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中国腐蚀与防护学报  2012, Vol. 32 Issue (5): 364-368    
  研究报告 本期目录 | 过刊浏览 |
双辉等离子渗Ta改性层的组织及耐蚀性
毕强, 张平则,黄俊,魏东博,李伟
南京航空航天大学材料科学与技术学院 南京 211106
MICROSTRUCTURE AND CORROSION RESISTANCE OF Ta MODIFIED LAYER FORMED BY DOUBLE GLOW PLASMA SURFACE METALLURGY
BI Qiang, ZHANG Pingze, HUANG Jun, WEI Dongbo, LI Wei
College of Material Science and Technology, Nanjing University of Aeronautics and Astronautics,Nanjing 211106
全文: PDF(1208 KB)  
摘要: 

用双辉等离子表面冶金技术在Q235钢表面制备Ta改性层。用XRD,SEM,EDS, 电化学腐蚀和中性盐雾试验分析Ta改性层的组织特征、成分和耐蚀性能。结果表明,Ta改性层与基体结合良好,厚度为32 μm左右。改性层中Ta元素含量呈梯度分布,主要物相为α-Ta。双辉等离子表面渗Ta处理后试样的耐蚀性明显优于基材。

关键词 双辉等离子表面冶金Ta改性层极化曲线电化学阻抗中性盐雾试验抗腐蚀性    
Abstract

Ta modified layer was obtained on Q235 steel by double glow plasma surface metallurgy and its microstructure, composition and corrosion resistance were investigated by XRD, SEM, EDS, polarization curve, electrochemical impedance spectroscopy(EIS) and neutral salt spray test(NSS). The results indicated that the Ta modified layer adhered strongly to substrate and its thickness was about 32μm. Ta element distributed gradiently from the surface to substrate and the modified layer was mainly consisted of α-Ta phase. The results of polarization curves, electrochemical impedance spectroscopy and neutral salt spray test revealed that the Ta modified layer exhibited better corrosion resistance than Q235 steel.

Key wordsdouble glow plasma surface metallurgy    Ta modified layer    polarization curve    electrochemical impedance spectroscopy    neutral salt spray test    corrosion resistance
收稿日期: 2011-08-29     
ZTFLH:  TG174.442  
基金资助:

江苏省科技成果转化专项资金项目(BA2007036)资助

通讯作者: 毕强,     E-mail: moka1021@126.com
Corresponding author: BI Qiang     E-mail: moka1021@126.com
作者简介: 毕强,女,1988年生,硕士,研究方向为等离子表面冶金

引用本文:

毕强, 张平则,黄俊,魏东博,李伟. 双辉等离子渗Ta改性层的组织及耐蚀性[J]. 中国腐蚀与防护学报, 2012, 32(5): 364-368.
BI Qiang, ZHANG Pingze, HUANG Jun, WEI Dongbo, LI Wei. MICROSTRUCTURE AND CORROSION RESISTANCE OF Ta MODIFIED LAYER FORMED BY DOUBLE GLOW PLASMA SURFACE METALLURGY. Journal of Chinese Society for Corrosion and protection, 2012, 32(5): 364-368.

链接本文:

https://www.jcscp.org/CN/      或      https://www.jcscp.org/CN/Y2012/V32/I5/364

[1] Gao Y, Xu J Y, Gao Q, et al. Research on characteristic of double glow discharge plasma surface alloying process[J].Eng. Sci., 2008, 10(2): 26-30

    (高原, 徐晋勇, 高清等. 双层辉光离子渗金属技术特点[J]. 中国工程科学, 2008, 10(2): 26-30)

[2] Gao Y, Xu J Y, Gao Q, et al. Analysis on characteristics of double glow discharge plasma surface alloying process[J]. Hot Working Technol., 2006, 35(6): 56-59

    (高原, 徐晋勇, 高清等. 双层辉光离子渗金属技术特点分析[J]. 热加工工艺, 2006, 35(6): 56-59)

[3] Qu N Q. Properties and applications of Ta/Nb & their alloys[J]. Rare Met. Cem. Carbides, 1998, (2): 48-54

    (屈乃琴. 钽铌及其合金的应用[J]. 稀有金属与硬质合金, 1998, (2): 48-54)

[4] Liu S Y. Applications of tantalum in high-tech[J]. Rare Met. Cem. Carbides, 1998, (2): 55-58

    (刘世友. 钽在高新技术中的应用[J]. 稀有金属与硬质合金, 1998, (2): 55-58)

[5] Lee S L, Cipollo M, Windover D, et al. Analysis of magnetron sputtered tantalum coatings versus electrochemically deposited tantalum from molten[J]. Surf. Coat. Technol., 1999, 120-121: 44-52

[6] Ashraf P M, Shibli S M A. Reinforcing aluminum with cerium oxide: A new and effective technique to prevent corrosion in marine environments[J]. Electrochem. Commun., 2007, 9: 443-448

[7] Zheludkevich M L, Yasakau K A, Bastos A C, et al. On the application of electrochemical impedance spectroscopy to study the self-healing properties of protective coatings[J]. Electrochem. Commun., 2007, 9: 2622-2628

[8] Li M C, Luo S Z, Zeng C L, et al.Corrosion behavior of TiN coated type 316 stainless steel in simulated PEMFC environments [J]. Corros. Sci., 2004, 46: 1369-1380

[9] Datta J, Samanta B, Jana A, et al. Role of Cl- and NO3- ions on the corrosion behavior of 20% SiCp reinforced 6061-Al metal matrix composite: A correlation between electrochemical studies and atomic force microscopy[J]. Corros. Sci., 2008, 50: 2658-2668

[10] Yu H, Zheng Y G, Yao Z M. The cavitation erosion and erosion-corrosion behavior of carbon steel in simulating solutions of three rivers of China [J]. Mater. Corros., 2006, 57: 705-714

[11] Cao C N, Zhang J Q. An introduction to electrochemical impedance spectroscopy [M]. Beijing: Science Press, 2002  (曹楚南, 张鉴清. 电化学阻抗谱[M]. 北京: 科学出版社, 2002)

[12] Ceng Y F, Luo J L. Passivity and pitting of carbon steel in chromate solutions [J]. Electrochem. Acta, 1999, 44(26): 4795-4804

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