Review on Metal Silicide Anti-oxidation Coatings

doi:10.11902/1005.4537.2020.076

Journal of Chinese Society for Corrosion and protection

2021, Vol. 41

Issue (3): 298-306 DOI: 10.11902/1005.4537.2020.076

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Review on Metal Silicide Anti-oxidation Coatings

AN Liang¹(

), GAO Changqi², JIA Jiangang², MA Qin²

^1.School of Bailie Mechanical Engineering, Lanzhou City University, Lanzhou 730070, China
^2.State Key Laboratory of Advanced Processing and Recycling of Nonferrous Metals, Lanzhou University of Technology, Lanzhou 730050, China

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Abstract

For chemical industry, the preparation technologies, the anti-oxidation mechanisms and the status of industrial applications of Si-Fe coatings are introduced. The research status of Si-Mo and Si-Zr coatings for the application of high temperature protection are overviewed particularly, simultaneously，the effect of various alloying elements on the anti-oxidation of silicide coatings and the relevant mechanisms are described. Compared to single-layer silicide coatings, bilayer or multi-layer composite coatings with excellent designability can meet simultaneously the requirements both of heat resistance of coatings and the adhesive strength between coatings and substrates, besides, which also can minimize defects such as the thermal expansion mismatch and elemental inter-diffusion between the coating and the substrate. Therefore, of which the performance advantages and structural design concept are illustrated. Lastly, the development trend of refractory metal silicide coatings is prospected so that to provide the proper reference for engineering application.

Key words: metal silicide anti-oxidation property alloying composite coating

Received: 06 May 2020

ZTFLH:

TG174.4

Fund: National Natural Science Foundation of China(51565024);Doctoral Start Fund of Lanzhou City University(LZCU-BS2018-22)

Corresponding Authors: AN Liang E-mail: anliang72@163.com

About author: AN Liang, E-mail: anliang72@163.com

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Cite this article:

AN Liang, GAO Changqi, JIA Jiangang, MA Qin. Review on Metal Silicide Anti-oxidation Coatings. Journal of Chinese Society for Corrosion and protection, 2021, 41(3): 298-306.

URL:

https://www.jcscp.org/EN/10.11902/1005.4537.2020.076 OR https://www.jcscp.org/EN/Y2021/V41/I3/298

Fig.1 Mechanisms of silicide layer formation^[17]

Fig.2 SEM image and the line distribution of elements in cross-section (A-AISI304 matrix; B-inner layer of oxidation film; C-outer layer of oxidation film)^[25]

Fig.3 Oxidation dynamics curves of EEUSS coatings^[32]

Fig.4 Cross-sectional BSE images of the Mo-Si-Al coating oxidized at 1250 ℃ for 1 h (a) and 30 h (b)^[35]

Fig.5 Cross-sectional images of the Mo-Si-B coating (a) and oxidized at 1250 ℃ for 100 h (b), magnified image of the oxide scale of the Mo-Si-B coating after oxidation at 1250 ℃ for 100 h (c)^[40]

Fig.6 Schematic diagram of the hybrid coating system combining AIP and sputtering techniques^[47]

Fig.7 Thermogravimetric curves of the Zr-Si-N films ann-ealed in air up to 1300 ℃^[55]

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