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ELECTROCHEMICAL PERFORMANCE OF INITIAL PITTING OF 15-5PH STAINLESS STEEL |
ZHOU Xianliang1,2, NIE Lun2, HUA Xiaozhen2, LIU Zhiyong2, CUI Xia2, PENG Xinyuan2
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1. Key Laboratory of Nondestructive Test, Ministry of Education, Nanchang Hangkong University, Nanchang 330063
2. School of Materials Science and Engineering, Nanchang Hangkong University, Nanchang 330063 |
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Abstract The initial pitting behavior of 15-5PH stainless steel immersed in 6% FeCl$_{3}$ solution was investigated by electrochemical impedance spectroscopy (EIS) and scanning Kelvin probe (SKP). The results showed that the electrochemical impedance magnitude and the impedance module declined with the immersion time. One time constant appeared in EIS spectrum first then two time constant as the immersion continued. The SKP results indicated that the anodic and cathodic areas alternated constantly with distinct character of localized corrosion. When the corrosion process continued, the surface potential of 15-5PH stainless steel increased, while anodic and cathodic area distinguished evidently from each other.
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Received: 07 September 2011
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Fund: National Natural Science Foundation of China |
Corresponding Authors:
zhou xianliang
E-mail: nielun23@126.com
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