Research on Corrosive Mechanism of Lead-Tin Based Alloy Cultural Relics of Warring States in Hubei Province

J Chin Soc Corr Pro

2007, Vol. 27

Issue (3): 162-166 DOI:

Research Report

Current Issue | Archive | Adv Search

Research on Corrosive Mechanism of Lead-Tin Based Alloy Cultural Relics of Warring States in Hubei Province

;;;

中国科学技术大学科技史与科技考古系

Cite this article:

;. Research on Corrosive Mechanism of Lead-Tin Based Alloy Cultural Relics of Warring States in Hubei Province. J Chin Soc Corr Pro, 2007, 27(3): 162-166 .

Download:

PDF(283KB)
Export: BibTeX | EndNote (RIS)

Abstract The alloys and corrosion products of the Pb - Sn alloy solders, existing in bronxes excavated from Jiuliandu site during Warring States Period, were analyzed by using techniques of energy spectrum, X- ray powder diffraction, X - ray fluorescence spectrometry and metallurgical analysis , etc. The analysis indicated that corrosive products that were composed of PbCO3, Pb and SnO2 were compact and firm, and the buried circumstance, with the neutral pH and the high content of HCO3-,was relatively isolated, which had cooperated to hinder the corrosion of Pb - Sn solders to keep bronzes in good figure.

Key words: Metallic cultural relics soil corrosion Pb-Sn alloy Pb corrosion Sn corrosion

Received: 12 December 2005

ZTFLH:

TG146.1+2

	Service

	E-mail this article
	Add to citation manager
	E-mail Alert
	RSS
	（）
	Articles by authors

URL:

https://www.jcscp.org/EN/ OR https://www.jcscp.org/EN/Y2007/V27/I3/162

[1]Li HX,Li Y D,Zhang S Q,Gao Y.Research on rusts of lead cablesunder soil corrosion[J].Corros.Sci.Prot.Technol.,1992,4(2):117-119(李洪锡,银耀德,张淑泉,高英.铅电缆土壤腐蚀产物研究[J].腐蚀科学与防腐技术,1992,4(2):117-119)
[2]Lu Y K.Surface corrosion kinetics of the solid lead,tin and their al-loy[J].J.University of Science and Technology Beijing,1991,13(5):493-497(鲁永奎.固态铅、锡及其铅锡焊料表面腐蚀动力学[J].北京科技大学学报,1991,13(5):493-497)
[3]K S S,V S S,ME,et al.Water contamination:impact of tin-leadsolder[J].Wat.Res.,1995,29(8):1827-1836
[4]Wang C S,Lu B,Zuo J,et al.Structural and elemental analysis onthe nanocrystalline SnO2in the surface of ancient Chinese black mir-rors[J].Nanostructured Materials,1995,5(4):486-496
[5]S H,K S,J C H.Quantitative determination of cerussite(lead car-bonate)by X-ray powder diffraction and inferences for lead specia-tion and transport in streamsediments froma former lead mining areain Scotland[J].Appl.Geochemistry,2001(16):597-608
[6]Yao W Y,Peng K,Tang MK,et al.Corrosion mechanism of lead in-got[J].J.Cent.South Univ.,(Natural Science)2004,35(1):54-58(姚维义,彭可,唐谟堂等.铅锭白锈形成机理[J].中南大学学报(自然科学版),2004,35(1):54-58)
[7]Xu P D,Zhao X P,Ya Y.Influence of Sn on electrochemical behav-ior of lead alloy electrodes in sulfuric acid[J].Battery Industry,1999,3(5):165-166(徐品弟,赵小佩,夏晔.锡对铅合金电极在硫酸溶液中的电化学行为影响的研究[J].电池工业,1999,3(5):165-166)
[8]Herrera-Urbina R,et al.The effect of Pb(II)species,pH anddissolved carbonate on the zeta potential at the quartz aqueous solu-tion interface[J].Colloids and Surfaces A:Physicochem.Eng.As-pects,1995,(98):25-33
[9]Xia Z D,Mu N,Shi YW.Corrosion behavior of tin-zinc based alloysolder[J].Corros.Sci.Prot.Technol.,2003,23(4):234-238(夏志东,穆南,史耀武.锡锌钎料的腐蚀行为[J].腐蚀科学与防护技术,2003,23(4):234-238)
[10]Lu Y H,Wang Y H,Wang J.Research on corrosive behavior of Pbunder acid soil[J].Modern Lineate Transmission,2002(2):14-17(鹿中晖,王永红,文杰.铅在酸性土壤中的腐蚀行为研究[J].现代有线传输,2002(2):14-17)
[11]S H,MA.Effects of temperature and r.f.power sputtering on elec-trical and optical properties of SnO2[J].Appl.Energy.,2000,(65):19-28
[12]Wang YH,Lu Z H,Li YZ.Research on corrosion behavior of cable'metal materials in soil[J].Modern Cable Transmission,2004,(4):79-83(王永红,鹿中晖,李英志.线缆金属材料在土壤中腐蚀行为研究[J].现代有线传输,2004,(4):79-83)
[13]Wang Y H,Wen J,Lu Y H.Research on accelerated corrosive ex-periment of Pb、Al by anions in the soil[J].Modern Lineate Trans-mission,2000,(2):28-30(王永红,文杰,鹿中晖.土壤中阴离子对铅、铝腐蚀的加速试验研究[J].现代有线传输,2000,(2):28-30)

[1]	HUANG Hulingtong, WANG Cheng, CHENG Xuequn, YANG Xiaojia, ZHANG Zhanwu, LI Liang. Corrosion Behavior of Q235 Carbon Steel in a Simulated Saline Soil of Southern Xinjiang[J]. 中国腐蚀与防护学报, 2026, 46(5): 1595-1604.
[2]	LU Yiliang, ZHANG Qiang, JIN Yan, CHEN Yun, YANG Bingkun, WANG Xiaofang, HAN Yu. Effect of Cl^--amount on Corrosion Behavior of Cu in Simulated Leaching Solutions of Soil at Korla District of Xinjiang[J]. 中国腐蚀与防护学报, 2026, 46(5): 1605-1612.
[3]	LIU Chenhui, LIU Guangming, ZHU Yanbin, LU Yiliang, ZHANG Lingling, HUANG Zebang. Corrosion Behavior of Pure Zinc in Simulated Underground Seawater Infiltrated Saline-alkali Soils[J]. 中国腐蚀与防护学报, 2026, 46(3): 864-874.
[4]	WANG Gang, LI Zhao, WANG Tao, DUAN Teng, DU Cuiwei. Corrosion Behavior in Soil of Xinjiang of Steels for Photovoltaic Pile Foundation[J]. 中国腐蚀与防护学报, 2024, 44(4): 987-992.
[5]	DAI Wei, LIU Yuanyuan, TU Wenrui, SUN Yangting, LI Jin, JIANG Yiming. Corrosion Behavior of Ag/Sn Galvanic Couple at Applied Potential[J]. 中国腐蚀与防护学报, 2024, 44(3): 700-706.
[6]	LI Wenjie, CHE Xiaoyu, TANG Yongcun, LIU Guangming, TIAN Wenming, HE Hualin, LIU Chenhui. Effect of Plastic Deformation Processing on Corrosion Behavior of Pure Zinc in a Leaching Solution of Soil at Tianjin[J]. 中国腐蚀与防护学报, 2024, 44(2): 497-504.
[7]	BIAN Yafei, TANG Wenming, ZHANG Jie, MAO Ruirui, MIAO Chunhui, CHEN Guohong. Soil Corrosion Characteristics of Q235 Steel Grounding Material Used in Power Grid in Anhui Province[J]. 中国腐蚀与防护学报, 2024, 44(1): 130-140.
[8]	GAO Yibin, DU Xiaogang, WANG Qiwei, ZHONG Liming, FU Wenhua, ZHANG Hanping, ZHANG Meng, JIANG Chunhai. Corrosion Behavior of Copper in a Simulated Grounding Condition in Electric Power Grid[J]. 中国腐蚀与防护学报, 2023, 43(2): 435-440.
[9]	DING Cong, ZHANG Jinling, YU Yanchong, LI Yelei, WANG Shebin. Corrosion Kinetics of A572Gr.65 Steel in Different Simulated Soil Solutions[J]. 中国腐蚀与防护学报, 2022, 42(1): 149-155.
[10]	TANG Rongmao, ZHU Yichen, LIU Guangming, LIU Yongqiang, LIU Xin, PEI Feng. Gray Correlative Degree Analysis of Q235 Steel/conductive Concrete Corrosion in Three Typical Soil Environments[J]. 中国腐蚀与防护学报, 2021, 41(1): 110-116.
[11]	ZHU Yichen,LIU Guangming,LIU Xin,PEI Feng,TIAN Xu,SHI Chao. Investigation on Interrelation of Field Corrosion Test and Accelerated Corrosion Test of Grounding Materials in Red Soil Environment[J]. 中国腐蚀与防护学报, 2019, 39(6): 550-556.
[12]	Libao YU, Maocheng YAN, Binbin WANG, Yun SHU, Jin XU, Cheng SUN. Microbial Corrosion of Q235 Steel in Acidic Red Soil Environment[J]. 中国腐蚀与防护学报, 2018, 38(1): 10-17.
[13]	Tao HUANG,Xiaoping CHEN,Xiangdong WANG,Fengyi MI,Rui LIU,Xiangyang LI. Effect of pH Value on Corrosion Behavior of Q235 Steel in an Artificial Soil[J]. 中国腐蚀与防护学报, 2016, 36(1): 31-38.
[14]	YAO Huiping, YAN Maocheng, YANG Xu, SUN Cheng. Electrochemical Behavior of X80 Pipeline Steel in the Initial Stage of Corrosion in an Acidic Red Soil[J]. 中国腐蚀与防护学报, 2014, 34(5): 472-476.
[15]	NIE Xianghui, LI Xiaogang, LI Yunlong, LI Jike, ZHANG Hongbo. ACCELERATION RATIOS AND DYNAMIC CORRELATION EXPERIMENTS ON THE CORROSION LOSS OF Q235 STEEL IN SEASHORE SOIL[J]. 中国腐蚀与防护学报, 2011, 31(3): 208-213.

No Suggested Reading articles found!

Viewed

Full text

Abstract

Cited

Shared

Discussed