人工合成类天然产物防污剂的研究进展

doi:10.11902/1005.4537.2016.051

中国腐蚀与防护学报

2016, Vol. 36

Issue (5): 389-397 DOI: 10.11902/1005.4537.2016.051

本期目录 | 过刊浏览

人工合成类天然产物防污剂的研究进展

郑绍军^1,²(

),王瑜²,朱瑞²,谷永东²,杨丹丹²,蔡星伟^1,²

1. 江苏科技大学海洋装备研究院镇江 212003
2. 江苏科技大学环境与化学工程学院镇江 212003

Recent Research Progress of Synthetic Substancesas Antifoulants

Shaojun ZHENG^1,²(

),Yu WANG²,Rui ZHU²,Yongdong GU²,Dandan YANG²,Xingwei CAI^1,²

1. Marine Equipment and Technology Institute, Jiangsu University of Scince and Technology, Zhenjiang 212003, China
2. School of Environment and Chemical Engineering,Jiangsu University of Science and Technology, Zhenjiang 212003, China

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摘要:

综述了人工合成类天然产物防污剂,主要包括异噻唑啉酮类、辣素类、吲哚类、呋喃类、树脂类防、吡啶类和二硫代类的研究进展。重点论述了以天然产物为先导化合物,通过合成手段研制防污剂的目前现状。

关键词 ：天然产物, 人工合成, 防污剂, 防污活性

Abstract：

The marine biofouling caused serious adverse impact on oceanographic equipment or instruments. Although toxic antifouling agents, such as tributyltin (TBT) are effective for removing or reducing biofouling, they have been prohibited due to environmental concerns. Thus, it is necessary to develop environment-friendly antifouling agents. Natural substances used as marine antifouling agents are a hot topic recently, which may possess many advantages, such as nontoxic, efficient, rapid degradable and environment-friendly. The main problem of the development of natural antifouling agent is the shortage of natural substances actually. However such natural substances can be obtained by large-scale chemical synthesis, therewith, which may create a huge potential to meet the need of antifouling agents. In this review, we summarized the recent research progress of synthetic substances of marine antifouling agents, including isothiazolinone derivatives, capsaicin derivatives, indoles derivatives, furan derivatives, resinous, derivatives, pyridine derivatives, and dithio derivatives. Finally, taking natural substances as reference, the further development trend of antifoulantsvia synthesis is proposed in detail.

Key words： nature product synthesis antifouling agent antifouling activity

基金资助:国家自然科学基金项目 (21502073),江苏省自然科学基金项目 (BK20150465) 和江苏高校(高技术船舶)协同创新中心及江苏科技大学海洋装备研究院项目 (HZ2016012) 资助

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郑绍军,王瑜,朱瑞,谷永东,杨丹丹,蔡星伟. 人工合成类天然产物防污剂的研究进展[J]. 中国腐蚀与防护学报, 2016, 36(5): 389-397.
Shaojun ZHENG, Yu WANG, Rui ZHU, Yongdong GU, Dandan YANG, Xingwei CAI. Recent Research Progress of Synthetic Substancesas Antifoulants. Journal of Chinese Society for Corrosion and protection, 2016, 36(5): 389-397.

链接本文:

https://www.jcscp.org/CN/10.11902/1005.4537.2016.051 或 https://www.jcscp.org/CN/Y2016/V36/I5/389

图1 异噻唑啉酮类化合物的分子结构

图2. Sea-Nine211的分子结构

图3 异噻唑啉酮类防污剂的分子结构

图4 辣素类化合物的分子结构

图5 化合物HMMBA、BMA和HMOBA的分子结构

图6 吲哚类天然产物防污剂的分子结构

图7 2, 5, 6-三溴-1-甲基芦竹碱的分子结构

图8 吲哚衍生物的分子结构

图9 5, 6-二氯芦竹碱的分子结构

图10 高分子防污剂的分子结构

图11 吡啶硫酮铜的分子结构

图12 PrenventolA4S 的分子结构

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