INVESTIGATION ON CARBON DIOXIDE CORROSION PERFORMANCE OF VARIOUS 13Cr STEELS IN SIMULATED STRATUM WATER

J Chin Soc Corr Pro

2012, Vol. 32

Issue (4): 300-305 DOI:

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INVESTIGATION ON CARBON DIOXIDE CORROSION PERFORMANCE OF VARIOUS 13Cr STEELS IN SIMULATED STRATUM WATER

HOU Zan¹, ZHOU Qingjun², WANG Qijiang^1,2, ZHANG Zhonghua², QI Huibin^1,2, WANG Jun¹

1. School of Materials Science & Engineering, Shanghai Jiao Tong University 200240
2. Bao Shan Iron & Steel Co. Ltd, 201900

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Abstract The corrosion behaviour of various 13Cr steels (marked as 13Cr-0, 13Cr1, M13Cr and S13Cr) in the CO$_{2}$ corrosion environment was investigated by high temperature and high pressure (HTHP) autoclave under conditions of different temperatures, concentrations of Cl ion and partial pressures of CO₂ to simulate the downhole surroundings of a certain oil field. Their corrosion scales were observed and analyzed by scanning electron microscope(SEM), energy dispersive spectrometer(EDS), X-ray diffraction(XRD) and X-ray photoelectron spectroscopy(XPS). The results shown that corrosion rates of all steels increased with rising of temperature, concentration of Cl ion and CO₂ partial pressure; temperature had the most notable impact on corrosion rates, at a high temperature, the four 13Cr steels exhibited conspicuous differences in corrosion rates; the order of corrosion rates of the four steels was 13Cr-0>13Cr-1>M13Cr>S13Cr. Furthermore, the morphologies and microstructures of corrosion scales on different steels differed significantly from each other.

Key words: 13Cr stainless steel high temperature and high pressure CO₂ corrosion

Received: 22 August 2011

ZTFLH:

TG172.6

Corresponding Authors: WANG Jun E-mail: junwang@situ.edu.cn

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Cite this article:

HOU Zan, ZHOU Qingjun, WANG Qijiang, ZHANG Zhonghua, QI Huibin, WANG Jun. INVESTIGATION ON CARBON DIOXIDE CORROSION PERFORMANCE OF VARIOUS 13Cr STEELS IN SIMULATED STRATUM WATER. J Chin Soc Corr Pro, 2012, 32(4): 300-305.

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https://www.jcscp.org/EN/ OR https://www.jcscp.org/EN/Y2012/V32/I4/300

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