Preparation, Anti-icing and De-icing Performance of Polyaniline Photothermal Superhydrophobic Anti-icing Coating

doi:10.11902/1005.4537.2024.010

Journal of Chinese Society for Corrosion and protection

2024, Vol. 44

Issue (6): 1485-1494 DOI: 10.11902/1005.4537.2024.010

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Preparation, Anti-icing and De-icing Performance of Polyaniline Photothermal Superhydrophobic Anti-icing Coating

AN Yan, JING Yongliang, LIU Tao(

), ZHANG Yuliang, LEI Yanhua, LI Xiaofeng(

), DONG Lihua

College of Ocean Science and Engineering, Shanghai Maritime University, Shanghai 201306, China

Cite this article:

AN Yan, JING Yongliang, LIU Tao, ZHANG Yuliang, LEI Yanhua, LI Xiaofeng, DONG Lihua. Preparation, Anti-icing and De-icing Performance of Polyaniline Photothermal Superhydrophobic Anti-icing Coating. Journal of Chinese Society for Corrosion and protection, 2024, 44(6): 1485-1494.

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Abstract

The F-PANI material was synthesized by modifying polyaniline (PANI) with perfluorodecyl triethoxysilane (FAS), which was subsequently blended with silicone resin (SR) to fabricate a functional F-PANI coating that exhibits both photo-thermal and superhydrophobic properties. The coating displays a contact angle of 150.8^o and a rolling angle of 3^o, along with superior mechanical strength, self-cleaning ability, and anti-corrosion performance. Upon exposure to 1 Sun irradiation at 20^oC, the F-PANI coating can attain a surface temperature of 83.5^oC within five minutes. Additionally, the coating demonstrates excellent photo-thermal features even at low temperatures. By 1 Sun irradiation at -25^oC, water droplets on the F-PANI coating were observed to be completely freezed after 830 s, showing a significantly slower freezing rate than the SR coating. Furthermore, the F-PANI coating exhibits defrosting and de-icing capability by 1 Sun irradiation at -15^oC.

Key words: polyaniline-modified superhydrophobic anti-icing coating photothermal de-icing

Received: 05 January 2024 32134.14.1005.4537.2024.010

ZTFLH:

TG174

Fund: National Natural Science Foundation of China(51771108);Shanghai Engineering Technology Center for Materials for Deep-sea Equipment(19DZ2253100)

Corresponding Authors: LIU Tao, E-mail: liutao@shmtu.edu.cn
LI Xiaofeng, E-mail: xfli@shmtu.edu.cn

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	AN Yan
	JING Yongliang
	LIU Tao
	ZHANG Yuliang
	LEI Yanhua
	LI Xiaofeng
	DONG Lihua

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https://www.jcscp.org/EN/10.11902/1005.4537.2024.010 OR https://www.jcscp.org/EN/Y2024/V44/I6/1485

Fig.1 Experimental flow chart of the preparation of fluorine-modified polyaniline powders

Fig.2 Comparisons of wettability (a) and EDS element mappings (b) of PANI and F-PANI powders, and SEM image of F-PANI powders (c)

Fig.3 FTIR (a) and XPS (b) spectra of PANI and F-PANI powders, and XPS fine spectra of C 1s of PANI (c) and F-PANI (d)

Fig.4 Optical photograph (a) and SEM images (b) of F-PANI coating, photographs of water droplet on the coating surface (c), schematic diagram of Cassie's model of the wetting state (d), digital photograph of the coating in water (e), and digital photographs of contact angle (f) and roll angle (g) of water droplet on the coating

Fig.5 Schematic diagrams (a，c)and variations of contact angle and sliding angle (b, d) for sandpaper abrasion experiment (a, b) and sand impact test (c, d) of F-PANI coating

Fig.6 Adhesion performances of silicone resin coating (a) and F-PANI coating (b) in three different liquids

Fig.7 Electrochemical impedance spectra (a) and dynamic potential polarization curves (b) of tinplate, organosilicone resin coating and F-PANI coating

Fig.8 Schematic diagrams of the delayed icing processes of droplets on silicone resin coating and F-PANI coating

Fig.9 Infrared photographs of the maximum surface temperatures of silicone resin coating and F-PANI coating at different light intensities (a), and warming curves of F-PANI coating (b)

Fig.10 Infrared photographs of the maximum temperatures for F-PANI coating after 5 min exposure under the conditions of temperature and light intensity

Fig.11 Surface topography changes of F-PANI coating during experimental processes of defrosting (a) and de-icing (b)

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