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中国腐蚀与防护学报  2007, Vol. 27 Issue (3): 186-192     
  综述 本期目录 | 过刊浏览 |
N80油套管钢CO2腐蚀的研究进展
何庆龙;孟惠民;王旭东;俞宏英;樊自拴;孙冬柏
北京科技大学
Recent Developments in Carbon Dioxide Corrosion of N80 Well Tube Steel
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北京科技大学
全文: PDF(550 KB)  
摘要: 综述了N80油套管钢CO2腐蚀的研究进展,提供了N80油套管钢腐蚀发生的最关键影响因素,提出了进一步研究的方向。目前,N80油套管钢CO2腐蚀研究发现,腐蚀速率随环境参数:温度、CO2分压、流速的增加出现峰值;腐蚀产物膜的结构影响腐蚀的进程和腐蚀形式,只有连续、致密、结合力强的膜才能抑制腐蚀加剧,保护基体;原油、H2S的加入改变反应的传输过程和界面状态,使反应机理更加复杂;各种预测系统不断丰富。而特别指出在CO2腐蚀产物膜的结构、力学性能、表征参量方面,腐蚀参量的影响研究缺乏系统性。提出一些设想,今后应着重于各腐蚀参量对腐蚀速率影响敏感区间的细化和对膜力学性能影响的研究,由此需要进一步改进动态模拟试验方法以及深入探讨动态电化学原位测量技术。
关键词 N80油套管钢CO2腐蚀产物膜影响因素进展    
Abstract:Recent developments in carbon dioxide corrosion of N80 well tube steel,the pivotal effect factors while corrosion happening and directions in forward research are reported in the article. At present, some important results are found,such as there will be a peak value of corrosion velocity during temperature,CO2 partial pressure,velocity of flow increasing;the structure of corrosion production scale effects on the process and formation of corrosion and only continuous,compact and high cohesion scale can restrain corrosion aggravating;reaction mechanism becomes more complicated when oil or H2S is added to the medium resulting in transmission process and interface state changing.Specially, it should be studied systematically that effects of the varieties of corrosion parameters on the structure and mechanical properties of corrosion scale.Henceforth,the keystones are detailing the sensitivity region that corrosion parameters effect on corrosion velocity,improving the method of dynamic simulate test,probing into the dynamic electrochemistry in-situ measurement technique.
Key wordsN80 well tube steel    carbon dioxide corrosion    production scale    effect factor    progress
收稿日期: 2005-12-01     
ZTFLH:  TG172  
通讯作者: 何庆龙     E-mail: heqinglong@yeah.net

引用本文:

何庆龙; 孟惠民; 王旭东; 俞宏英; 樊自拴; 孙冬柏 . N80油套管钢CO2腐蚀的研究进展[J]. 中国腐蚀与防护学报, 2007, 27(3): 186-192 .
. Recent Developments in Carbon Dioxide Corrosion of N80 Well Tube Steel. J Chin Soc Corr Pro, 2007, 27(3): 186-192 .

链接本文:

https://www.jcscp.org/CN/      或      https://www.jcscp.org/CN/Y2007/V27/I3/186

[1]Warrd C D E,Milliams D E.Carbonic acid corrosion of steel[J].Corrosion,1975,31(5):177-181
[2]Ogundele G I,White W E.Some observations on corrosion of carbonsteel in aqueous environments containing carbon dioxide[J].Corro-sion,1986,42(2):71-78
[3]Ogundele G I,White W E.Observations on the influences of dis-solved hydrocarbon gases and variable water chemistries on corrosionof an API-L80 steel[J].Corrosion,1987,43(11):665-673
[4]Kermani M B,Morshed A.Carbon dioxide corrosion in oil and gasproduction-a compendium[J].Corrosion,2003,59(8):659-683
[5]Chen C F,Zhao G X,Lu MX,et al.Study of CO2corrosion scales onN80 steel[J].J.Chin.Soc.Corros.Prot.,2002,22(3):143-146(陈长风,赵国仙,路民旭等.N80钢CO2腐蚀产物膜研究[J].中国腐蚀与防护学报,2002,22(3):143-146)
[6]Zhao G X,Yan M L,Bai Z Q,et al.Experimentation study of CO2corrosion behavior on N80 steel[J].China Petroleum Machinery,2000,28(12):14-16(赵国仙,严密林,白真权等.N80钢CO2腐蚀行为试验研究[J].石油机械,2000,28(12):14-16)
[7]Yu F,Gao K W,Qiao L J,et al.Effect of temperature on structureand mechanical properties of CO2corrosion product films on pipelinesteel X65[J].J.Mechanical Strength,2004,26(s):36-38(俞芳,高克玮,乔立杰等.温度对X65管线钢CO2腐蚀产物膜结构和力学性能的影响[J].机械强度,2004.26(s):36-38)
[8]Zhang Q,Li Q A,Wen J B,et al.Effect of CO2partial pressure oncorrosion scales of tubular steels[J].China Petroleum Machinery,2004,32(4):13-17(张清,李全安,文九巴等.CO2分压对油管钢腐蚀产物膜的影响[J].石油机械,2004,32(4):13-17)
[9]Lin G F,Zhao G X,Bai Z Q,et al.Effect of CO2partial pressure onthe morphology of corrosion metallic product scale[J].J.Chin.Soc.Corros.Prot.,2004,24(5):284-288(林冠发,赵国仙,白真权等.CO2分压对金属腐蚀产物膜形貌结果的影响[J].中国腐蚀与防护学报,2004,24(5):284-288)
[10]Guan D,Wang Q,Lu MX.Progress of research and application onCO2corrosion under multiphase media at high temperature and highpressure condition[J].Total Corrosion Control,2005,19(5):7-10(关东,王强,路民旭.高温高压CO2多相介质腐蚀研究及应用的新进展[J].全面腐蚀控制,2005,19(5):7-10)
[11]Li G F,Bai Z Q,et al.Wear behavior of CO2corrosion scales onwell tube steel N80 in water-sand two-phase fluid medium[J].Tribology,2005,25(1):78-82(林冠发,白真权等.N80钢CO2腐蚀产物膜在水砂两相流介质中的磨损性能[J].摩擦学学报,2005,25(1):78-82)
[12]Shu X X,Li J B,Zheng MS,et al.Static and dynamic analogy stud-y of corrosion action of N80 steel in the extraction liquid of oil field[J].Welded Pipe and Tube,2005,28(4):16-24(舒欣欣,李金波,郑茂盛等.N80钢在油田采出液中腐蚀行为的静态和动态模拟研究[J].焊管,2005,28(4):16-24)
[13]Yu F,Gao KW,et al.The fracture toughness of CO2corrosion scalein pipeline steel[J].Mater.Letters,2005,(59):1709-1713
[14]Zhao G X,Chen C F,Lu MX,et al.The formation of product scaleand mass transfer channels during CO2corrosion[J].J.Chin.Soc.Corros.Prot.,2002,22(6):363-366(赵国仙,陈长风,路民旭等.CO2腐蚀产物膜及膜中物质交换通道的形成[J].中国腐蚀与防护学报,2002,22(6):363-366)
[15]Lv X H,Zhao G X,Lu M X.A comparison study on dynamic andstatic corrosion of N80 steel induced by CO2[J].Corros.Sci.Prot.Technol.,2003,15(1):5-8(吕祥鸿,赵国仙,路民旭.N80钢动态和静态CO2腐蚀行为对比研究[J].腐蚀科学与防护技术,2003,15(1):5-8)
[16]Chen C F,Zhao G X,Lu MX.Behavior of CO2pitting corrosion ofN80 steel[J].J.Chin.Soc.Corros.Prot.,2003,23(1):21-25(陈长风,赵国仙,路民旭.N80油管钢CO2腐蚀点蚀行为[J].中国腐蚀与防护学报,2003,23(1):21-25)
[17]Wu S L,Cui Z D,He F,et al.Characterization of the surface filmformed from carbon dioxide corrosion on N80 steel[J].Mater.Let-ters,2004,(58):1076-1081
[18]Li J P,Zhao G X,Wang Y,et al.Static corrosion of oil thimble usedin Tarim oil field[J].J.Chin.Soc.Corros.Prot.,2004,24(4):230-233(李建平,赵国仙,王玉等.塔里木油田用油套管钢的静态腐蚀试验[J].中国腐蚀与防护学报,2004,24(4):230-233)
[19]Li Q A,Zhang Q,Wen J B,et al.Effect of temperature on CO2cor-rosion scales of tubular steels[J].Transactions of Materials andHeat-treatment,2004,25(1):79-83(李全安,张清,文九巴等.温度对油管钢CO2腐蚀产物膜的影响[J].材料热处理学报,2004,25(1):79-83)
[20]Li J,Sun D B,Yang D J,et al.Study on corrosion behavior of oilwell in HT/HP CO2corrosion environment[J].Iron and Steel,2001,36(6):48-52(李静,孙冬柏,杨德钧等.油管钢高温高压CO2腐蚀行为研究[J].钢铁,2001,36(6):48-52)
[21]Hou J G,An W J,Chang W,et al.Simulating study of the influenceof crude oil on CO2corrosion[J].China Offshore Oil and Gas,2005,17(1):60-64(侯建国,安维杰,常炜等.原油对CO2腐蚀影响的模拟研究[J].中国海上油气,2005,17(1):60-64)
[22]Long F L,Zheng W J,Chen C F,et al.Influence of temperature,CO2partial pressure,flow rate and pH value on uniform corrosionrate of X65 pipeline steel[J].Corros.Prot.,2005,26(7):290-294(龙凤乐,郑文军,陈长风等.温度、CO2分压、流速、pH值对X65管线钢CO2均匀腐蚀速率的影响规律[J].腐蚀与防护,2005,26(7):290-294)
[23]Crolet J L.“Which CO2corrosion,hence which prediction?”inpredicting CO2corrosion in the oil and gas industry[A].EuropeanFederation of Corrosion Publication No.13[C].London.U.K:In-stitute of Materials,1994:1
[24]Li J P,Zhao G X,Hao S M.Dynamic corrosion behavior of N80,P105 and SM110 steel[J].J.Chin.Soc.Corros.Prot.,2005,25(4):241-244(李建平,赵国仙,郝士明.几种因素对油套管钢CO2腐蚀行为影响[J].中国腐蚀与防护学报,2005,25(4):241-244)
[25]Li J P,Zhao G X,Hao S M,et al.Local corrosion rate of conven-tional tubing steels[J].J.Northeastern University(Natural Sci-ence),2004,25(11):1069-1071(李建平,赵国仙,郝士明等.常用油管钢的CO2局部腐蚀速率[J].东北大学学报(自然科学版),2004,25(11):1069-1071)
[26]Nesic S,Carroll F.Horizontal rotation cylinder-a compact appara-tus for studying the effect of water wetting on carbon dioxide corro-sion of mild steel[J].Corrosion,2003,59(12):1085-1095
[27]Cui Z D,Wu S L,et al.Corrosion behavior of oil tube steels underconditions of multiphase flowsaturated with supercritical carbon di-oxide[J].Mater.Letters,2004,(58):1035-1040
[28]Wu S L,Cui Z D,Li C F,et al.Study on corrosion of tubes in car-bon dioxide saturated crude oil/water mixtures[J].J.Chin.Soc.Corros.Prot.,2003,23(6):340-344(吴水林,崔振铎,李春福等.油管钢在饱和二氧化碳模拟油田液中的腐蚀研究[J].中国腐蚀与防护学报,2003,23(6):340-344)
[29]Ji E Y,Li A K,Zhang Y H,el at.Effect of crude oils on corrosionbehavior of N80 steel[J].Mater.Prot.,2004,37(5):42-45(姬鄂豫,李爱魁,张银华等.原油对碳钢腐蚀行为影响的研究[J].材料保护,2004,37(5):42-45)
[30]Ward E D,William.Corrosion of iron in an H2S-CO2-H2-Osystem[J].Corrosion,1962,18:119-124
[31]Mishra B.Physical characteristics of iron carbonate scale formationin line pipe steels[A].Corrosion/92[C].Houston.TX:NACE,1992,13
[32]Li HL,Bai Z Q,Li P L,et al.Study on corrosion factors of APIN80steel in simulated CO2/H2S environment[A].Second Conferenceof Materials Research in Petroleum and Petrifaction Industry[C].Chengdu:2001,101-104(李鹤林,白真权,李鹏亮等.模拟CO2/H2S环境中API N80钢的腐蚀影响因素研究[A].第二届石油石化工业用材研究会论文集[C].成都:2001,101-104)
[33]Zhang Q,Li Q A,Wen J B,et al.Effect of CO2partial pressure onCO2/H2S corrosion of oil tube steel[J].J.Iron and Steel Re-search,2004,16(4):72-74(张清,李全安,文九巴等.CO2分压对油管钢CO2/H2S腐蚀的影响[J].钢铁研究学报,2004,16(4):72-74)
[34]Zhang Q,Li Q A,Wen J B,et al.Effect of H2S partial pressure onCO2/H2S corrosion of oil tube steels[J].Corros.Sci.Prot.Techn-ol.,2004,16(6):395-397(张清,李全安,文九巴等.H2S分压对油管钢CO2/H2S腐蚀的影响[J].腐蚀科学与防护技术,2004,16(6):395-397)
[35]Li R,He X Y,Liao F,et al.Effect exerted by H2S on the corrosionbehavior of N80#oil pipe steel[J].J.Sichuan Teachers College(Natural Science),2001,22(1):53-57(李容,何晓英,廖钫等.H2S对N80号油管钢CO2/H2S腐蚀的影响[J].四川大学学报(自然科学版),2001,22(1):53-57)
[36]He X Y,Li R,Liao F.Corrosion behavior of N80#oil pipe steel inacid solution with H2S[J].Corros.Sci.Prot.Technol.,2001,13(4):239-243(何晓英,李容,廖钫.N80油管钢在含H2S酸性溶液中的腐蚀行为[J].腐蚀科学与防护技术,2001,13(4):239-243)
[37]Bai Z Q,Ren C Q,Liu D X.Analyzing electrochemical behaviors ofN80 steel under the conditions of high temperature and high pres-sure containing CO2/H2S[J].China Petroleum Machinery,2004,32(12):14-18(白真权,任呈强,刘道新.N80钢在CO2/H2S高温高压环境中的腐蚀行为[J].石油机械,2004,32(12):14-18)
[38]Bai Z Q,Li H L,Liu D X,et al.Corrosion factors of N80 steel insimulated H2S/CO2environment[J].Mater.Prot.,2003,36(4):32(白真权,李鹤林,刘道新等.模拟油田CO2/H2S环境中N80钢的腐蚀及影响因素研究[J].材料保护,2003,36(4):32)
[39]Fan Z H,Lv X H,Zhao G X,et al.Electrochemical characteracticsof CO2induced corrosion of N80 steel[J].Corros.Sci.Prot.Techn-ol.,2005,17(2):75-78(樊治海,吕祥鸿,赵国仙等.常压条件下N80钢的CO2腐蚀的电化学特性[J].腐蚀科学与防护技术,2005,17(2):75-78)
[40]Li M,Wen S Z.Nanoindentation and its application[J].ChinaMechanism Engineer,2002,13(16):1437-1440(黎明,温诗铸.压痕技术及其应用[J].中国机械工程,2002,13(16):1437-1440)
[41]Xie C Y.Application of nanoindentation technology in material sci-ence[J].Physics,2001,30(7):282-285(谢存毅.纳米压痕技术在材料科学中的应用[J].物理,2001,30(7):282-285)
[42]Oliver W C,Pharr W C.An improved technique for determininghardness and elastic modulus using load and displacement sensingindentation experiments[J].J.Mater.Research,1992,7(6):1564-1583
[43]YUF.Structure and mechanical properties of CO2corrosion productscale[D].Beijing:University of Science and Technology Beijing,2005,2(俞芳.CO2腐蚀产物膜的结构及力学性能研究[D].北京:北京科技大学,2005,2)
[44]Chen C F,Lu MX,Zhao G X,et al.Mechanical properties of CO2corrosion scale on N80 well tube steel[J].Acta Metall.Sin.,2003,39(2):175-181(陈长风,路民旭,赵国仙等.N80油套管钢CO2腐蚀产物膜力学性能的研究[J].金属学报,2003,39(2):175-181)
[45]Ren C Q,Liu D X,Bai Z Q,et al.Study on mechanical properties ofcorrosion scale on surface of tubular steel N80[J].Mater.Eng.,2004,(8):17-21(任呈强,刘道新,白真权等.N80油套管钢腐蚀产物膜的力学性能[J].材料工程,2004(8):17-21)
[46]Li C F,Wang B,Dai J L,et al.Study of carbon dioxide corrosionmechanism in high pressure and high temperature[J].J.SouthwestPetroleum Institute,2005,27(1):75-80(李春福,王斌,代家林等.超高压高温CO2腐蚀研究理论探讨[J].西安石油学院学报,2005,27(1):75-80)
[47]Lin G F,Bai Z Q,Zhao X W,et al.Effect of temperature and pres-sure on profile of CO2corrosion scales on oil well steels[J].ChinaPetroleum Machinery,2005,33(2):1-4(林冠发,白真权,赵新伟等.CO2腐蚀产物膜形态结构与温度和压力的关系[J].石油机械,2005,33(2):1-5)
[48]Yang X T,Zhou Q.Acomparative analysis of the effects of CO2cor-rosion on banded pipeline steel structure in lower temperature areas[J].J.Gansu Sciences,2005,17(2):110-103(杨新田,周琦.管线钢带状组织对低温区CO2腐蚀行影响的比较分析[J].甘肃科学学报,2005,17(2):110-113)
[49]Zhou Q,Fu X S,Huang S J.Influence of banded structure in spe-cial oil tube on corrosion behavior at low temperature[J].Corros.Prot.,2005,26(11):472-476(周琦,付希圣,黄淑菊.石油专用管中的带状组织对低温区CO2腐蚀的影响[J].腐蚀与防护,2005,26(11):472-476)
[50]Zhang G A,Lu M X,Wu Y S.Effect of HCO3-concentration onCO2corrosion in gas and oil fields[J].Electrochemistry,2005,11(4):387-392(张国安,路民旭,吴荫顺.HCO3-浓度对油气田中CO2腐蚀的影响[J].电化学,2005,11(4):387-392)
[51]Ye C Y,Wang Z B,Yan ML,et al.Resistance to CO2corrosion ofelectroless plating of Ni-P coating on steel N80[J].Corros.Sci.Prot.Technol.,2005,17(4):265-267(叶春艳,王占榜,严密林等.油套管钢化学镀Ni-P的抗CO2腐蚀性能[J].腐蚀科学与防护技术,2005,17(4):265-267)
[52]Li AK,Li G M,Guo X P.Study on adsorption behavior of inhibitorson N80 steel[J].Electrochemistry,2003,9(3):314-319(李爱魁,李国敏,郭兴蓬.缓蚀剂在N80钢上吸附行为研究[J].电化学,2003,9(3):314-319)
[53]Nordsveen M,Nesic S,Nyborg R,Stangeland A.A mechanisticmodel for carbon dioxide corrosion of mild steel in the presence ofprotective iron carbonate films-part1:theory and verification[J].Corrosion,2003,59(6):443-456
[54]Nesic S,Nordsveen M,Nyborg R,Stangeland A.A mechanisticmodel for carbon dioxide corrosion of mild steel in the presence ofprotective iron carbonate films-part 2:a numerical experiment[J].Corrosion,2003,59(6):489-498
[55]Nesic S,Lee K J.A mechanistic model for carbon dioxide corrosionof mild steel in the presence of protective iron carbonate films-part3:film growth model[J].Corrosion,2003,59(7):616-628
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