Please wait a minute...
J Chin Soc Corr Pro  2012, Vol. 32 Issue (4): 311-316    DOI:
Current Issue | Archive | Adv Search |
MICROSTRUCTURE AND CORROSION RESISTANCE OF WATERBORNE Al-Zn-Si ALLOY COATING
JIANG Qiong1, MIAO Qiang1, YAO Zhengjun1, WEI Xiaoxin2
1. College of Material Science & Engineering, Nanjing University of Aeronautics and Astronautics, Nanjing 211106
2. Jiangsu Linlong New Materials Co. Ltd, Wuxi 214183
Download:  PDF(2014KB) 
Export:  BibTeX | EndNote (RIS)      
Abstract  A kind of anti-corrosive paint consisted of epoxy silane and lamellar Al-Zn-Si alloy particles was introduced in this paper. Corrosion properties of waterborne Al-Zn-Si alloy coating were tested through salt water immersion method, electrochemical method. Furthermore, the microstructure, corrosion products of the coating were detected by means of SEM, EDS and XRD. The experimental results showed that Al-Zn-Si alloy particles dispersed in coating in the form of flake structure which formed a more effective physical shield, extending the path of the corrosive medium to body; furthermore, in the corrosion processes corrosion product film formed which filled in pores of the coating and had good shielding property; Tafel curves indicated that Al-Zn-Si alloy was a good sacrificial anode material of aluminum. In addition, anti-corrosive mechanism of Al-Zn-Si alloy coating was analyzed which possessed excellent cathodic protection, and its excellent corrosion resistance was related to lamellar Al-Zn-Si alloy powder which had lower dissolution rate, inhibited the corrosion of the coating and prolonged the duration of cathodic protection.
Key words:  Al-Zn-Si alloy coating      corrosion protective coatings      salt water corrosion      cathodic protection     
Received:  28 June 2011     
ZTFLH: 

TG179

 

Cite this article: 

JIANG Qiong, MIAO Qiang, YAO Zhengjun, WEI Xiaoxin. MICROSTRUCTURE AND CORROSION RESISTANCE OF WATERBORNE Al-Zn-Si ALLOY COATING. J Chin Soc Corr Pro, 2012, 32(4): 311-316.

URL: 

https://www.jcscp.org/EN/     OR     https://www.jcscp.org/EN/Y2012/V32/I4/311

[1] Zhang H B. Corrosion resistance of the hot dip 55% aluminum-zinc-1.6%silicon alloy coatings on steel [J]. J. Shanghai Jiaotong Univ., 1998, 32(9): 121-125

    (张洪斌. 55%铝-锌-1.6%硅合金镀层的耐蚀性能[J].上海交通大学学报, 1998, 32(9): 121-125)

[2] Guo Y Q. An investigation on the corrosion behavior of 55%Al-Zn-1.6%Si alloy coating in ammonia water [J]. Dev. Appl. Mater., 2003, 18(2): 25-27

    (郭永强. 热浸55%Al-Zn-1.6%Si合金镀层在氨水中的腐蚀行为研究[J].材料开发与应用, 2003, 18(2): 25-27)

[3] Zhang H B, Huang Y C, Pan J W, et al. Crevice corrosion of Al-1.6%Si coating and 55%Al-Zn-1.6%Si alloy coating [J]. Chlor-alkali Ind., 1996,(5): 12-15

    (张洪斌, 黄永昌, 潘健武等. Al-1.6%Si镀层和55%Al-Zn-1.6%Si合金镀层的缝隙腐蚀 [J]. 氯碱工业, 1996, (5): 12-15)

[4] Wen G N, Liu X B. Electrochemical behaviour and corrosion resistance of zinc based coating [J]. Mater. Prot., 1998, 31(2): 8-9

    (文光男, 刘希柏. 锌基涂层的电化学行为及防蚀机理 [J]. 材料保护, 1998, 31(2): 8-9)

[5] Liu K R, Ma P C, Pu N W, et al. Influence of silicon coating on the corrosion resistance of Zn-Al-Mg-RE-Si alloy [J]. J. Rare Earths, 2010, 28(Suppl.): 378-381

[6] Li C L. Preparation of Zn-Al pseudo alloy coatings and their corrosion resistance in marine environment [D]. Beijing: China University of Petroleum, 2010

    (李春玲. Zn-Al伪合金涂层的制备及耐海洋腐蚀性能研究[D]. 北京: 中国石油大学, 2010)

[7] Li J, Laufer E E, Masounave J. Wear in Zn-Al-Si alloys [J]. Wear, 1993, 165(1): 51-56

[8] Xiao Y D, Fu Z Y, Zhu P, et al. Study on corrosion resistance of spray Zn85Al alloy coating for steel construction [J]. Therm. Spray Technol., 2010, 2(2): 19-25

    (萧以德, 付志勇, 朱鹏等. 热喷涂锌-铝合金涂层对钢结构防护性能研究 [J]. 热喷涂技术, 2010, 2(2): 19-25)

[9] Zhang H B. A New heavy duty anticorrosive coating-Zn-Al alloy flake coating [J]. Chlor-alkali Ind., 1998, (6): 26-29

    (张洪斌. 新型重防腐蚀涂料-锌铝合金鳞片涂料[J]. 氯碱工业, 1998,(6): 26-29)

[10] Hernandez M, Genesca J, Uruchurtu J, et al. Effect of an inhibitive pigment zinc-aluminum-phosphate (ZAP) on the corrosion mechanisms of steel in wa-terborne coatings [J]. Prog. Org. Coat., 2006, 56(2-3): 199-206

[11] Vesely D, Kalendova A. Anticorrosion efficiency of ZnxMgyAl2O4 core-shell spinels in organic coatings [J]. Prog. Org. Coat., 2008, 62(1): 5-20

[12] Cong S H, Yang H L, Wang X C, et al. Salt spray corrosion properties of the paint coatings rich in Zn-Al-Mg-Ce alloy powders [J]. J. Wuhan Univ. Sci. Technol., 2009, 32(3): 242-246

     (从善海, 杨洪林, 汪旭超等. 富Zn-Al-Mg-Ce合金油漆涂层的盐雾腐蚀性能研究 [J]. 武汉科技大学学报, 2009, 32(3): 242-246)

[13] Cong S H, Hou Q. Corrosion resistance performance of epoxy Zn-Al-Mg-Ce riched alloy coating [J]. Chin. Surf. Eng., 2010, 23(1): 109-112

     (从善海, 侯强. 环氧富Zn-Al-Mg-Ce合金涂层耐腐蚀性能 [J]. 中国表面工程, 2010, 23(1): 109-112)

[14] JB/T10619-2006, Specification for chromium-free zinc-aluminum coating[S].

     (JB/T10619-2006, 无铬锌铝涂层技术条件[S].)

[15] Xie D M, Hu J M, Tong S P, et al. Influence of zinc content and surface contamination on the electrochemical behaviors of epoxy zinc-rich primer [J]. Acta Metall. Sin., 2004, 40(1): 103-108

     (谢德明, 胡吉明, 童少平等. Zn粉含量及表面沾污对环氧富Zn漆电化学行为的影响[J]. 金属学报, 2004, 40(1): 103-108)

[16] Han S M, Zheng Y Z, Yu S X, et al. Corrosion prevention characteristics and mechanism of zinc-aluminum-chromium coating [J]. Chin. J. Nonferrous Met., 2002, 12(3): 619-623

     (韩树民, 郑炀曾, 于学升等. 锌铝铬膜的防腐性能与机理[J]. 中国有色金属学报, 2002, 12(3): 619-623)

[17] Li M X. Study and design of sacrificial anodes and cathodic protection system on marine ship [J]. Equip. Manuf. Technol., 2007, (8): 31-34

     (李明昕. 船舶牺牲阳极的阴极保护设计研究[J]. 装备制造技术,2007, (7): 31-34)

[18] Marder A R. The metallurgy of zinc coated steel [J]. Prog. Mater. Sci., 2000, 45(3): 191-271

[19] Chen B K, Yuan X H,Zhang Q F. Coating structure and anti-corrosion mechanism of hot dipped 55%Al-Zn alloy on sheet steel [J]. Corros. Prot., 2009, 30(1): 16-21

     (陈斌瑎, 袁训华, 张启富. 热浸镀55%Al-Zn合金镀层钢板的镀层结构及防腐蚀机理 [J]. 腐蚀与防护, 2009, 30(1): 16-21)

[20] Yang Z B, Yang Z L, Guo W S, et al. Study on the anticorrosion mechanism of flake zinc-rich coatings film [J]. Chin. Coat., 2006, 21(1): 19-21

     (杨振波, 杨忠林, 郭万生等. 鳞片状富锌涂层耐蚀机理的研究[J].中国涂料, 2006, 21(1): 19-21)

[21] Zhang J, Yu Z H, Li Y. Corrosion behavior of hot-dipped Zn-55%Al-Si coated steel wires in seawater [J]. Chin. J. Mater. Res., 2008, 22 (4): 347-352

     (张杰, 于振花, 李焰. Zn-55%A1-Si合金镀层钢丝在海水中的耐蚀性能[J]. 材料研究学报, 2008, 22 (4): 347-352)

[22] Han F J, Zhou Y M, Wang X Z. Preparation of anticorrosive coating with lamellar zinc particles [J]. Corros. Prot., 2006, 27(3): 109-112

     (韩风俊, 周钰明, 汪小舟. 鳞片状锌粉防腐蚀涂料的研制 [J]. 腐蚀与防护. 2006.3, 27(3): 109-112)

[23] He J B, Lu D R, Li X L, et al. Investigation on corrosion kinetics behavior of dacromet coating [J]. Chem. Res. Appl., 2002, 14(1): 81-83

     (何建波, 鲁道荣, 李学良等. 达克罗涂层的腐蚀动力学行为研究[J]. 化学研究与应用. 2002, 14(1): 81-83)
[1] DAI Mingjie, LIU Jing, HUANG Feng, HU Qian, LI Shuang. Pitting Corrosion Behavior of X100 Pipeline Steel in a Simulated Acidic Soil Solution under Fluctuated Cathodic Protection Potentials Based on Orthogonal Method[J]. 中国腐蚀与防护学报, 2020, 40(5): 425-431.
[2] LIANG Yi, DU Yanxia. Research Progress on Evaluation Criteria and Mechanism of Corrosion Under Cathodic Protection and AC Interference[J]. 中国腐蚀与防护学报, 2020, 40(3): 215-222.
[3] ZHAO Shuyan,TONG Xinhong,LIU Fuchun,WENG Jinyu,HAN En-Hou,LI Xiaohui,YANG Lin. Corrosion Resistance of Three Zinc-rich Epoxy Coatings[J]. 中国腐蚀与防护学报, 2019, 39(6): 563-570.
[4] Guirong WANG,Yawei SHAO,Yanqiu WANG,Guozhe MENG,Bin LIU. Effect of Applied Cathodic Protection Potential on Cathodic Delamination of Damaged Epoxy Coating[J]. 中国腐蚀与防护学报, 2019, 39(3): 235-244.
[5] Ping QIU, Lianjie YANG, Yu SONG, Hongfei YANG. Influence of DMF Modified TiO2 Film on the Photogenerated Cathodic Protection Behavior[J]. 中国腐蚀与防护学报, 2018, 38(3): 289-295.
[6] Jie KOU, Xince ZHANG, Gan CUI, Baoan YANG. Research Progress on Cathodic Protection Potential Distribution of Tank Bottom Plate[J]. 中国腐蚀与防护学报, 2017, 37(4): 305-314.
[7] Xiaolin WANG, Maocheng YAN, Yun SHU, Cheng SUN, Wei KE. AC Interference Corrosion of Pipeline Steel Beneath Delaminated Coating with Holiday[J]. 中国腐蚀与防护学报, 2017, 37(4): 341-346.
[8] Tingyong WANG,Lanying MA,Xiangchen WANG,Haibing ZHANG,Kai CHEN,Yonggui YAN. Investigation of Cathodic Protection Parameters of Candi-date Materials of Condenser for a Nuclear Power Station and Its Application in Seawater[J]. 中国腐蚀与防护学报, 2016, 36(6): 624-630.
[9] Shuang YANG,Nan TANG,Maocheng YAN,Kangwen ZHAO,Cheng SUN,Jin XU,Changkun YU. Effect of Temperature on Corrosion Behavior of X80 Pipeline Steel in Acidic Soil[J]. 中国腐蚀与防护学报, 2015, 35(3): 227-232.
[10] XU Hongmei, LIU Wei, CAO Lixin, SU Ge, GAO Rongjie. Preparation of ZnO/TiO2 Composite Film on 304 Stainless Steel and Its Photo-cathodic Protection Properties[J]. 中国腐蚀与防护学报, 2014, 34(6): 507-514.
[11] FAN Fengqin, SONG Jiwen, LI Chengjie, DU Min. Effect of Flow Velocity on Cathodic Protection of DH36 Steel in Seawater[J]. 中国腐蚀与防护学报, 2014, 34(6): 550-557.
[12] QIU Jing, DU Min, LU Yuan, ZHANG Ying, GUO Haijun, LI Chengjie. Cathodic Protection of X65 Carbon Steel in a Simulated Oilfield Produced Water[J]. 中国腐蚀与防护学报, 2014, 34(4): 333-338.
[13] LIN Yonghua,ZHANG Xuefeng,HAN Li,ZHANG Lanhe. Comparison of Corrosion Protection Measures of Grounding Grids for Electric Power Station[J]. 中国腐蚀与防护学报, 2013, 33(6): 501-506.
[14] ZHU Junmou,YAO Zhengjun,JIANG Qiong,WEI Dongbo,YIN Guoxian,
LUO Xixi,ZHOU Wenbin. Microstructure and Corrosion Resistance of Cr-free Nanocomposite Zn/Al Coatings[J]. 中国腐蚀与防护学报, 2013, 33(5): 425-429.
[15] WEN Lijuan,GAO Zhiming,LIU Yangyang,LIN Feng. Effects of Applied Cathodic Potential on Susceptibility to Hydrogen Embrittlement and Mechanical Properties of Q235 Steel[J]. 中国腐蚀与防护学报, 2013, 33(4): 271-276.
No Suggested Reading articles found!