铁细菌对L245钢腐蚀行为的影响研究

doi:10.11902/1005.4537.2020.105

中国腐蚀与防护学报

2021, Vol. 41

Issue (2): 248-254 DOI: 10.11902/1005.4537.2020.105

研究报告

本期目录 | 过刊浏览

铁细菌对L245钢腐蚀行为的影响研究

王坤泰, 陈馥(

), 李环, 罗米娜, 贺杰, 廖子涵

西南石油大学化学化工学院成都 610500

Corrosion Behavior of L245 Pipeline Steel in Shale Gas Fracturing Produced Water Containing Iron Bacteria

WANG Kuntai, CHEN Fu(

), LI Huan, LUO Mina, HE Jie, LIAO Zihan

School of Chemical Engineering, Southwest University of Petroleum, Chengdu 610500, China

全文: PDF(4401 KB) HTML

摘要:

采用挂片、电化学实验和SEM等手段研究了L245钢在含有铁细菌 (FB) 的页岩气压裂产出水中的腐蚀行为。结果表明：有、无FB压裂产出水都会对L245钢造成腐蚀，但失重分析和极化曲线分析都证明FB的存在促进了L245钢的腐蚀；电化学阻抗拟合结果表明，在不含FB的页岩气压裂产出水中，L245钢的腐蚀速率在前5 d逐渐增大，后快速减小。在含有FB的页岩气压裂产出水中，L245钢的腐蚀速率先减小，至8 d后逐渐增大。SEM分析结果表明，两种体系生成了不同的腐蚀产物膜。

关键词 ： L245钢, 铁细菌, 电化学, 微生物腐蚀, 页岩气压裂产出水

Abstract：

To provide theoretical reference for the corrosion protection engineering of metallic facilities in the water treatment process of shale gas fracturing produced water, the corrosion behavior of L245 steel induced by iron bacteria (FB) in shale gas fracturing produced water was studied by means of immersion test with mass loss measurement, electrochemical test and SEM characterization. Results showed that both of the shale gas fracturing produced waters with and without iron bacteria could all cause corrosion of L245 steel, but mass loss analysis and polarization curve analysis proved that the presence of FB promotes the corrosion of L245 steel. Further, the electrochemical impedance fitting results showed that in the shale gas fracturing produced water without FB, the corrosion rate of L245 steel increased slowly in the first 5 d, and then rapidly decreased. Whereas, in the shale gas fracturing produced water containing FB, the corrosion rate of L245 steel first decreased untill 8 d and then increased rapidly. SEM analysis results showed that the formed corrosion product films are quite different in the shale gas fracturing produced waters with and without iron bacteria.

Key words： L245 steel iron bacteria electrochemistry microbiologically influenced corrosion shale gas fracturing produced water

收稿日期: 2020-06-20

ZTFLH:

TG127.5

基金资助:四川省科技计划项目(2019YJ0353)

通讯作者: 陈馥 E-mail: chenfu@swpu.edu.cn

Corresponding author: CHEN Fu E-mail: chenfu@swpu.edu.cn

作者简介: 王坤泰，男，1996年生，硕士生

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引用本文:

王坤泰, 陈馥, 李环, 罗米娜, 贺杰, 廖子涵. 铁细菌对L245钢腐蚀行为的影响研究[J]. 中国腐蚀与防护学报, 2021, 41(2): 248-254.
Kuntai WANG, Fu CHEN, Huan LI, Mina LUO, Jie HE, Zihan LIAO. Corrosion Behavior of L245 Pipeline Steel in Shale Gas Fracturing Produced Water Containing Iron Bacteria. Journal of Chinese Society for Corrosion and protection, 2021, 41(2): 248-254.

链接本文:

https://www.jcscp.org/CN/10.11902/1005.4537.2020.105 或 https://www.jcscp.org/CN/Y2021/V41/I2/248

图1 L245钢在空白和含FB体系中浸泡21 d的极化曲线

图2 L245钢在空白和含有FB体系中浸泡不同时间的Nyquist和Bode图

图3 L245钢在空白和含有FB体系中的电化学阻抗等效拟合电路

表1 L245钢在无菌页岩气压裂产出水中的电化学阻抗谱拟合参数

表2 L245钢在含FB页岩气压裂产出水中的电化学阻抗谱拟合参数

图4 L245钢在空白和含FB的产出水中浸泡21 d后的腐蚀形貌

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