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中国腐蚀与防护学报  2005, Vol. 25 Issue (5): 312-316     
  研究报告 本期目录 | 过刊浏览 |
Cr-Ni型水轮机材料电化学腐蚀和抗空蚀行为
娄延春;赵芳欣;于波;王景成;熊云龙
沈阳铸造研究所
ELECTROCHEMICAL CORROSION AND CAVITATION EROSION BEHAVIOR OF Cr-Ni HYDRAULEC TURBINE MATERIAL
Yanchun Lou;Fangxin Zhao;Bo Yu;Jingcheng Wang;Yunlong Xiong
沈阳铸造研究所
全文: PDF(172 KB)  
摘要: 以ZG20Cr13为对比材料,在浓度为1mol/L的H2SO4溶液中测定了ZG06Cr13Ni4Mo(简称13-4)和Cr含量降至1061%、834%和664%(mass)时材料的阳极极化曲线.利用超声振荡空蚀实验机和洛氏硬度计分别研究了13-4、85Cr-4N i(简称85-4)和高强韧性Cr-Ni型不锈钢SRIF的空蚀行为和局域弹性性质,并研究了试验材料的组织和力学性能.结果表明,随13-4中Cr含量降低,材料的电化学腐蚀性能降低.当Cr含量降低至834%时,材料的电化学腐蚀性能与ZG20Cr13相当,仍属于不锈钢范畴.8.5-4、13-4和SRIF的局域弹性性质he无明显差别,13-4的抗空蚀性能略高于8.5-4,SRIF的抗空蚀性能明显高于前两者.
关键词 Cr-Ni不锈钢水轮机材料电化学腐蚀空蚀    
Abstract:Based on ZG06Cr13Ni4Mo (13-4),while its chromium content being reduced to 10.61%,8.34% and 6.64% respectively,their anodic polarization curves compared with that of ZG20Cr13 have been tested in 1mol/L H2SO4 solution.Using ultrasonic vibration cavitation erosion device and Rockwell apparatus,the 13-4,the 8.5Cr-4Ni (8.5-4) and the high strength and high toughness stainless steel -SRIF have been studied on the behaviors of cavitation erosion resistance and local micro-zone elasticity respectively.Their microstructures and mechanical properties have also been investigated.The results show that electrochemical corrosion properties decrease as chromium content decreases comparing with these of the 13-4.When chromium content decreases to 8.34%,the material and ZG20Cr13 are matched in electrochemical corrosion properties,which is still in the category of stainless steel.The values of local micro-zone elasticity he of 8.5-4,13-4 and SRIF are very close.The cavitation erosion resistances of the 13-4 are higher a little than these of the 8.5-4,and these of the SRIF are obviously higher than those of 8.5-4 and 13-4.
Key wordsCr-Ni stainless steel    hydraulic turbine material    electrochemical corrosion    cavitation erosion    mechan
收稿日期: 2005-01-20     
ZTFLH:  TG174.36  
通讯作者: 娄延春     E-mail: Yub@Chinasrif.com
Corresponding author: Yanchun Lou     E-mail: Yub@Chinasrif.com

引用本文:

娄延春; 赵芳欣; 于波; 王景成; 熊云龙 . Cr-Ni型水轮机材料电化学腐蚀和抗空蚀行为[J]. 中国腐蚀与防护学报, 2005, 25(5): 312-316 .
Yanchun Lou, Fangxin Zhao, Bo Yu, Jingcheng Wang, Yunlong Xiong. ELECTROCHEMICAL CORROSION AND CAVITATION EROSION BEHAVIOR OF Cr-Ni HYDRAULEC TURBINE MATERIAL. J Chin Soc Corr Pro, 2005, 25(5): 312-316 .

链接本文:

https://www.jcscp.org/CN/      或      https://www.jcscp.org/CN/Y2005/V25/I5/312

[1]Gysel W,Gerber E,Trautwein A.CA6NM:New developmentsbased on 20 years experience[J].Stainless Steel Castings,1982,(3):403-435
[2]Lou Y C,Lang X,Zhao F X.Effect of variation in chromium on thecharacteristic and regulation of heat treatment for Cr-Ni hydraulicturbine material[J].Foundry,2004,53(5):345-349(娄延春,朗霄,赵芳欣.铬含量对Cr-Ni型水轮机材料特性的影响与调控[J].铸造,2004,53(5):345-349)
[3]Pandey J L,Singh I,Singh M N.Electrochemical corrosion be-haviour of heat-treated AISI 304 austenitic stainless steel in inor-ganic acid mixture[J].Anti-Corrosion Methods and Materials,1997,44(1):6-9
[4]Barreau S,Morton J,Hermas A A.A correlation between phospho-rous impurity in stainless steel and a second anodic current maxi-mum in H2SO4[J].Corros.Sci.,1999,41(12):2251-2266
[5]Wang Z Y,Zhu J H.Effect of primary factors on cavitation erosionresistance of some metastable austenitic metals[J].Acta Metall.Sin.,2003,39(3):273-277(王再友,朱金华.亚稳奥氏体金属抗空蚀性能及其主要控制因素[J].金属学报,2003,39(3):273-277)
[6]Liu W,Zheng Y G,Yao Z M.Cavitation erosion of 20SiMn and0Cr13Ni5Mo steels in distilled water with and without sand[J].Ac-ta Metall.Sin.,2001,37(2):197-201(柳伟,郑玉贵,姚治铭.清水和含沙水中20SiMn和0Cr13Ni5Mo钢的空蚀行为[J].金属学报,2001,37(2):197-201)
[7]Mann B S.Boronizing of cast martensitic chromium nickel stainlesssteel and its abrasion and cavitation-erosion behaviour[J].Wear,1997,208(1):125-131
[8]Long N D,Zhu J H.Cavitation erosion resistance of Fe-26Mn-6Si-7Cr-1Cu shape memory alloy[J].Mater.Sci.Technol.,2003,19(12):1733-1736
[9]Kwok C T,Man H C,Cheng F T.Cavitation erosion of duplex andsuper duplex stainless steels[J].Scripta Materialia,1998,39(9):1229-1236
[10]Luo S Z,Jing H M,Zheng Y G.Cavitation-corrosion behavior ofCrMnN duplex stainless steel[J].J.Chin.Soc.Corros.Prot.,2003,23(5):276-281(骆素珍,敬和民,郑玉贵.CrMnN双相不锈钢的空泡腐蚀行为研究[J].中国腐蚀与防护学报,2003,23(5):276-281)
[11]Wang B,Wang Y D,Zhang Z H.Plating rare earth chromium onhydraulic turbine’s substrates to improve resistance to cavitationerosion and abrasion[J].J.Chin.Soc.Corros.Prot.,2003,23(1):34-37(王飚,王宇栋,张自华.电镀稀土铬提高水轮机的抗空蚀磨损能力[J].中国腐蚀与防护学报,2003,23(1):34-37)
[12]Kaesche H.The Corrosion of Metal[J].The 2ndEdition.Berlin:Springer Press,1979(Kaesche H.Die Korrosion der Metalle—Zweite V llig neubear-beitete und erweiterte Auflage[M].Berlin:Springer,1979)
[13]Geng C W,He S S,Yu B.Study on martensitic stainless steelZG0Cr13Ni4Mo for nuclear power[J].Metal Physics Examinationand Testing,1992,(4):13-25(耿承伟,何树生,于波.核电站用ZG0Cr13Ni4Mo马氏体不锈钢研制[J].物理测试,1992,(4):13-25)
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