H2 中O2 和CO掺杂对X52管线钢氢脆敏感性影响研究

doi:10.11902/1005.4537.2024.159

中国腐蚀与防护学报

2025, Vol. 45

Issue (2): 371-380 CSTR: 32134.14.1005.4537.2024.159 DOI: 10.11902/1005.4537.2024.159

临氢关键材料服役行为研究专刊

本期目录 | 过刊浏览

H₂ 中O₂ 和CO掺杂对X52管线钢氢脆敏感性影响研究

万红江¹^,², 明洪亮¹^,²(

), 王俭秋¹, 韩恩厚¹^,³

^1.中国科学院金属研究所沈阳 110016
^2.中国科学技术大学材料科学与工程学院沈阳 110016
^3.广东腐蚀科学与技术创新研究院广州 510530

Effect of Small Amount of O₂ and CO on Hydrogen Embrittlement Susceptibility of X52 Pipeline Steel

WAN Hongjiang¹^,², MING Hongliang¹^,²(

), WANG Jianqiu¹, HAN En-Hou¹^,³

^1.Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016, China
^2.School of Materials Science and Engineering, University of Science and Technology of China, Shenyang 110016, China
^3.Institute of Corrosion Science and Technology, Guangzhou 510530, China

引用本文:

万红江, 明洪亮, 王俭秋, 韩恩厚. H₂ 中O₂ 和CO掺杂对X52管线钢氢脆敏感性影响研究[J]. 中国腐蚀与防护学报, 2025, 45(2): 371-380.
Hongjiang WAN, Hongliang MING, Jianqiu WANG, En-Hou HAN. Effect of Small Amount of O₂ and CO on Hydrogen Embrittlement Susceptibility of X52 Pipeline Steel[J]. Journal of Chinese Society for Corrosion and protection, 2025, 45(2): 371-380.

全文: PDF(33701 KB) HTML

摘要:

通过慢应变速率拉伸实验研究了纯氢气体中O₂和CO含量对X52管线钢氢脆敏感性的影响，并采用扫描电子显微镜对试样的断口进行了观察。结果表明，X52管线钢的氢脆敏感性随H₂中O₂和CO含量的增大而降低，当H₂中O₂体积分数为0.01%或CO体积分数为0.02%时，X52管线钢的氢脆敏感性指数分别为0.83%和8.11%，仅分别为纯氢环境下的3.96%和38.66%。O₂和CO与H₂在金属表面的竞争吸附是导致管线钢氢脆敏感性降低的根本原因。

关键词 ： X52管线钢, 氢脆, O₂, CO, 竞争吸附

Abstract：

The effect of small injected amount of O₂ and CO on the hydrogen embrittlement susceptibility of X52 pipeline steel in pure gaseous hydrogen was investigated by slow strain rate tensile tests, while the fracture of the tested steel was characterized by scanning electron microscope. Results reveal that the hydrogen embrittlement susceptibility of X52 pipeline steel decreases with the increase of the injected amount of O₂ and CO in the gaseous hydrogen. For the gaseous hydrogen with either 0.01% (volume fraction) O₂ or 0.02% (volume fraction) CO, the acquired hydrogen embrittlement index of X52 pipeline steel is 0.83% and 8.11%, which correspond to 3.96% and 38.66% those in pure gaseous hydrogen, respectively. It follows that the competitive adsorption of O₂ and CO with the presence of H₂ leads to the reduction of hydrogen embrittlement sensitivity of the pipeline steel.

Key words： X52 pipeline steel hydrogen embrittlement O₂ CO competitive adsorption

收稿日期: 2024-05-21 32134.14.1005.4537.2024.159

ZTFLH:

TG172

基金资助:国家重点研发计划(2021YFB4001601);中国科学院青年创新促进会(2022187)

通讯作者: 明洪亮，E-mail：hlming12s@imr.ac.cn，研究方向为材料力学化学交互作用

Corresponding author: MING Hongliang, E-mail: hlming12s@imr.ac.cn

作者简介: 万红江，男，1999年生，硕士生

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https://www.jcscp.org/CN/10.11902/1005.4537.2024.159 或 https://www.jcscp.org/CN/Y2025/V45/I2/371

图1 管状试样尺寸图

表1 不同O2和CO含量H2中拉伸实验条件

图2 X52管线钢的金相组织

图3 在掺入不同含量O2的H2气氛中试样的工程应力-应变曲线

图4 在掺入不同含量O2的H2气氛中试样的拉伸数据和氢脆敏感性指数

图5 在掺入不同含量O2的H2气氛中试样的拉伸断口整体形貌

图6 在掺入0.001%O2的H2气氛中试样断口形貌

图7 在掺入0.005%O2的H2气氛中试样断口形貌

图8 在掺入0.01%O2的H2气氛中试样断口形貌

图9 在掺入不同含量CO的H2中试样的工程应力-应变曲线

图10 在掺入不同含量CO的H2中试样的拉伸数据和氢脆敏感性指数

图11 在掺入不同含量CO的H2中试样的断口形貌

图12 在掺入0.005%CO的H2气氛中试样断口形貌

图13 在掺入0.01%CO的H2气氛中试样断口形貌

图14 在掺入0.02%CO的H2气氛中试样断口形貌

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