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ON THE MEASUREMENT OF DIFFER ENTIAL POLARIZATION RESISTANCE |
Cao Chunan Song Shizhe~* and Wang You(Institute of Corrosion and Protection of Metals; Academia Sinica) (* Department of Materials; Tianjin University) |
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Abstract The difficulties encountered in Linear Polarization Resistance(LPR) measurements are discussed. A method for determining Differential Polarization Resistance(DPR) is proposed, Its principle is explained, and a DPR measuring device based on this principle is set up. By this technique, the theoretical errors arising from linearizing approximation in LPR measuring techniques will not exist, and other problems encountered in LPR measuring techniques such as how to choose measuring frequency and polarization value properly for a given corroding metallic electrode system will disappear. The effect of nonfaradaic current on results measured may be ignored by this measuring technique, so it is possible to perform the measurement rather rapidly and thus to trace the corrosion potential closely. The DPRs as measured by this technique have been compared with the theoretical PRs and LPRs obtained from polarization curves for Fe in 4 different solutions.
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Received: 25 August 1986
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Cite this article:
Cao Chunan Song Shizhe~* and Wang You(Institute of Corrosion and Protection of Metals; Academia Sinica) (* Department of Materials; Tianjin University). ON THE MEASUREMENT OF DIFFER ENTIAL POLARIZATION RESISTANCE. J Chin Soc Corr Pro, 1986, 6(4): 264-272.
URL:
https://www.jcscp.org/EN/ OR https://www.jcscp.org/EN/Y1986/V6/I4/264
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[1] Stern, M.; Geary, A. L., J. Electochem. Soc., 104, 56(1957) [2] Cao Chunan, Corrosion Science, 22, 205(1982) [3] Prazak, M.; Barton, K., Corrosion Science, 7, 159(1967) [4] Neufeld, P.; Queenan, E. D., Brit. Corros. Journ, 5(2) , 72(1970) [5] 曹楚南,关于测定腐蚀速度的电化学方法中的若干问题,中国腐蚀与防护学会成立大会学术报告,(1979) [6] 曹楚南,腐蚀电化学原理,化学工业出版社,(1986) [7] Mansfeld, F., Corrosion, 32; 143(1976) [8] 曹楚南,中国腐蚀与防护学报,5(3) ,(1985) |
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