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Journal of Chinese Society for Corrosion and protection  2022, Vol. 42 Issue (3): 479-485    DOI: 10.11902/1005.4537.2021.110
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Effect of Polyacrylic Acid on Dispersion Characteristics of Corrosion Product Fe3O4 in Water of Power Plant and Its Mechanism
SONG Xianzhi, ZHU Zhiping(), ZHOU Pan, HE Mingpeng, JIANG Yuankang, WANG Zhenggang
Hunan Provincial Key Laboratory of Materials Protection for Electric Power and Transportation, School of Chemistry and Biological Engineering, Changsha University of Science and Technology, Changsha 410114, China
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Abstract  

The deposition of corrosion product Fe3O4 on the steam generator heat exchange tubes and supporting tube sheets is one of the main causes of corrosion accidents in the secondary circuit of nuclear power plants. Adding a dispersant can reduce the amount of corrosion product deposition. In this paper, polyacrylic acid (PAA) is selected as the dispersant, and its dispersion effect on Fe3O4 was examined in water with different concentration ratios of PAA to Fe3O4 (0, 0.01, 0.1, 1, 10) at ambient temperature for 0 and 24 h respectively. Then the effect of PAA on the dispersion characteristics of Fe3O4 was assessed via coupon test with a simulated secondary loop operating condition (autoclave), as well as the corresponding oxide scale formed on carbon steel was characterized by means of SEM with EDS. The results show that the addition of PAA will increase the absolute value of the Zeta potential of Fe3O4 and reduce the particle size of the corrosion product Fe3O4. PAA has a good dispersing effect on Fe3O4, when the concentration ratio of PAA to Fe3O4 is 0.1, the dispersion effect is the best. When the Fe3O4 concentration ratio is too large, the particle size increases and the dispersion effect decreases. With the increase of PAA concentration (0, 10 and 100 mg/L), the deposited Fe3O4 particleson the steel surfaceafter tested in autoclave are finer so that the oxide scale on carbon steel coupon was much dense and uniform. As the PAA concentration increases, the C content of oxide scale on carbon steel surface increases, indicating that PAA participates in the surface film formation process. The above results can provide certain theoretical guidance for the application of PAA in the secondary circuit of nuclear power plants.

Key words:  Fe3O4      PAA      Zeta potential      particle size      dispersion     
Received:  18 May 2021     
ZTFLH:  TG174  
Fund: Hunan Provincial Science and Technology Plan Key Project(2013GK2016);Hunan Graduate Innovation Project(CX20190700)
Corresponding Authors:  ZHU Zhiping     E-mail:  zzp8389@163.com
About author:  ZHU Zhiping, E-mail: zzp8389@163.com

Cite this article: 

SONG Xianzhi, ZHU Zhiping, ZHOU Pan, HE Mingpeng, JIANG Yuankang, WANG Zhenggang. Effect of Polyacrylic Acid on Dispersion Characteristics of Corrosion Product Fe3O4 in Water of Power Plant and Its Mechanism. Journal of Chinese Society for Corrosion and protection, 2022, 42(3): 479-485.

URL: 

https://www.jcscp.org/EN/10.11902/1005.4537.2021.110     OR     https://www.jcscp.org/EN/Y2022/V42/I3/479

Fig.1  Influence of the content of PAA on the settlement of Fe3O4 after setting for 0 h (a) and 24 h (b)
Fig.2  Transmittances of PAA/Fe3O4 mixtures with the different concentration ratios after setting for 0 h (a) and 24 h (b)
Fig.3  Zeta Potentials of the mixture systems with the different concentration ratios of PAA and Fe3O4 after setting for 0 h (a) and 24 h (b)
Fig.4  Particle sizes of PAA and Fe3O4 mixture systems with the different concentration ratios after setting for 0 h (a, b) and 24 h (c, d)
Fig.5  XRD patterns of 20 # steel after corrosion at 280 ℃ for 80 h in the simulated water with the different concentrations of PAA
Fig.6  SEM surface morphologies of 20# steel after corrosion at 280 ℃ for 80 h in the simulated water containing 0 mg/L (a), 10 mg/L (b) and 100 mg/L (c) PAA
Fig.7  Diameter distributions of oxide particles formed on 20# steel after corrosion at 280 ℃ for 80 h in the simulated water containing 0 mg/L (a) and 100 mg/L (b) PAA
Fig.8  Surface images (a, c) EDS composition analysis results (b, d) of the oxide scale formed on 20# steel after corrosion at 280 ℃ for 80 h in the simulated water containing 0 mg/L (a, b) and 100 mg/L (c, d) PAA
Fig.9  Schematic diagram of dispersion mechanism
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