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THE INHOMOGENEITY OF CORROSION POTENTIALS DISTRIBUTION WITH RUST PREVENTIVE OIL FILM |
Qingdong Zhong;Qiaomin Xie;Guoding Zhou |
上海市上海电力学院电化学室 |
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Abstract Theoretical analysis of inhomogeneity of corrosion poten tials with rust preventive oil film and conformity to discontinuous binomial dis t ribution is described.This paper is on the basis of Bailey and Ritchie's general electrochemical theory for the oxidation of metals.In general electrochemical t heory,oxidizing metal is viewed as a self-driving electrochemical cell in which the oxide acts as both ionic and electronic conductor.It is pointed out that the ory analysis results are coincident with experimental measurements.There exist t w o kinds of film in the rust preventive oil film,ionic film and electronic film,w hich lead to inhomogeneous corrosion potentials distribution on metal surface an d discontinuous binomial distribution.
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Received: 11 May 2000
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Corresponding Authors:
Qingdong Zhong
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