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中国腐蚀与防护学报  2015, Vol. 35 Issue (5): 474-478    DOI: 10.11902/1005.4537.2014.186
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AISI4135钢在浪溅区的润湿特征及规律
黄彦良1(),余秀明1,2,郑珉1,2,曲文娟1,2,Amar Prasad Yadav1,Roland De Marco3
2. 中国科学院大学 北京 100049
3. University of the Sunshine Coast, Queensland 4558
Wetting Characteristics and Regularity of AISI4135 Steel in Marine Splash Zone
Yanliang HUANG1(),Xiuming YU1,2,Min ZHENG1,2,Wenjuan QU1,2,Prasad Yadav Amar1,De Marco Roland3
1. Key Laboratory of Marine Environment Corrosion and Marine Fouling, Institute of Oceanology, Chinese Academy of Sciences, Qingdao 266071, China
2. University of Chinese Academy of Sciences, Beijing 100049, China
3. University of the Sunshine Coast, Queensland 4558, Australia
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摘要: 

对浪溅区不同位置处AISI4135钢试样表面的润湿状态随潮汐的变化进行了研究。结果表明:浪溅区试样表面润湿程度与位置和潮汐的变化有关,大体上呈随潮位升高润湿程度加大,随潮位降低润湿程度降低的变化趋势。但在同一时刻试样的润湿状态与潮位和试样的位置关系具有不确定性,试样的润湿程度随暴露天数的增加有增强的趋势。浪溅区由于飞溅的海水泡沫的作用及较高的空气湿度,即使在低潮区仍然处于湿润状态,这与腐蚀产物有较高的吸湿特性有关。碳钢在浪溅区腐蚀速率的极值点对应一特定的润湿程度,在极值点以下常能观察到由于浪花飞溅、水汽凝结出现的肉眼可见液膜,这和金属腐蚀速率与表面液膜厚度的关系相一致。

关键词 钢铁材料浪溅区润湿状态    
Abstract

The corrosion rate of steels in marine splash zone is high, and it is generally considered to be due to the environmental characteristics of this zone. One of the important distinctions between the marine splash zone and the normal atmospheric zone is the wetting condition of steel surfaces. However even in the same splash zone, the corrosion rate of one spot is different to that of the other ones on the surface of one steel pile, thereby on which a corrosion rate peak should exist at a specific spot. In order to reveal the nature of the difference in corrosion rate at different positions of a steel pile, the variations of the wetting condition of steel specimens with tidal movement was monitored, while the specimens located at different positions along a vertical line passing the tide zone. It follows that the wetting degree of the steel specimen in the splash zone is closely related with its location and the tidal movement, and which substantially follows an overall trend that the wetting degree increases with the rising tide level and decrease with the lowering tide level; the wetting degree of the steel specimen increases with the increase of exposure time. But for a specific moment, a certain relationship dose not exist for the wetting degree with the tide movement and the location of steel specimen. Even though by the time of the low tide level the steel specimen located in splash zone is still in a wet condition due to the effect of the high air humidity and flying seawater foam, which correlates also to the high moisture absorption characteristics of corrosion products scale on the carbon steel. The extreme corrosion rate of the steel in splash zone corresponds to a specific wetting degree. Furthermore, on the area below the extreme point, thin water film on the surface of steel specimens can often be observed by naked eyes, which is consistent with the relationship between corrosion rate and thickness of liquid film on the metal surface.

Key wordsiron and steel    splash zone    wetting condition
    
ZTFLH:     
基金资助:国家自然科学基金项目 (41276087),江苏省自然科学基金项目 (BK2012649) 和中国科学院发展中国家访问学者项目资助

引用本文:

黄彦良, 余秀明, 郑珉, 曲文娟, Amar Prasad Yadav, Roland De Marco. AISI4135钢在浪溅区的润湿特征及规律[J]. 中国腐蚀与防护学报, 2015, 35(5): 474-478.
Yanliang HUANG, Xiuming YU, Min ZHENG, Wenjuan QU, Prasad Yadav Amar, De Marco Roland. Wetting Characteristics and Regularity of AISI4135 Steel in Marine Splash Zone. Journal of Chinese Society for Corrosion and protection, 2015, 35(5): 474-478.

链接本文:

https://www.jcscp.org/CN/10.11902/1005.4537.2014.186      或      https://www.jcscp.org/CN/Y2015/V35/I5/474

图1  浪溅区试样表面润湿状态测试装置简图
图2  浪溅区试样表面润湿状态与潮汐变化的关系
图3  2013年6月4日浪溅区1号试样的润湿状态与潮汐变化的关系
图4  低潮位时试样的润湿程度与暴露时间的关系
图5  试样的平均润湿程度与暴露时间的关系
图6  试样的平均润湿程度与其距离平均高潮线距离的关系
图7  海水液滴在无锈和带锈试样上的润湿情况
图8  无锈和带锈试样的吸湿情况
图9  碳钢在青岛海区浪溅区3个月的腐蚀速率实验结果[9]
图10  碳钢在浪溅区的腐蚀速率与润湿程度的关系
[1] Hou B R. Marine Corrosion Environment Theory and Application[M]. Beijing:Science Press, 1999 (侯保荣主编. 海洋腐蚀环境理论及其应用[M]. 北京: 科学出版社, 1999)
[2] Zhu X R, Wang X R, Huang G Q. Corrosion and protection of steel in marine splash zone[J]. Mar. Sci., 1995, 19(3): 23 (朱相荣, 王相润, 黄桂桥. 钢在海洋飞溅带的腐蚀与防护[J]. 海洋科学, 1995, 19(3): 23)
[3] Zhu X R, Huang G Q, Lin L Y, et al. Long term corrosion characteristics of metallic materials in marine environments[J]. Corros. Eng. Sci. Technol., 2008, 43(4): 328
[4] Smith M, Bowley C, Williams L. In-situ protection of splash zones-30 years on[J]. Mater. Perform., 2002, 41(10): 30
[5] A staff report. Marine corrosion findings at Kure beach reviewed for editors[J]. Chem. Eng. News Archive, 1949, 27(26): 1867
[6] Kazuaki Z. Corrosion and life cycle management of port structures[J]. Corros. Sci., 2005, 47: 2353
[7] Ramana K V S, Kaliappan S, Ramanathan N, et al. Characterization of rust phases formed on low carbon steel exposed to natural marine environment of Chennai harbour-South India[J]. Mater. Corros., 2007, 58(11): 873
[8] Dai Y S. The anti-corrosion design and construction method of foreign port workers and marine engineering steel structures in tidal wave splash zone[J]. J. Waterway Harbor, 1981, (Z1): 33 (戴永寿. 国外港工和海工钢结构物潮差段和浪溅区的防腐设计研究及施工方法[J]. 水道港口, 1981, (Z1): 33)
[9] Zhu X R, Huang G Q. Corrosine behaviour of steel in marine splash zone[J]. Corros. Sci. Prot. Technol., 1995, 7(3): 246 (朱相荣, 黄桂桥. 钢在海洋飞溅带腐蚀行为探讨[J]. 腐蚀科学与防护技术, 1995, 7(3): 246)
[10] Liu W, Wang J. Environmental impact of material corrosion research progress in marine splash zone[J]. J. Chin. Soc. Corros. Prot., 2010, 30(6): 504 (刘薇, 王佳. 浪溅区环境对材料腐蚀行为影响的研究进展[J]. 中国腐蚀与防护学报, 2010, 30(6): 504)
[11] Hou B R. Marine Corrosion and Protection[M]. Beijing: Science Press, 1997 (侯保荣. 海洋腐蚀与防护[M]. 北京: 科学出版社, 1997)
[12] Cui X L, Wang X Y, Ma J H, et al. Corrosion resistance of 15MnMoVN steel exposed in marine splash zone[J]. J. Iron Steel Res., 1995, 7(4): 43 (崔寿峰, 王相闫, 马斤华等. 飞溅区15MnMoVN钢锈层的研究[J]. 钢铁研究学报, 1995, 7(4): 43)
[13] Research Institute of Chemical Machinery,Ministry of Chemical Industry. Manual of Corrosion and Protection-corrosion Theory, Testing and Monitoring[M]. Beijing: Chemical Industry Press, 1989 (化学工业部化工机械研究院主编. 腐蚀与防护手册-腐蚀理论、试验及监测[M]. 北京: 化学工业出版社, 1989)
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