Oxidation Behavior in Water Vapor and Tribological Property in Atmosphere with 60%Relative Humidity at 580 ℃ for Inconel 718 Alloy

doi:10.11902/1005.4537.2022.069

Journal of Chinese Society for Corrosion and protection

2023, Vol. 43

Issue (2): 271-279 DOI: 10.11902/1005.4537.2022.069

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Oxidation Behavior in Water Vapor and Tribological Property in Atmosphere with 60%Relative Humidity at 580 ℃ for Inconel 718 Alloy

HE Nankai¹^,², WANG Yongxin¹(

), ZHOU Shengguo², ZHOU Dapeng¹, LI Jinlong¹

^1.Key Laboratory of Marine Materials and Related Technologies, Zhejiang Key Laboratory of Marine Materials and Protective Technologies, Ningbo Institute of Materials Technology and Engineering, Chinese Academy of Sciences, Ningbo 315201, China
^2.School of Materials Science and Engineering, Jiangxi University of Science and Technology, Ganzhou 341000, China

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Abstract

The oxidation behavior of Inconel 718 alloy in flowing water vapor and the wear performance in atmosphere of 60% relative humidity at 580 ℃ were investigated respectively via tubular furnace with an adjustable steam supply unit and a ball-disc type high temperature friction and wear tester. The results showed that the oxidation kinetic curves of Inconel 718 alloy in flowing water vapor at 580 ℃ followed a double linear law approximately. In comparison to those formed in dry air, the oxidation products formed in high-temperature water vapor were coarse with network-like cracks. However, the composition of oxidation products formed in water vapor and dry air were more or less the same, which all composed mainly of NiFe₂O₄ and small amount of NiO, Cr₂O₃, and Fe₂O₃. Beneath the oxide scale, a Cr-depletion region was found. On the other hand, the friction coefficient of Inconel 718 alloy decreased at 580 ℃ with the increase of friction load, while the wear rate increased gradually. The wear mechanism of Inconel 718 alloy by 2 N was mainly adhesive wear, while the wear mechanism was mainly fatigue wear and abrasive wear above 5 N.

Key words: Inconel 718 alloy pure water vapor high-temperature oxidation high-temperature friction wear mechanism

Received: 11 March 2022 32134.14.1005.4537.2022.069

ZTFLH:

TG174

Fund: National Key R&D Program of China(2020YFB2010401);Youth Innovation Promotion Association CAS(2018336)

About author: WANG Yongxin, E-mail: yxwang@nimte.ac.cn

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Cite this article:

HE Nankai, WANG Yongxin, ZHOU Shengguo, ZHOU Dapeng, LI Jinlong. Oxidation Behavior in Water Vapor and Tribological Property in Atmosphere with 60%Relative Humidity at 580 ℃ for Inconel 718 Alloy. Journal of Chinese Society for Corrosion and protection, 2023, 43(2): 271-279.

URL:

https://www.jcscp.org/EN/10.11902/1005.4537.2022.069 OR https://www.jcscp.org/EN/Y2023/V43/I2/271

Fig.1 Surface macro-morphologies (a, c) and oxidation kinetic curves (b, d) of Inconel 718 alloy oxidized for different time in dry air (a, b) and water vapor (c, d)

Fig.2 Surface (a, c, e) and cross-sectional (b, d, f) morphologies of Inconel 718 alloy before (a, b) and after oxidation for 168 h at 580 ℃ in dry air (c, d) and water vapor (e, f)

Fig.3 Cross-sectional morphologies and EDS elemental mappings of Inconel 718 alloy before (a) and after oxidation for 168 h at 580 ℃ in dry air (b) and water vapor (c)

Fig.4 Raman patterns of Inconel 718 alloy oxidized for 168 h at 580 ℃ in dry air (a) and water vapor (b)

Fig.5 Schematic diagram of the oxidation mechanism of Inconel 718 alloy in high-temperature water vapor

Fig.6 Coefficient of friction (a) and wear rate (b) of Inconel 718 alloy at different loads

Fig.7 Morphologies of wear tracks (a1-d1) and wear scars (a2-d2), 3D (a3-d3) and 2D (a4-d4) profiles of wear tracks of Inconel 718 alloy at 2 N (a1-a4); 5N (b1-b4); 8N (c1-c4); 10N (d1-d4) loads

Fig.8 Morphologies of wear tracks (a, c, e, g) and wear debris (b, d, f, h) of Inconel 718 alloy at different loads

Table 1 Distribution of primary elements on the wear track surface of Inconel 718 alloy under different loads (mass fraction / %)

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