|
|
|
| Surface Stabilization and Rust Structure of Weathering Steel |
SHI Jian( ), HU Xuewen, HE Bo, YANG Zheng, WANG Fei, GUO Rui |
| Technology Center of Masteel, Ma'anshan Iron and Steel Co. Ltd., Ma'anshan 243000, China |
|
|
|
|
Abstract Aiming at the problem of emerging traces of fluid flow containing rust products on the surface of the bare weathering steel during real service in atmosphere, a stabilizing treatment solution for the weathering steel was designed, and after stabilization treatment, the weathering steel was exposed in a real atmosphere for 0.5 a. The evolution process of the forming rust layer on the weathering steel was monitored and characterized. The corrosion kinetic curve shows that the weight variation of weathering steel gradually reaches a stable state through four stages, and the mass gain (loss) of each stage changes linearly. The enrichment of Cu and Cr in the rust increases the electrochemical protectiveness of the rust layer, reduces the corrosion rate and shortens the stabilization process of the bare weathering steel.
|
|
Received: 11 October 2021
|
|
|
|
Corresponding Authors:
SHI Jian
E-mail: stoneshi810@163.com
|
About author: SHI Jian, E-mail: stoneshi810@163.com
|
| 1 |
Yadav A P, Nishikata A, Tsuru T. Electrochemical impedance study on galvanized steel corrosion under cyclic wet-dry conditions-influence of time of wetness [J]. Corros. Sci., 2004, 46: 169
doi: 10.1016/S0010-938X(03)00130-6
|
| 2 |
Liu T, Wang S M, Zhao X J. Stabilization treatment and formation of rust layer on weathering steel [J]. China Surf. Eng., 2019, 32(6): 98
|
|
刘涛, 王胜民, 赵晓军. 耐候钢锈层的稳定化处理及锈层形成 [J]. 中国表面工程, 2019, 32(6): 98
|
| 3 |
Hara S, Kamimura T, Miyuki H, et al. Taxonomy for protective ability of rust layer using its composition formed on weathering steel bridge [J]. Corros. Sci., 2007, 49: 1131
doi: 10.1016/j.corsci.2006.06.016
|
| 4 |
Liang C F, Hou W T. The effect of alloying in carbon steels and low alloy steels on their atmospheric corrosion resistance [J]. J. Chin. Soc. Corros. Prot., 1997, 17: 87
|
|
梁彩凤, 侯文泰. 合金元素对碳钢和低合金钢在大气中耐腐蚀性的影响 [J]. 中国腐蚀与防护学报, 1997, 17: 87
|
| 5 |
Cano H, Neff D, Morcillo M, et al. Characterization of corrosion products formed on Ni 2.4wt%-Cu 0.5wt%-Cr 0.5wt% weathering steel exposed in marine atmospheres [J]. Corros. Sci., 2014, 87: 438
doi: 10.1016/j.corsci.2014.07.011
|
| 6 |
Chen X H, Dong J H, Han E-H, et al. Effect of Ni on the ion-selectivity of rust layer on low alloy steel [J]. Mater. Lett., 2007, 61: 4050
doi: 10.1016/j.matlet.2007.01.014
|
| 7 |
Zhong B, Xu X L, Chen Y Q, et al. Electrochemical impedance spectrum for corrosion of a weathering steel 09CuPCrNi-A in 3.5% NaCl solution [J]. Corros. Sci. Prot. Technol., 2011, 23: 437
|
|
钟彬, 徐小连, 陈义庆 等. 09CuPCrNi-A耐大气腐蚀钢电化学阻抗研究 [J]. 腐蚀科学与防护技术, 2011, 23: 437
|
| 8 |
Shi Z J, Wang L, Chen N, et al. Research status and development on surface rust layer and stabilizing treatment of weathering steels [J]. Corros. Sci. Prot. Technol., 2015, 27: 503
|
|
石振家, 王雷, 陈楠 等. 耐候钢表面锈层及其稳定化处理现状与发展趋势 [J]. 腐蚀科学与防护技术, 2015, 27: 503
|
| 9 |
Liu G C, Dong J H, Han E-H, et al. Progress in research on rust layer of weathering steel [J]. Corros. Sci. Prot. Technol., 2006, 18: 268
|
|
刘国超, 董俊华, 韩恩厚 等. 耐候钢锈层研究进展 [J]. 腐蚀科学与防护技术, 2006, 18: 268
|
| 10 |
Gao L J, Yang J W, Yu D Y, et al. A new rust stabilization treatment of weathering steel and its periodic immersed corrosion resistance in 3.5%NaCl solution [J]. Surf. Technol., 2017, 46(8): 234
|
|
高立军, 杨建炜, 于东云 等. 耐候钢新型表面锈层稳定剂处理及其耐3.5%NaCl溶液周浸腐蚀性能 [J]. 表面技术, 2017, 46(8): 234
|
| 11 |
Liu H X, Huang F, Yuan W, et al. Corrosion behavior of 690MPa grade high strength Bainite steel in a simulated rural atmosphere [J]. J. Chin. Soc. Corros. Prot., 2020, 40: 416
|
|
刘海霞, 黄峰, 袁玮 等. 690MPa级高强贝氏体钢在模拟乡村大气中的腐蚀行为 [J]. 中国腐蚀与防护学报, 2020, 40: 416
|
| 12 |
Ishikawa T, Minamigawa M, Kandori K, et al. Influence of metal ions on the transformation of γ-FeOOH into α-FeOOH [J]. J. Electrochem. Soc., 2004, 151: B512
doi: 10.1149/1.1778167
|
| 13 |
Choi Y S, Shim J J, Kim J G. Effects of Cr, Cu, Ni and Ca on the corrosion behavior of low carbon steel in synthetic tap water [J]. J. Alloy. Compd., 2005, 391: 162
doi: 10.1016/j.jallcom.2004.07.081
|
| 14 |
Misawa T, Kyuno T, Suëtaka W, et al. The mechanism of atmospheric rusting and the effect of Cu and P on the rust formation of low alloy steels [J]. Corros. Sci., 1971, 11: 35
doi: 10.1016/S0010-938X(71)80072-0
|
| 15 |
Hao X C, Xiao K, Zhang H Q, et al. Influence of alloying elements Cu and Cr on the corrosion resistance of weathering steels in simulated ocean atmospheric environment [J]. Mater. Prot., 2009, 42(1): 21
|
|
郝献超, 肖葵, 张汉青 等. 模拟海洋大气环境下Cu和Cr对耐候钢耐腐蚀性能的影响 [J]. 材料保护, 2009, 42(1): 21
|
| 16 |
Hao X H, Dong J H, Wei J, et al. Effect of Cu on corrosion behavior of low alloy steel under the simulated bottom plate environment of cargo oil tank [J]. Corros. Sci., 2017, 121: 84
doi: 10.1016/j.corsci.2017.03.012
|
| 17 |
Shi J, Hu X W, He B, et al. Sulfuric acid corrosion resistance of Q345NS steel welded joint [J]. J. Chin. Soc. Corros. Prot., 2021, 41: 565
|
|
石践, 胡学文, 何博 等. Q345NS钢焊接接头耐硫酸腐蚀特性研究 [J]. 中国腐蚀与防护学报, 2021, 41: 565
|
| 18 |
Li M S, Xin L, Qian Y H, et al. A review on studies of internal stress in oxide scales [J]. Corros. Sci. Prot. Technol., 1999, 11: 300
|
|
李美栓, 辛丽, 钱余海 等. 氧化膜应力研究进展 [J]. 腐蚀科学与防护技术, 1999, 11: 300
|
| No Suggested Reading articles found! |
|
|
Viewed |
|
|
|
Full text
|
|
|
|
|
Abstract
|
|
|
|
|
Cited |
|
|
|
|
| |
Shared |
|
|
|
|
| |
Discussed |
|
|
|
|
