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J Chin Soc Corr Pro  1996, Vol. 16 Issue (1): 20-28    DOI:
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A COMPARATIVE INVESTIGATION OF OXIDATION PERFORMANCE OF SUPERALLOYS M17 AND M17F AT HIGH TEMPERATURES
Peng Xiao;Shen Jianian;Hu Wusheng;Yuall Keqi;Zhou Longjiang;Li Tiefan(State Key Laboratory of Corrosion and Protection; Instutite of Corrosion and Protection of Metals;Chinese Academy of Sciences; Shenyang 110015)
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Abstract  Both isothermal (at 1000℃,1050℃, 1100℃) and thermal cyclic(at 1000℃) oxidation performance of superalloys M17F and M17 in air were studied through TGA, XRD, SEM/EDAX and SEM/EPMA.The oxidation rate of M17F was much lower than that of M17, and the scale on M17F was more adhesive than that on M17. Such differences might result from the difference in the microstructure and refractory elements of the two superalloys. The irregular precipitation of γ' and/or (γ+γ')eutectic plates with higher Ti/Cr ratio resulted in rapid oxidation at the corresponding areas and thereby in the uneven scale on M17, while γ' precipitates were fine and dispersed in M17F. Furthermore, the rapid oxidation of the long strip-like MC carbides in M17 prevented the alloy from developing a protective scale. Elemental Ta in M17F brought about a Ta-rich oxide ribbon keying at the oxide scale/alloy substrate interface and thereby improved the cyclic oxidation performance of the alloy. Implanted Y+ favored the formation of a protective Cr2O3 layer in the scale and was thereby beneficial to the improvement of the oxidation-resistance of the alloy.
Key words:  High temperature oxidation      Nickel-based superalloy      Microstructure      Refractory element      Yttrium implantation     
Received:  25 February 1996     
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Peng Xiao;Shen Jianian;Hu Wusheng;Yuall Keqi;Zhou Longjiang;Li Tiefan(State Key Laboratory of Corrosion and Protection; Instutite of Corrosion and Protection of Metals;Chinese Academy of Sciences; Shenyang 110015). A COMPARATIVE INVESTIGATION OF OXIDATION PERFORMANCE OF SUPERALLOYS M17 AND M17F AT HIGH TEMPERATURES. J Chin Soc Corr Pro, 1996, 16(1): 20-28.

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https://www.jcscp.org/EN/     OR     https://www.jcscp.org/EN/Y1996/V16/I1/20

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