Research Progress on Modification of Microarc Oxidation Coatings on Ti-alloy Surface by Adding Ceramic Particles to Electrolyte

doi:10.11902/1005.4537.2024.382

Journal of Chinese Society for Corrosion and protection

2025, Vol. 45

Issue (5): 1175-1186 DOI: 10.11902/1005.4537.2024.382

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Research Progress on Modification of Microarc Oxidation Coatings on Ti-alloy Surface by Adding Ceramic Particles to Electrolyte

HE Jianghai, YANG Ziyu, LIU Qi, MA Zihua, HE Wei, CHEN Fei(

)

School of New Materials and Chemical Engineering, Beijing Institute of Petrochemical Technology, Beijing 102617, China

Cite this article:

HE Jianghai, YANG Ziyu, LIU Qi, MA Zihua, HE Wei, CHEN Fei. Research Progress on Modification of Microarc Oxidation Coatings on Ti-alloy Surface by Adding Ceramic Particles to Electrolyte. Journal of Chinese Society for Corrosion and protection, 2025, 45(5): 1175-1186.

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Abstract

It is known that modification with micro arc oxidation (MAO) technique, the physical defects such as porosities or pinholes may commonly exist in the formed coatings on the Ti-alloy surface, which seriously affects the relevant properties and the service life-time of Ti-alloy parts or facilities, in view of this problem, herein it summarizes the research progress on the addition of binary compounds in the electrolyte to modify the relevant properties of MAO coatings on Ti-alloy in terms of the resistance to abrasion, corrosion and high temperature oxidation, as well as the photocatalytic and antimicrobial properties. Furthermore, the future research direction and ideas to create MAO coatings of peculiar performance for Ti-alloy, the utilizing different binary compounds with various function and particle size, even multiple binary compounds etc. are proposed, hoping to provide reference and reference for future research on titanium alloys.

Key words: microarc oxidation Ti-alloy defects binary compounds properties

Received: 26 November 2024 32134.14.1005.4537.2024.382

ZTFLH:

TG174.45

Fund: Natural Science Foundation of Beijing(2202017)

Corresponding Authors: CHEN Fei, E-mail: chenfei@bipt.edu.cn

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	HE Jianghai
	YANG Ziyu
	LIU Qi
	MA Zihua
	HE Wei
	CHEN Fei

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https://www.jcscp.org/EN/10.11902/1005.4537.2024.382 OR https://www.jcscp.org/EN/Y2025/V45/I5/1175

Fig.1 Surface and cross-sectional morphologies of MAO films formed on Ti-alloy in the electrolytes containing different contents of ZrO₂ particles: (a) 0 g/L, (b) 0.25 g/L, (c) 0.5 g/L, (d) 0.75 g/L, (e) 1.00 g/L, (f) 1.25 g/L^[36]

Table 1 Effects of binary compound particles added in the electrolytes on the corrosion resistances of MAO films of Ti-alloy in 3.5%NaCl solution

Fig.2 EIS and fitting curves of MAO coating formed in the electrolyte containing MoS₂ particles in 3.5% (mass fraction) NaCl solution: (a, b) Nyquist plots, (c) Bode impedance plots, (d) Bode phase angle plots^[46]

Table 2 Effects of additions of binary compound particles in the electrolytes on the hardnesses and friction coefficients of MAO coatings on Ti-alloy

Fig.3 Abrasion SEM morphology of the surface film layer of GO particles with different contents added to the electrolyte: (a, c) 0 g/L, (b, d) 5 g/L^[64]

Fig.4 Mass gains and corresponding macroscopic morphologies of TC11 alloy without and with MAO treatments in the electrolytes containing different concentrations of Nd₂O₃ after oxidation at 800 ℃ for 50 h^[55]

Fig.5 UV-Vis spectra of TiO₂ and TiO₂/Eu₂O₃ MAO films^[66]

Fig.6 Photogenerated current intensities of TiO₂ and TiO₂/Eu₂O₃ MAO films^[66]

Fig.7 Photocatalytic activities of TiO₂ and TiO₂/Eu₂O₃ MAO films^[66]

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