High Temperature Oxidation Behavior of F55 Super Duplex Stainless Steel at 800-1000oC in 1.013×105 Pa O2

doi:10.11902/1005.4537.2023.326

Journal of Chinese Society for Corrosion and protection

2024, Vol. 44

Issue (5): 1332-1338 DOI: 10.11902/1005.4537.2023.326

Current Issue | Archive | Adv Search

High Temperature Oxidation Behavior of F55 Super Duplex Stainless Steel at 800-1000^oC in 1.013×10⁵ Pa O₂

WU Ming¹, REN Yanjie¹^,²(

), MA Zhuochun¹, ZHANG Sitian¹, CHEN Jian¹, NIU Yan¹(

)

1 Department of Energy and Power Engineering, Changsha University of Science and Technology, Changsha 410076, China
2 School of Mechanical & Energy Engineering, Zhejiang University of Science & Technology, Hangzhou 310023, China

Cite this article:

WU Ming, REN Yanjie, MA Zhuochun, ZHANG Sitian, CHEN Jian, NIU Yan. High Temperature Oxidation Behavior of F55 Super Duplex Stainless Steel at 800-1000^oC in 1.013×10⁵ Pa O₂. Journal of Chinese Society for Corrosion and protection, 2024, 44(5): 1332-1338.

Download:

HTML

PDF(13960KB)
Export: BibTeX | EndNote (RIS)

Abstract

The oxidation behavior of F55 duplex stainless steel in 1.013 × 10⁵ Pa pure oxygen at 800, 900, 1000℃ has been studied by means of thermal gravimetric analyzer, optical microscope, scanning electron microscope (SEM) and X-ray diffraction (XRD). The results show that the oxide scales are mainly composed of Cr₂O₃ and Cr-Mn oxides at the designed temperatures. The oxidation kinetics curves follow parabolic law, and the oxidation mass gain increases with the increase of temperature. During the oxidation process, the α phase on the surface of the alloy changes into γ phase due to the outward diffusion of Cr, while the α phase in the matrix undergoes eutectoid reaction to form σ + γ and other phases. Cr in the σ phase generated by the eutectoid reaction preferentially diffuses to the surface of the alloy to participate in the oxidation reaction.

Key words: F55 duplex stainless steel high temperature oxidation phase change eutectoid reaction

Received: 18 October 2023 32134.14.1005.4537.2023.326

ZTFLH:

TG174

Fund: Education Department of Hunan Province of China(21A0204)

Corresponding Authors: REN Yanjie, E-mail: yjren@csust.edu.cnNIU Yan, E-mail: yniu@csust.edu.cn

	Service

	E-mail this article
	Add to citation manager
	E-mail Alert
	RSS
	（）
	Articles by authors
	WU Ming
	REN Yanjie
	MA Zhuochun
	ZHANG Sitian
	CHEN Jian
	NIU Yan

URL:

https://www.jcscp.org/EN/10.11902/1005.4537.2023.326 OR https://www.jcscp.org/EN/Y2024/V44/I5/1332

Fig.1 Optical (a, b) and SEM metallograph (c), and XRD pattern (d) of F55 duplex stainless steel

Fig.2 Kinetic curves of F55 duplex stainless steel during oxidation in 1.013×10⁵ Pa O₂ at 800, 900 and 1000^oC for 50 h: (a) linear plots, (b) parabolic plots

Table 1 Parabolic rate constants and durations of the various stages for F55 alloy during oxidation for 50 h in 1.013×10⁵ Pa O₂ at 800, 900 and 1000^oC

Fig.3 Cross-sectional morphologies (a, c, e) and EDS element mappings (b, d, f) of F55 duplex stainless steel oxidized in 1.013×10⁵ Pa O₂ at 800^oC (a, b), 900^oC (c, d) and 1000^oC (e, f) for 50 h

Table 2 Calculated diffusion coefficients of Cr atoms in α-Fe and γ-Fe

Fig.4 Microstructures of F55 alloy before (a) and after 50 h oxidation at 800^oC (b), 900^oC (c) and 1000^oC (d)

Table 3 Phase and main element components of rolled F55 steel before and after 50 h oxidation at 800, 900 and 1000^oC

1	Lussana D, Baldissin D, Massazza M, et al. Thermodynamic and kinetics aspects of high temperature oxidation on a 304L stainless steel [J]. Oxid. Met., 2013, 81: 515
2	Gunn R N. Duplex Stainless Steels: Microstructure, Properties and Applications [M]. Cambridge: Abington Publishing, 1997: 16
3	Baddoo N R. Stainless steel in construction: a review of research, applications, challenges and opportunities [J]. J. Constr. Steel Res., 2008, 64: 1199
4	Gowthaman P S, Jeyakumar S, Saravanan B A. Machinability and tool wear mechanism of Duplex stainless steel–A review [J]. Mater. Today: Proc., 2020, 26: 1423
5	Lo K H, Shek C H, Lai J K L. Recent developments in stainless steels [J]. Mater. Sci. Eng., 2009, 65R: 39
6	Li Y, Wang J, Zhang Y, et al. Analysis of initial oxidation process of 2205 duplex stainless steel in closed container at high temperature [J]. J. Chin. Soc. Corros. Prot., 2018, 38: 296
	李越, 王剑, 张勇等. 2205双相不锈钢密闭容器中高温初始氧化过程分析 [J]. 中国腐蚀与防护学报, 2018, 38: 296
7	Matsumoto M, Kimura K, Sugiura N. The influence of high-temperature oxidation on the phase distribution of metal substrate in duplex stainless steel [J]. Oxid. Met., 2021, 96: 531
8	Pardal J M, Tavares S S M, da Penha Cindra Fonseca M, et al. Deleterious phases precipitation on superduplex stainless steel UNS S32750: characterization by light optical and scanning electron microscopy [J]. Mater. Res., 2010, 13: 401
9	Caplan D, Cohen M. The volatilization of chromium oxide [J]. J. Electrochem. Soc., 1961, 108: 438
10	Lillerud K P, Kofstad P. On high temperature oxidation of chromium: I. Oxidation of annealed, thermally etched chromium at 800°–1100°C [J]. J. Electrochem. Soc., 1980, 127: 2397
11	Lobnig R E, Schmidt H P, Hennesen K, et al. Diffusion of cations in chromia layers grown on iron-base alloys [J]. Oxid. Met., 1992, 37: 81
12	Stanislowski M, Wessel E, Hilpert K, et al. Chromium vaporization from high-temperature alloys: I. Chromia-forming steels and the influence of outer oxide layers [J]. J. Electrochem. Soc., 2007, 154: A295
13	Jin Q M, Li J, Xu Y L, et al. High-temperature oxidation of duplex stainless steels S32101 and S32304 in air and simulated industrial reheating atmosphere [J]. Corros. Sci., 2010, 52: 2846
14	Tao M S, Ren Y J, Huang J, et al. Microstructure and high temperature oxidation properties of Inconel 625 alloy fabricated by rolling and selective laser melting [J]. Mater. Sci. Technol., 2022, 30(4): 1
	陶明生, 任延杰, 黄杰等. 激光选区熔化与轧制Inconel 625合金的微观组织与高温氧化性能研究 [J]. 材料科学与工艺, 2022, 30(4): 1
15	Huang W Y, Li Y T, Yanjie R E N, et al. Effect of scanning speed on the high-temperature oxidation resistance and mechanical properties of Inconel 625 alloys fabricated by selective laser melting [J]. Vacuum, 2022, 206: 111447
16	Siri C, Popa I, Vion A, et al. Impact of selective laser melting additive manufacturing on the high temperature behavior of AISI 316L austenitic stainless steel [J]. Oxid. Met., 2020, 94: 527
17	Neumann G, Tuijn C. Self-diffusion and Impurity Diffusion in Pure Metals: Handbook of Experimental Data [M]. Amsterdam: Pergamon, 2009: 259
18	Li L F, Jiang Z H, Riquier Y. High-temperature oxidation of duplex stainless steels in air and mixed gas of air and CH₄ [J]. Corros. Sci., 2005, 47: 57
19	An L C, Cao J, Zhang T, et al. Cr diffusion and continuous repairing behavior during high-temperature oxidation of duplex stainless steel [J]. Mater. Corros., 2017, 68: 1116
20	Jepson M A E, Higginson R L. In-situ observation of the oxidation of S32101 duplex stainless steel at 900^oC [J]. Corros. Sci., 2012, 59: 263
21	Han P D, Bai J G, Li H F, et al. The Mo distribution and σ phase formation of the Austenitic stainless [A]. Proceedings of the National Symposium on Mathematical Applications in Materials Science [C]. Baoding: 2010: 55
	韩培德, 白晋钢, 李洪飞等. 奥氏体不锈钢中Mo元素分布与σ相析出规律 [A]. 全国材料科学中的数学应用研讨会论文集 [C]. 保定: 中国体视学学会金相与显微分析分会, 2010: 55
22	Domínguez-Aguilar M A, Newman R C. Detection of deleterious phases in duplex stainless steel by weak galvanostatic polarization in alkaline solution [J]. Corros. Sci., 2006, 48: 2560
23	Chen Y L, Luo Z Y, Li J Y. Effect of solution temperature on microstructure and pitting corrosion resistance of S32760 duplex stainless steel [J]. Acta Metall. Sin., 2015, 51: 1085
	陈雨来, 罗照银, 李静媛. 固溶温度对S32760双相不锈钢组织与耐点蚀性能的影响 [J]. 金属学报, 2015, 51: 1085
24	Kim S T, Jang S H, Lee I S, et al. Effects of solution heat-treatment and nitrogen in shielding gas on the resistance to pitting corrosion of hyper duplex stainless steel welds [J]. Corros. Sci., 2011, 53: 1939
25	Han Y, Zou D N, Zhang W, et al. Influence of sigma phase precipitation on pitting corrosion of 2507 super-duplex stainless steel [J]. Mater. Sci. Forum, 2010, 658: 380
26	Weber L, Uggowitzer P J. Partitioning of chromium and molybdenum in super duplex stainless steels with respect to nitrogen and nickel content [J]. Mater. Sci. Eng., 1998, 242A: 222
27	Brenner S S. Catastrophic oxidation of some molybdenum-containing alloys [J]. J. Electrochem. Soc., 1955, 102: 16
28	Deng B, Wang Z Y, Jiang Y M, et al. Effect of thermal cycles on the corrosion and mechanical properties of UNS S31803 duplex stainless steel [J]. Corros. Sci., 2009, 51: 2969
29	Mészáros I, Bögre B. Complex study of eutectoidal phase transformation of 2507-type super-duplex stainless steel [J]. Materials, 2019, 12: 2205
30	Buscail H, El Messki S, Riffard F, et al. Role of molybdenum on the AISI 316L oxidation at 900^oC [J]. J. Mater. Sci., 2008, 43: 6960

[1]	LI Kaiyang, ZHAI Yunlong, HU Xinyu, WU Hong, LIU Bin, XING Shaohua, HOU Jian, ZHANG Fan, ZHANG Naiqiang. Research Progress on High Temperature Corrosion of Eutectic High Entropy Alloys[J]. 中国腐蚀与防护学报, 2024, 44(6): 1377-1388.
[2]	ZHANG Bangyan, WU Hongbin, HU Xuegang, DONG Jiajian, ZHENG Shijie, YIN Weiwei, ZHANG Fangyu, TIAN Lixi, LIU Guangming. High Temperature Oxidation Behavior of FeCrAl/La₂Zr₂O₇ Composites Prepared by Mechanical Alloying and Spark Plasma Sintering[J]. 中国腐蚀与防护学报, 2024, 44(4): 965-971.
[3]	FENG Kangkang, REN Yanjie, LV Yunlei, ZHOU Mengni, CHEN Jian, NIU Yan. Effect of Si Content on Oxidation Behavior of Quaternary Fe-20Ni-20Cr- ySi Alloys in Oxygen at 900^oC[J]. 中国腐蚀与防护学报, 2024, 44(1): 100-106.
[4]	WANG Shuang, WANG Zixing, CHENG Xiaonong, LUO Rui. Effect of Rare Earth La on High Temperature Oxidation of Cobalt-based Superalloy GH5188 at 1100^oC[J]. 中国腐蚀与防护学报, 2024, 44(1): 221-228.
[5]	REN Yan, ZHANG Xintao, GAI Xin, XU Jingjun, ZHANG Wei, CHEN Yong, LI Meishuan. High Temperature Oxidation Behavior of Quaternary (Cr_2/3Ti_1/3)₃AlC₂ MAX Ceramic in Air and Steam[J]. 中国腐蚀与防护学报, 2023, 43(6): 1284-1292.
[6]	LIU Huanhuan, LIU Guangming, LI Futian, MENG Lingqi, XIAHOU Junzhao, GU Jialei. Oxidation Behavior of TP439 Stainless Steel in Water Vapor at 800 ℃[J]. 中国腐蚀与防护学报, 2023, 43(2): 377-383.
[7]	REN Yanjie, LV Yunlei, DAI Ting, GUO Xiaohui, CHEN Jian, ZHOU Libo, QIU Wei, NIU Yan. Oxidation Behavior of Ternary Alloys Co-20Ni-3Al and Co-20Ni-5Al in 10⁵ Pa O₂ Atmosphere at 800-1000 ℃[J]. 中国腐蚀与防护学报, 2022, 42(6): 995-1001.
[8]	XIE Leipeng, CHEN Minghui, WANG Jinlong, WANG Fuhui. High Temperature Oxidation Behavior of Ultrafine Grained ODS Nickel-based Superalloy Prepared by Spark Plasma Sintering[J]. 中国腐蚀与防护学报, 2022, 42(5): 709-716.
[9]	ZHANG Qin, LIANG Taosha, WANG Wen, ZHAO Langlang, JIANG Yuefeng. Oxidation Kinetics and Microstructure Evolution of Nanocrystalline Ni-12Cr Alloy at 800 ℃[J]. 中国腐蚀与防护学报, 2022, 42(5): 733-742.
[10]	PEI Shubo, WAN Dongyang, ZHOU Ping, CAO Guoqin, HU Junhua. Research Progress on Preparation, Microstructure, Oxidation- and Corrosion-resistance of High-entropy Alloy Coatings[J]. 中国腐蚀与防护学报, 2022, 42(5): 873-878.
[11]	QIU Panpan, SHU Xiaoyong, HU Linli, YANG Tao, FANG Yuqing. Research Progress of Pt-modified Aluminide Coating on Nickel-base Superalloys[J]. 中国腐蚀与防护学报, 2022, 42(2): 186-192.
[12]	LI Ling, DU Xiran, QU Pinquan, LI Jiancheng, WANG Jinlong, GU Yan, ZHANG Jia, CHEN Minghui, WANG Fuhui. Effect of Vacuum Heat Treatment on Oxidation Behavior of Arc Ion Plated NiCoCrAlY Coatings[J]. 中国腐蚀与防护学报, 2022, 42(2): 243-248.
[13]	YANG Sheng, ZHANG Huijie, XIANG Wuyuan, OUYANG Tao, XIAO Fen, ZHOU Hui. Effect of Post Surface Treatment of Micro-arc Oxidation Films/TC4 Ti-alloy on Their Morphology and Galvanic Corrosion Performance[J]. 中国腐蚀与防护学报, 2021, 41(6): 905-908.
[14]	XIE Dongbai, HONG Hao, WANG Wen, PENG Xiao, DUO Shuwang. Oxidation Behavior of Stainless Steel 1Cr11Ni2W2MoV in a Simulated Kerosene Combustion Environment[J]. 中国腐蚀与防护学报, 2020, 40(4): 358-366.
[15]	XU Xunhu,HE Cuiqun,XIANG Junhuai,WANG Ling,ZHANG Honghua,ZHENG Xiaodong. High Temperature Oxidation Behavior of Co-20Re-25Cr-1Si Alloy in 0.1 MPa Pure Oxygen[J]. 中国腐蚀与防护学报, 2020, 40(1): 75-80.

No Suggested Reading articles found!

Viewed

Full text

Abstract

Cited

Shared

Discussed