X70钢在磷酸盐缓冲溶液中的孔蚀电化学行为研究

中国腐蚀与防护学报

2006, Vol. 26

Issue (2): 80-84

研究报告

本期目录 | 过刊浏览

X70钢在磷酸盐缓冲溶液中的孔蚀电化学行为研究

毛健鹏;唐聿明;左禹*

北京化工大学材料科学与工程学院

The Electrochemical Characteristics of Pitting of X70 Pipeline Steel

Jian Peng Mao;Yuming Tang;Yu Zuo

北京化工大学材料科学与工程学院

全文: PDF(167 KB)

摘要: 研究了X70钢在磷酸盐缓冲溶液中的亚稳态与稳态孔蚀的电化学行为特征。发现Cl－浓度对X70钢在磷酸盐缓冲溶液中的孔蚀保护电位影响不大，而PO43－对X70钢有较强的孔蚀抑制作用，增加PO43－浓度，能够有效提高X70钢的孔蚀保护电位。提高缓冲溶液的pH值能够抑制X70钢小孔的形核和生长。X70钢亚稳态小孔形核主要受到铝氧夹杂物的影响, 且随着电位的升高，电流波动频率先升高后降低，而峰值电流则趋于增大。X70钢在磷酸盐缓冲溶液中形成的钝化膜在钝化区内阻抗基本不受电位的影响。

关键词 ：孔蚀, 亚稳态孔蚀, 电流波动, X70钢, 交流阻抗

Abstract：The Electrochemical Characteristics of pitting of X70 Pipeline Steel in Phosphate Buffer Solution are studied in this paper. It is found that the effect of Cl- ions on pitting protection potential is neglectable. PO43- ions show strong inhibition on nucleation and the growth of pitting. Impurity and the surface grooves left by polishing result in the nucleation and the growth of metastable pitting. The nucleation frequency increases at first and then decreases with potential, while peak current increases continually. In the potential range of metastable pitting, the impedance of passive film keeps almost unchanged with potential. However, the impedance shows an obvious decrease when potential is above pitting potential Eb.

Key words： pitting metastable pitting current fluctuations X70 steel EIS

收稿日期: 2005-01-13

ZTFLH:

TG174

通讯作者: 毛健鹏 E-mail: mipal@sina.com

Corresponding author: Jian Peng Mao E-mail: mipal@sina.com

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引用本文:

毛健鹏; 唐聿明; 左禹* . X70钢在磷酸盐缓冲溶液中的孔蚀电化学行为研究[J]. 中国腐蚀与防护学报, 2006, 26(2): 80-84 .
Jian Peng Mao, Yuming Tang, Yu Zuo. The Electrochemical Characteristics of Pitting of X70 Pipeline Steel. J Chin Soc Corr Pro, 2006, 26(2): 80-84 .

链接本文:

https://www.jcscp.org/CN/ 或 https://www.jcscp.org/CN/Y2006/V26/I2/80

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