This article summarizes the research status about the research methods, corrosion inhibition mechanisms, and extraction methods of plant corrosion inhibitors on Al in acidic, alkaline, and other media since 2008, and moreover, the future research directions and key scientific issues of plant corrosion inhibitors are also prospected.

Key wordsplant inhibitor    aluminum    adsorption    research progress    prospect
收稿日期: 2022-09-07      32134.14.1005.4537.2022.275
ZTFLH:  TG174.42  
基金资助:国家自然科学基金(52161016);国家自然科学基金(51761036);云南省基础研究计划杰出青年基金(202001AV070008);云南省农业基础研究联合专项重点项目(202101BD070001-017);云南省万人计划青年拔尖人才专项(51900109)
通讯作者: 李向红,E-mail: xianghong-li@163.com,研究方向为缓蚀剂   
Corresponding author: LI Xianghong, E-mail: xianghong-li@163.com   
作者简介: 李树丽,女,1995年生,博士生

引用本文:

李树丽, 邓书端, 李向红. 铝植物缓蚀剂的研究进展与展望[J]. 中国腐蚀与防护学报, 2023, 43(5): 929-947.
LI Shuli, DENG Shuduan, LI Xianghong. Research Progress and Prospects of Plant Corrosion Inhibitors for Aluminum. Journal of Chinese Society for Corrosion and protection, 2023, 43(5): 929-947.

链接本文:

https://www.jcscp.org/CN/10.11902/1005.4537.2022.275      或      https://www.jcscp.org/CN/Y2023/V43/I5/929

PlantExtraction solventCorrosive mediumImmersion time (t) & temperature (T)Extract Conc. & highest efficiency (IE)Functional groups or compoundsRef.
t / hT / KConc.IE
Raphia hookeri gumEthanol0.1 mol/L HCl0.5303500 mg/L85.5%-[71]
Ananas sativum leavesEthanol0.1 mol/L HCl24333500 mg/L96.1%-[35]
Cocos nucifera L. water-0.5 mol/L HCl-3037.5% (v/v)93.0%

-OR, -COOH,

-NR2, -SR

[72]
Chlomolaena odorata L. leaves

Hydrochloric

acid

2.0 mol/L HCl-30350% (v/v)92.2%-[49]
Bambusa subaeuqualis leavesEthanol1.0 mol/L HCl630380 mg/L55.0%Flavonoids, carbohydrate, amino acids, aromatic components, etc[64]
Phyllostachys nigra munro leavesEthanol0.1 mol/L HCl63131000 mg/L95.0%Flavonoids, carbohydrate, amino acids, aromatic components, etc[65]
Citrullus ColocynthisMethanolH2SO4 and HCl-313---[73]
Newbouldia laevis leavesSulfuric acid0.5 mol/L H2SO48303400 mg/L92.0%-[53]
Neosinocalamus affinis leavesEthanol1.0 mol/L HCl1.53031000 mg/L84.2%Flavonoids[66]
Chromolaena odorata

Hydrochloric

acid

2.0 mol/L HCl4/15-0.16 mol/L--[48]
African star appleEthanol1.5 mol/L H2SO424303500 mg/L40.5%-[74]
Jasminum nudiflorum Lindl. leavesEthanol1.0 mol/L HCl22931000 mg/L97.9%Oxygen glycosides[62]
Dendrocalamus brandisii leavesEthanol1.0 mol/L HCl22931000 mg/L91.3%Flavonoids[58]
Spondias mombin L.Sulfuric acid0.5 mol/L H2SO4243035% v/v+ 5 mmol/L KI95.1%Ascorbic acid riboflavin, thiamine, nicotinic acid[75]
Treculia africanaEthanol1.0 mol/L HCl2303500 mg/L74.2%

Phenols, terpenes,

flavonoid, tannins

[46]
Coconut coirAcetone1.0 mol/L HCl2333500 mg/L80.0%Alkaloids, flavonoids, organic acids, etc[76]
Phyllostachy sulphurea leavesEthanol2.0 mol/L H2SO448303

1000 mg/L

+Ce4+

64.4%-[67]
Yushania polytrichaEthanol1.0 mol/L HCl22931000 mg/L88.7%-[68]
Garcinia indicaWater0.5 mol/L H3PO4-323500 mg/L85.6%Garcinol, isogarcinol, curcumin[59]
Coriandrum sativum L. seedsWater1.0 mol/L H3PO4-303500 mg/L72.8%Linalool[60]
JSME

Hydrochloric

acid

1.0 mol/L HCl230310% (v/v) +1% Urotropine98.1%-[77]
Phyllostachy sulphurea leavesEthanol1.0 mol/L HCl6293750 mg/L77.7%Flavonoids, active carbohydrate amino acids, aromatic components, etc[78]
Morinda tinctoriaWater0.5 mol/L HCl23037% (v/v) + 1% KCl96.7%-[79]
Phyllostachy sulphurea leavesEthanol1.0 mol/L HCl22931000 mg/L90.8%Flavonoids[69]
GarlicAcetone0.5 mol/L HCl230325 mg/L55.7 %Sulfur compounds[80]
Neosinocalamus affinies leavesEthanol0.1 mol/L HNO36298900 mg/L74.3%-[70]
Lupine seedsWater0.1 mol/L HClO4-3038 mg/L76.6%-[81]
Lupine seedsWater0.1 mol/L HCl-30380 mg/L71.9%-[82]
Dendrocalmus latifcorus munro leavesEthanol1.0 mol/L HNO362981000 mg/L78.6%Flavonoids, carbohydrate, amino acids, aromatic components, etc[57]
Thymus algeriensis

Hydrochloric

acid

1.0 mol/L HCl2298750 mg/L+ +3 mmol/L KI93.1%-[83]
Black pepperMethanol1.0 mol/L HCl1308243 mg/L99.7%Piperine, terpenoid, lipid compounds[84]
Psidium guajavaEthanol0.5 mol/L HCl243031206 mg/L85.7%-[85]
Scutellaria baicalensis georgi-1.0 mol/L HCl3298900 mg/L95.3%Baicalin derivatives[9]
Trigonellafoenum-graecum L.Dichloromethane1.0 mol/L HCl-2981400 mg/L86.6%O-H, C=O, C-O and O-heterocyclic ring[86]
Dryopteris cochleate leafMethanol1.0 mol/L H2SO462982400 mg/L95.1%Alkaloids, phenolics, flavonoids, proteins, carbohydrates, terpenoids[40]
TecomaDichloromethane1.0 mol/L H2SO43298300 mg/L90.0%-[25]
Murraya koenigiiWater2.0 mol/L HCl-303400 mg/L91.8%

β-elemene, mahanimbine,

terpene-4-ol

[50]
Illicium verumMethanol1.0 mol/L HCl13081140 mg/L95.6%E-anethole[87]
Asparagus racemosus-1.0 mol/L HCl12986000 mg/L74.4%.Steroidal saponin-shatavarin, sarsasapogenin[43]
Acacia tortilisWater1.0 mol/L HCl723038% (v/v)89.6%-[44]
Arecanut husk

Hydrochloric

acid

0.5 mol/L HCl130318000 mg/L81.7%-[88]
Polygonatum odaratumMethanol1.0 mol/L HCl3303500 mg/L92.2%Phenolic, flavonoids[26]
Phyllanthus amarusEthanol1.0 mol/L HCl24303500 mg/L69.2%Phyllanthusin D[27]
Papaya peel

Hydrochloric

acid

1.0 mol/L HCl33032000 mg/L98.1%Papain[89]
SapindusWater1.0 mol/L HCl12932000 mg/L98.0%Sapindus[90]
Cordia dichotoma seedsEthanol0.5 mol/L HCl723031050 mg/L90.1%-[91]
Arecanut husk

Hydrochloric

acid

0.5 mol/L HCl130318000 mg/L94.4%-[92]
Acacia senegalWater0.5 mol/L H2SO4483038% (v/v)92.6%

Alkaloid, tannins, saponins, flavonoids,

glycosides

[55]
Borassus flabelliferMethanol1.0 mol/L H2SO43303400 mg/L66.8%

O-H, N-H, C=O, C-O, C=C and epoxy

group and aromatic ring

[93]
Bassia muricataEthanol1.0 mol/L H2SO424298300 mg/L90.0%Heteroatom compound[52]
Glycine maxWater1.0 mol/L HCl3298300 mg/L81.3%Flavonoids[94]
Walnut green huskEthanol1.0 mol/L HNO3242931000 mg/L85.7%Flavonoids, naphthoquinones[95]
Hemerocallis fulvaMethanol1.0 mol/L H2SO43303600 mg/L89.0%

Phenolic,

flavonoid

[54]
Juglans regiaMethanol2.0 mol/L HCl0.5298300 mg/L98.7%Phenolic, terpenoids[51]
Terminalia glaucescens planchEthanol0.3 mol/L H2SO4-298400 mg/L98.6%Terpenoids[56]
Ricinus communis-HCl53031000 mg/L82.6%Alkaloids, cardiac glycosides, flavonoids, phenolics, phytates, saponins, tanins[96]
Ziziphus spina-christiEthanol1.0 mol/L HCl2303140 mg/L76.9%N-H, C-O[63]
Conocarpus erectusDichloromethane1.0 mol/L HCl2298300 mg/L91.1%

Tannins, flavonoids,

coumarins, triterpenes

[45]
Theobroma cocoa podWater0.5 mol/L HCl530332% (v/v)81.2%1, 2-bis (trimethylsilyl) benzene[97]
Sargassum latifolium-0.5 mol/L HCl-298300 mg/L--[42]
Orange peelEthanol1.0 mol/L HCl2293300 mg/L98.0%Flavonoids[98]
T.conophorumWater1.5 mol/L HCl4.530340 mg/L78.6%-[47]
Punica granatumWater1.0 mol/L HCl12984000 mg/L77.6%-[99]
BuckwheatEthanol1.0 mol/L HCl2303500 mg/L86.7%-[100]
Flos sophorae immaturusEthanol1.0 mol/L HCl2293500 mg/L83.2%Flavonoids[101]
Carica papayaEthanol2.0 mol/L HCl24303

500 mg/L+

0.6 mol/L KBr

87.4%Protein, terpenoids[102]
表1  最佳条件下植物提取物对Al的缓蚀效率 (酸性介质)
PlantExtraction solventCorrosive medium

Immersion

time (t) &

temperature (T)

Extract Conc. & highest efficiency (IE)Functional groups or compoundsRef.
t / hT / KConc.IE
Ambrosia maritima L.Water2.0 mol/L NaOH-298990 mg/L88.3%-[111]
Gossipium hirsutum L.Sodium hydroxide2.0 mol/L NaOH230352% (v/v)97.0%Aldehyde-type[120]
Phyllanthus amarusSodium hydroxide2.0 mol/L NaOH630320% (v/v)76.0%Lignans[119]
Hibiscus sabdariffa leavesWater0.5 mol/L NaOH1.53031500 mg/L84.7%Thiamine, niacin, ascorbic acid, anthocyanins[106]
Lupinus varius L.Sodium hydroxide1.0 mol/L NaOH1298100% (v/v)93.7%-[108]
Lippia citriodora-0.1 mol/L Na2CO312981800 mg/L90.3%Limonene, neral, geranial[125]
Pisum sativumSodium hydroxide1.0 mol/L NaOH33031500 mg/L94.5%Cellulose[117]
KalmeghSodium hydroxide1.0 mol/L NaOH1/43031000 mg/L82.5%Bicyclic diterpenoid lactone[109]
Moringa oleifera Lam.Sodium hydroxide1.0 mol/L NaOH1/4303600 g/L85.3%4-(alpha-l-rhamnopyranosyloxy)-benzylglucosinolate[115]
Piper longumWater1.0 mol/L NaOH1308243 mg/L99.6%Alkaloids[122]
Rauwolfia serpentinaSodium hydroxide1.0 mol/L NaOH3303200 mg/L97.0%Indole alkaloids[118]
Apium graveolens L.Water0.25 mol/L NaOH7/63031500 mg/L93.3%Limonene[124]
Wheat strawSodium hydroxide1.0 mol/L NaOH3-300 mg/L81.1%Lignin[110]
Sapota leafWater3.0 mol/L NaOH53332000 mg/L95.0%-[112]
Mentha pulegium-0.1 mol/L Na2CO3-298800 mg/L94.2%Pulegone[126]
Medicagosativa L.Ethanol1.0 mol/L NaOH13085.0% (v/v)92.4%-[41]
Collard greens-4.0 mol/L NaOH1-2000 mg/l89.6%Hydroxycinnamoyls, flavonols, kaempferol[113]
Chrysanthemum coronariumWater4.0 mol/L NaOH1-4500 mg/L95.1%C-C/C=C/CH/CH2/CH3, C-OH/C-O-C, C=O[121]
Morinda tinctoriaWater0.5 mol/L NaOH243332.5% (v/v)68.9%-[107]
表2  最佳条件下植物提取物对Al的缓蚀效率 (碱性)
PlantExtraction solventCorrosive medium

Immersion

time (t) &

temperature (T)

Extract Conc. & highest efficiency (IE)Functional groups or compoundsRef.
t / hT / KConc.IE
Phoenix dactylifera L.Water3.5% NaCl2-2000 mg/L72.0%Carbohydrate[138]
Laurus nobilis L.-3% NaCl2429850 mg/L90.2%1,8-cineole[130]
Coptis chinensisEthanol3.5% NaCl-2981000 mg/L96.0%Berberine[139]
Psidium guajava-3.5% NaCl23030.5% (v/v)90.5%-[132]
Psidium guajava-3.5% NaCl23030.5% (v/v)98.9%-[133]
RosemaryEthanolBiodiesel2000298500 mg/L95.7%Phenolic diterpenes[141]
Lawsonia inermisEthanolSeawater-302.6600 mg/L93.0%Lawsone[134]
WalnutWaterHeat transfer fluid336361140 mg/L74.3%-[142]
Linum usitatissimumEthanol3.5% NaCl24-1200 mg/L82.0%-[136]
Casto-3.5% NaCl48304500 mg/L85.2%-[143]
TurmericMethanolSeawater192-1%88.9%Flavonoids, tannins[135]
Pumpkin seeds-3.5% NaCl20 h2981000 mg/L95.0%(Z,Z)-9,12-octad- ecadienoic acid, palmitic acid, linoleic acid[140]
Ocimum basilicumWater3.0% NaCl62981000 mg/L95.0%-[129]
Garlic-3.5% NaCl--8 mL/L96.8%Pyridoxal phosphate[128]
Acanthocereus tetragonusWater0.6 mol/L NaCl24-100 mg/L80.9%-[131]
Aerva lanataWater3.5% NaCl120-600 mg/L88.0%Aromatic ring, heteroatoms, oxygen[137]
表3  最佳条件下植物提取物对铝的缓蚀效率 (其他介质)
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