|
|
EFFECTS OF IMMERSION TIME ON THE RESISTIVITY OF COAL TAR MODIFIED EPOXY COATINGS WITH DIFFERENT CONTENT OF TITANIUM POWDER |
;; |
太原科技大学 |
|
|
Abstract The effects of different amounts of titanium powder (200 mesh), used as additive, on the resistivity of the coating of coal tar epoxy resin cured with polyamine in distilled aqueous 3.5%(mass%) sodium chloride so-lution has been studied by electrochemical impedance spectroscopy (EIS). The influencing factors of the resis-tivity were discussed, and the variation of the resistivity was also studied by calculating permittivity for the coat-ings herewith. Analysis of the electrochemical impedance spectra of the coating as a function of titanium content and immersion time showed that for short immersion times (half an hour) the resistivity was increased when the titanium content was decreased and that for long immersion times (192 hours) the reverse was the case.
|
Received: 25 September 2005
|
|
[1]Kouloumbi N,Tsangaris G M,Kyvelidis S T.Evaluation of corro-sion behavior of metal-filled polymeric coatings[J].J.Coat.Tech-nol.,1994,26(828):83-88 [2]Kouloumbi N,Tsangaris G M,Skordos A,Kyvelidis S.Evaluation of the behaviour of particulate polymeric coatings in a corrosive en-vironment influence of the concentration of metal particles[J].Prog.Org.Coat.,1996,28(6):117-124 [3]Selvaraj M,Guruviah S.Optimisation of metallic pigments in coat-ings by an electrochemical technique and an investigation of man-ganese powder as pigment for metal rich primers[J].Prog.Org.Coat.,1996,28(4):271-277 [4]Cao C N,Zhang J Q.An Introducton to Electrochemical Impedance Spectroscope[M].Beijing:Science Press,2002(曹楚南,张鉴清.电化学交流阻抗谱导论[M].北京:科学出版社,2002) [5]Beiro M,Collazo A,Izquierdo M,et al.Characterisation of barrier properties of organic paints:the zinc phosphate effectiveness[J].Prog.Org.Coat.,2003,46(2):97-106 [6]Castela A S,Sim%es A M.Water sorption in freestanding PVC films by capacitance measurement[J].Prog.Org.Coat.,2003,46(2):130-134 [7]Perez C,Collazo A,Izquierdo M,Merino P,Novoa X R.Charac-terisation of the barrier properties of different paint systems partⅠ.Experimental set-up and ideal Fickian diffusion[J].Prog.Org.Coat.,1999,36(1-2):102-108 [8]Liu B,Li Y,Lin H,Cao C N.Electrochemical impedance spec-troscopy study on the diffusion behavior of water through epoxy coatings[J].Corrosion,2003,59(9):817-820 [9]Van Westing E P M,Ferrari G M,de Wrr G H W.The determina-tion of coating performance with impedance measurements-Ⅱ.Wa-ter uptake of coatings[J].Corros.Sci.,1993,35(5):957-977 [10]Bellucci F,Nicodemo L,Monetta T,Kloppers M J,Latanision R M.A study of corrosion initiation on polyimide coatings[J].Corros.Sci.,1992,33(8):1203-1226 [11]Bellucci F,Nicodemo L.Water transport in organic coatings[J].Corrosion,1993,49(3):235-247 |
No Suggested Reading articles found! |
|
|
Viewed |
|
|
|
Full text
|
|
|
|
|
Abstract
|
|
|
|
|
Cited |
|
|
|
|
|
Shared |
|
|
|
|
|
Discussed |
|
|
|
|