Protective Performance of NiFe-LDH Composite Coatings Modified by insitu Polymerized Polyaniline

doi:10.11902/1005.4537.2022.099

Journal of Chinese Society for Corrosion and protection

2023, Vol. 43

Issue (2): 312-320 DOI: 10.11902/1005.4537.2022.099

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Protective Performance of NiFe-LDH Composite Coatings Modified by insitu Polymerized Polyaniline

JIANG Fangfang¹, YUN Hong¹(

), PENG Li², ZHANG Yihao¹, LI Weishun¹, DAI Wenjing¹, WANG Baofeng¹, XU Qunjie¹

^1.Shanghai Key Laboratory of Materials Protection and Advanced Materials in Electric Power, Shanghai Engineering Research Center of Heat-exchange System and Energy Saving, Shanghai University of Electric Power, College of Environmental and Chemical Engineering, Shanghai 200090, China
^2.Technical Center for Mechanical and Electrical Product Inspection and Testing of Shanghai Customs, Shanghai 200135, China

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Abstract

Different kinds of NiFe-LDH/polyaniline (PANI) composite coatings were prepared on the surface of 304 stainless steel by hydrothermal method coupled with in-situ polymerization method. The surface morphology and structure of the prepared LDH coatings were investigated by scanning electron microscope (SEM), energy dispersive spectroscope (EDS), X-ray diffractometer (XRD), Fourier transform infrared spectroscope (FT-IR) and X-ray photoelectron spectroscope (XPS). While the anti-corrosive performance of the coatings was characterized by means of polarization curve measurement and electrochemical impedance spectroscope, and the corrosion mechanism was discussed. The results showed that the composite LDH coatings with lamellar structure may be acquired by adding Fe(NO₃)₃. Then, its surface structure was further optimized by modification with PANI. There was a chemical bond between PANI and LDH, and the synergistic effect of them could improve the comprehensive performance of the composite coating. During 168 h immersion in 1 mol/L H₂SO₄ solution, NiFe-LDH/PANI composite coating exhibited good chemical stability, which implied that the coating could provide excellent physical shielding and anodic protection for 304 stainless steel.

Key words: polyaniline layered double hydroxide anti-corrosive 304 stainless steel

Received: 09 April 2022 32134.14.1005.4537.2022.099

ZTFLH:

TB332

Fund: National Natural Science Foundation of China(21972090);National Natural Science Foundation of China(22075173)

About author: YUN Hong, E-mail: yunhong@shiep.edu.cn

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	Fangfang JIANG
	Hong YUN
	Li PENG
	Yihao ZHANG
	Weishun LI
	Wenjing DAI
	Baofeng WANG
	Qunjie XU

Cite this article:

JIANG Fangfang, YUN Hong, PENG Li, ZHANG Yihao, LI Weishun, DAI Wenjing, WANG Baofeng, XU Qunjie. Protective Performance of NiFe-LDH Composite Coatings Modified by insitu Polymerized Polyaniline. Journal of Chinese Society for Corrosion and protection, 2023, 43(2): 312-320.

URL:

https://www.jcscp.org/EN/10.11902/1005.4537.2022.099 OR https://www.jcscp.org/EN/Y2023/V43/I2/312

Fig.1 SEM surface images (a, c, e, f) of NiFe-LDH (a), NiFe(s)-LDH (c), NiFe-LDH/PANI (e) and NiFe(s)-LDH/PANI (f) coatings on 304 stainless steel, and EDS element mappings of NiFe-LDH (b) and NiFe(s)-LDH (d) coatings

Fig.2 XRD patterns of the PANI, NiFe(s)-LDH, NiFe-LDH, NiFe(s)-LDH/PANI and NiFe-LDH/PANI coatings on 304 strainless steel

Fig.3 FT-IR spectroscopies of the as-prepared coatings on 304 strainless steel

Fig.4 Microscope images of NiFe(s)-LDH (a), NiFe-LDH (b), NiFe(s)-LDH/PANI (c) and NiFe-LDH/PANI (d) coatings on 304 strainless steel after adhesion test

Fig.5 Potential polarization curves of the 304 strainless steel samples with different coatings in 1 mol/L H₂SO₄ solution

Fig.6 Nyquist plots (a) of the 304 strainless steel samples with different coatings in 1 mol/L H₂SO₄ solution, and equivalent circuits for NiFe(s)-LDH and NiFe-LDH coatings (b) and NiFe(s)-LDH/PANI and NiFe-LDH/PANI coatings (c)

Table 1 Fitting parameters of electrochemical impedance spectroscopies of four coatings immersed in 1 mol/L H₂SO₄ solution for different time

Fig.7 Nyquist diagrams of different coatings immersed in 1 mol/L H₂SO₄ solution for different durations (a-d) and equivalent circuit diagram (e)

Fig.8 XPS survey spectra of various coatings (a), and fine spectra of N 1s (b), C 1s (c) and O 1s (d) for PANI, NiFe-LDH/PANI and NiFe(s)-LDH/PANI coatings, and Fe 2p (e) for NiFe-LDH and NiFe-LDH/PANI coatings

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