STUDY ON THE BEHAVIOR OF ELECTROPLATING Zn-Fe-P ALLOY

J Chin Soc Corr Pro

2001, Vol. 21

Issue (5): 280-285 DOI:

Research Report

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STUDY ON THE BEHAVIOR OF ELECTROPLATING Zn-Fe-P ALLOY

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浙江大学玉泉求是村留博楼2005#

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Abstract A new formula containing H3PO3 as phosphorus so urce of Zn-Fe-P electrodeposits was reported.The results showed that the content s of the phosphorus and the iron in the electrodeposits change synchronously.The electrochemical behavior of H3PO3 and Fe2+ in the electroplating solu tion has been investigated by cyclic voltammetry, it was shown that they promote s the reduction of each other and which has been studied in the view of quantum chemistry firstly.The theoretical results showed that, because the orbit radius of 4s of Fe is shorter than that of Zn, the overlapping integral of iron and pho sphorus(sFe-P) is smaller than that of zinc and phosphorus(sZn-P) wh ich results in the synchronous variation of the contents of the phosphorus and t he iron in the electrodeposits, and which also showed that the cooperative effec t of phosphorus and iron series metal.

Key words: Zn-Fe-P alloy electroplating behavior quantum chemistr y

Received: 02 August 2000

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. STUDY ON THE BEHAVIOR OF ELECTROPLATING Zn-Fe-P ALLOY. J Chin Soc Corr Pro, 2001, 21(5): 280-285 .

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https://www.jcscp.org/EN/ OR https://www.jcscp.org/EN/Y2001/V21/I5/280

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