Research Progress of Monitoring Ion Concentration Variation of Micro-areas in Corrosion Crevice Interior

doi:10.11902/1005.4537.2022.325

Journal of Chinese Society for Corrosion and protection

2023, Vol. 43

Issue (4): 828-836 DOI: 10.11902/1005.4537.2022.325

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Research Progress of Monitoring Ion Concentration Variation of Micro-areas in Corrosion Crevice Interior

BAI Yihan¹, ZHANG Hang¹, ZHU Zejie¹(

), WANG Jiangying¹, CAO Fahe²

^1.School of Materials and Chemistry, China Jiliang University, Hangzhou 310018, China
^2.School of Materials Science, Sun Yat-sen University, Guangzhou 510006, China

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Abstract

In the early stage of crevice corrosion, the change of micro-chemical environment inside the crevice are closely related to the occurrence and development of crevice corrosion. This work briefly introduced the basic principles and influencing factors of crevice corrosion. Then the research progress in monitoring the ion concentration variation inside the crevice during recent years were summarized, including the in situ chemical imaging of solid-state ion-selective electrodes and fluorescence molecular in situ monitoring method, sampling analysis method and numerical calculation simulation. In addition, research work of micro-electrochemical sensors combined with SECM in the measurement of the ion concentration variation of micro-areas inside the crevice of stainless steel by our group is also introduced. Future applications of this technique in crevice corrosion are highlighted.

Key words: crevice corrosion microelectrochemical sensor scanning electrochemical microscopy

Received: 21 October 2022 32134.14.1005.4537.2022.325

ZTFLH:

TG174

Fund: National Natural Science Foundation of China(52001301);Zhejiang Province Fundamental Research Funds for the Central Universities(2022YW45)

Corresponding Authors: ZHU Zejie, E-mail: zejiezhu@cjlu.edu.cn

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Cite this article:

BAI Yihan, ZHANG Hang, ZHU Zejie, WANG Jiangying, CAO Fahe. Research Progress of Monitoring Ion Concentration Variation of Micro-areas in Corrosion Crevice Interior. Journal of Chinese Society for Corrosion and protection, 2023, 43(4): 828-836.

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https://www.jcscp.org/EN/10.11902/1005.4537.2022.325 OR https://www.jcscp.org/EN/Y2023/V43/I4/828

Fig.1 Schematic diagram of the corrosion behavior of crevice corrosion^[13]

Fig.2 Schematic diagram of proposed potential distribution on the crevice wall in the stage of propagation of crevice corrosion^[20]

Fig.3 Profiles of pH for iron inside the crevice in 0.5 mol/L Na₂SO₄ (a=0.7 mm) solution^[34]

Fig.4 pH versus time inside and outside the seam with and without 600 mg/L HAc in a CO₂-saturated solution of 1.65% NaCl^[35]

Fig.5 Optical micrograph of the crevice specimen collected (a), fluorescence micrograph of pH over time (b) and Cl^- concentration over time (c)^[38]

Fig.6 Total current, pH and Cl^- concentration of high manganese austenitic stainless steel in 0.01 mol/L NaCl solution (pH=3) evolve with time^[38]

Fig.7 Cationic chromatograms of 316L stainless steel in 2 mol/L KNO₃ solution^[40]

Fig.8 Comparison of the predicted pH profile change over time for 304 stainless steel at various sites: (a) (0,7), (b) (0,4), (c) (0,0.5) using the current model and experiment^[41]

Fig.9 Evolution of pH value of solution in crevice with time^[43]

Fig.10 Evolution of the pH value of 201 stainless steel in 1 mol/L NaCl solution (pH=4.00, crevice width 500 μm) with time at different positions from the crevice mouth

Fig.11 Evolution of the pH value of 201 stainless steel in 1 mol/L NaCl solution (pH=4.00) at the bottom of the crevice with different crevice widths with time

Fig.12 Evolution of Cl^- concentration of 201 stainless steel in 1 mol/L NaCl (pH=4.00) solution at different positions inside the crevice with time

1	Yan L, Song G L, Wang Z M, et al. Crevice corrosion of steel rebar in chloride-contaminated concrete [J]. Constr. Build. Mater., 2021, 296: 123587 doi: 10.1016/j.conbuildmat.2021.123587
2	Huang X, Zhou K, Ye Q Z, et al. Crevice corrosion behaviors of CoCrMo alloy and stainless steel 316L artificial joint materials in physiological saline [J]. Corros. Sci., 2022, 197: 110075 doi: 10.1016/j.corsci.2021.110075
3	Ilic E, Pardo A, Hauert R, et al. Silicon corrosion in neutral media: The influence of confined geometries and crevice corrosion in simulated physiological solutions [J]. J. Electrochem. Soc., 2019, 166: C125 doi: 10.1149/2.0241906jes
4	Zhu L Y, Cui Z Y, Cui H Z, et al. The effect of applied stress on the crevice corrosion of 304 stainless steel in 3.5 wt% NaCl solution [J]. Corros. Sci., 2022, 196: 110039 doi: 10.1016/j.corsci.2021.110039
5	Xu W C, Deng Y, Zhang B B, et al. Crevice corrosion of U75V high-speed rail steel with varying crevice gap size by in-situ monitoring [J]. J. Mater. Res. Technol., 2022, 16: 1856 doi: 10.1016/j.jmrt.2021.12.116
6	Mu J, Li Y Z, Wang X. Crevice corrosion behavior of X70 steel in NaCl solution with different pH [J]. Corros. Sci., 2021, 182: 109310 doi: 10.1016/j.corsci.2021.109310
7	Lu L, Li X G. Corrosion products of reverse crevice corrosion of copper [J]. Int. J. Miner. Metall. Mater., 2011, 18: 320 doi: 10.1007/s12613-011-0441-x
8	Zhang T S, Wang J L, Li G F, et al. Crevice corrosion of X80 carbon steel induced by sulfate reducing bacteria in simulated seawater [J]. Bioelectrochemistry, 2021, 142: 107933 doi: 10.1016/j.bioelechem.2021.107933
9	Xu X Y, Liu S M, Liu Y, et al. Corrosion of stainless steel valves in a reverse osmosis system: Analysis of corrosion products and metal loss [J]. Eng. Fail. Anal., 2019, 105: 40 doi: 10.1016/j.engfailanal.2019.06.026
10	Ning F Q, Tan J B, Zhang Z Y, et al. Effects of thiosulfate and dissolved oxygen on crevice corrosion of Alloy 690 in high-temperature chloride solution [J]. J. Mater. Sci. Technol., 2021, 66: 163 doi: 10.1016/j.jmst.2020.05.074
11	Evans U R. The electrochemical character of corrosion [J]. J. Inst. Met., 1923, 30: 239
12	Fontana M G, Greene N D, McDonald D D. Corrosion engineering [J]. J. Electrochem. Soc., 1979, 126: 232C
13	Li Y Z, Wang X, Zhang G A. Corrosion behaviour of 13Cr stainless steel under stress and crevice in 3.5 wt. % NaCl solution [J]. Corros. Sci., 2020, 163: 108290 doi: 10.1016/j.corsci.2019.108290
14	Zhang C W, Fu T L, Chen H Y, et al. Research progress on crevice corrosion, plasma nitriding and surface nanocrystallization of titanium alloys [J]. Surf. Technol., 2019, 48(11): 114
	张乘玮, 付天琳, 陈涵悦等. 钛合金缝隙腐蚀、离子渗氮与表面纳米化的研究进展[J]. 表面技术, 2019, 48(11): 114
15	Li Y Z, Xu N, Guo X P, et al. The role of acetic acid or H⁺ in initiating crevice corrosion of N80 carbon steel in CO₂-saturated NaCl solution [J]. Corros. Sci., 2017, 128: 9 doi: 10.1016/j.corsci.2017.08.028
16	Pickering H W. The significance of the local electrode potential within pits, crevices and cracks [J]. Corros. Sci., 1989, 29: 325 doi: 10.1016/0010-938X(89)90039-5
17	Aoyama T, Sugawara Y, Muto I, et al. In situ monitoring of crevice corrosion morphology of Type 316L stainless steel and repassivation behavior induced by sulfate ions [J]. Corros. Sci., 2017, 127: 131 doi: 10.1016/j.corsci.2017.08.005
18	Shojaei E, Mirjalili M, Moayed M H. The influence of the crevice induced IR drop on polarization measurement of localized corrosion behavior of 316L stainless steel [J]. Corros. Sci., 2019, 156: 96 doi: 10.1016/j.corsci.2019.04.030
19	Hu Q, Zhang G A, Qiu Y B, et al. The crevice corrosion behaviour of stainless steel in sodium chloride solution [J]. Corros. Sci., 2011, 53: 4065 doi: 10.1016/j.corsci.2011.08.012
20	Yang Y Z, Jiang Y M, Li J. In situ investigation of crevice corrosion on UNS S32101 duplex stainless steel in sodium chloride solution [J]. Corros. Sci., 2013, 76: 163 doi: 10.1016/j.corsci.2013.06.039
21	Ning F Q. Crevice corrosion behaviors of nickel-based Alloy 690 and 405 stainless steel in high temperature high pressure water [D]. Hefei: University of Science and Technology of China, 2021
	宁方强. 690镍基合金/405不锈钢高温高压水缝隙腐蚀行为研究 [D]. 合肥: 中国科学技术大学, 2021
22	Torres C, Johnsen R, Iannuzzi M. Crevice corrosion of solution annealed 25Cr duplex stainless steels: Effect of W on critical temperatures [J]. Corros. Sci., 2021, 178: 109053 doi: 10.1016/j.corsci.2020.109053
23	Ming N X, Wang Q S, He C, et al. Effect of temperature on corrosion behavior of X70 steel in an artificial CO₂-containing formation water [J]. J. Chin. Soc. Corros. Prot., 2021, 41: 233
	明男希, 王岐山, 何川等. 温度对X70钢在含CO₂地层水中腐蚀行为影响 [J]. 中国腐蚀与防护学报, 2021, 41: 233 doi: 10.11902/1005.4537.2020.049
24	Zhang W L, Zhang Z L, Wu Z L, et al. Effect of temperature on pitting corrosion behavior of 316L stainless steel in oilfield wastewater [J]. J. Chin. Soc. Corros. Prot., 2022, 42: 143
	张文丽, 张振龙, 吴兆亮等. 温度对316L不锈钢在油田污水中点蚀行为的影响研究 [J]. 中国腐蚀与防护学报, 2022, 42: 143 doi: 10.11902/1005.4537.2020.257
25	Ren A, Li C T, Liu F H, et al. Effect of Cl^- on corrosion behavior of alloy 690 in high temperature and high pressure water solution [J]. Chin. J. Nonferrous Met., 2012, 22: 1082
	任爱, 李成涛, 刘飞华等. Cl^-对690合金在高温高压水中腐蚀行为的影响 [J]. 中国有色金属学报, 2012, 22: 1082
26	Ding Q M, Gao Y N, Hou W L, et al. Influence of Cl^– concentration on corrosion behavior of reinforced concrete in soil [J]. J. Chin. Soc. Corros. Prot., 2021, 41: 705
	丁清苗, 高宇宁, 侯文亮等. Cl^–浓度对钢筋混凝土在土壤中腐蚀行为的影响 [J]. 中国腐蚀与防护学报, 2021, 41: 705 doi: 10.11902/1005.4537.2020.207
27	Han D, Jiang Y M, Shi C, et al. Effect of temperature, chloride ion and pH on the crevice corrosion behavior of SAF 2205 duplex stainless steel in chloride solutions [J]. J. Mater. Sci., 2012, 47: 1018 doi: 10.1007/s10853-011-5889-6
28	Zhao J M, Zuo Y, Xiong J P, et al. Effect of pH value on corrosion behavior of low carbon steel in high salt waste water [J]. Mater. Prot., 2001, 34(7): 8
	赵景茂, 左禹, 熊金平等. pH对低碳钢在高含盐污水中的腐蚀影响 [J]. 材料保护, 2001, 34(7): 8
29	Shojaei E, Moayed M H, Mirjalili M, et al. Proposed stability product criterion for open hemispherical metastable pits formed in the crevices of different aspect ratios (l/d) on 316L stainless steel in 3.5% NaCl solution [J]. Corros. Sci., 2021, 184: 109389 doi: 10.1016/j.corsci.2021.109389
30	Zhao B J, Fan Y, Li Z Z, et al. Crevice corrosion behavior of 316L stainless steel paired with four different materials [J]. J. Chin. Soc. Corros. Prot., 2020, 40: 332
	赵柏杰, 范益, 李镇镇等. 不同类型接触面对316L不锈钢缝隙腐蚀的影响 [J]. 中国腐蚀与防护学报, 2020, 40: 332 doi: 10.11902/1005.4537.2019.198
31	Kamaraj A, Erning J W. Susceptibility of 304 stainless steel to crevice corrosion in electrochemically active fluids [J]. Corrosion, 2020, 76: 424 doi: 10.5006/3324
32	Song Y Q, Du C W, Li X G. Electrochemical corrosion behavior of carbon steel with bulk coating holidays [J]. J. Univ. Sci. Technol. Beijing Min. Metall. Mater., 2006, 13: 37
33	Jakobsen P T, Maahn E. Temperature and potential dependence of crevice corrosion of AISI 316 stainless steel [J]. Corros. Sci., 2001, 43: 1693 doi: 10.1016/S0010-938X(00)00167-0
34	Wolfe R C, Weil K G, Shaw B A, et al. Measurement of pH gradients in the crevice corrosion of iron using a palladium hydride microelectrode [J]. J. Electrochem. Soc., 2005, 152: B82 doi: 10.1149/1.1851053
35	Li Y Z, Xu N, Liu G R, et al. Crevice corrosion of N80 carbon steel in CO₂-saturated environment containing acetic acid [J]. Corros. Sci., 2016, 112: 426 doi: 10.1016/j.corsci.2016.08.002
36	Picot A, D'Aléo A, Baldeck P L, et al. Long-lived two-photon excited luminescence of water-soluble europium complex: Applications in biological imaging using two-photon scanning microscopy [J]. J. Am. Chem. Soc., 2008, 130: 1532 doi: 10.1021/ja076837c pmid: 18193870
37	Lee M H, Park N, Yi C, et al. Mitochondria-immobilized pH-sensitive off-on fluorescent probe [J]. J. Am. Chem. Soc., 2014, 136: 14136 doi: 10.1021/ja506301n pmid: 25158001
38	Nishimoto M, Ogawa J, Muto I, et al. Simultaneous visualization of pH and Cl^- distributions inside the crevice of stainless steel [J]. Corros. Sci., 2016, 106: 298 doi: 10.1016/j.corsci.2016.01.028
39	Trout T K, Bellama J M, Faltynek R A, et al. Effect of pH on the emission properties of aqueous tris (2, 6-dipicolinato) terbium (III) complexes [J]. Inorg. Chim. Acta, 1989, 155: 13 doi: 10.1016/S0020-1693(00)89273-7
40	Aoyama T, Sugawara Y, Muto I, et al. NH 4 + generation: The role of NO 3 - in the crevice corrosion repassivation of Type 316L stainless steel [J]. J. Electrochem. Soc., 2019, 166: C250 doi: 10.1149/2.0501910jes
41	Chen X, Gao F J, Wang Y L, et al. Transient numerical model for crevice corrosion of pipelines under disbonded coating with cathodic protection [J]. Mater. Des., 2016, 89: 196 doi: 10.1016/j.matdes.2015.09.047
42	Ding J W, Wang H T, Han E H. A multiphysics model for studying transient crevice corrosion of stainless steel [J]. J. Mater. Sci. Technol., 2021, 60: 186 doi: 10.1016/j.jmst.2020.06.008
43	Liu F, Liu Q W, Chen J T, et al. Application of peridynamic method to analysis of crevice corrosion [J]. Bull. Sci. Technol., 2020, 36(3): 96
	刘飞, 刘齐文, 陈景涛等. 近场动力学方法在缝隙腐蚀问题中的应用 [J]. 科技通报, 2020, 36(3): 96
44	Cao F H, Xia Y, Liu W J, et al. Basic principles and applications of SECM in metal corrosion [J]. J. Electrochem., 2013, 19: 393

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