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J Chin Soc Corr Pro  2009, Vol. 29 Issue (6): 442-446    DOI:
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LONG-TERM ATMOSPHERIC CORROSION BEHAVIOR OF LY12 ALUMINIUM ALLOY
SUN Shuangqing; ZHENG Qifei; LI Defu; CHEN Jie; WEN Junguo
General Research Institute for Nonferrous Metals; Beijing 100088; China
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Abstract  

Atmospheric corrosion behavior of LY12 was investigated in five typical atmospheres in China over 20 years. Mass loss and loss in mechanical properties were measured; Appearance, cross-section photomicrograph and corrosion products were observed and analyzed by optical microscope and XRD. The results show that in hot and humid atmosphere of Wanning and Qionghai exfoliation corrosion occurred on LY12 after 6 and 10 years, respectively, and almost lost its mechanical properties after 20 years exposure. While in Beijing atmosphere, LY12 still performed excellent mechanical properties after 20 years exposure. The mass loss data were higher in Jiangjin and Qingdao due to higher average RH and SO2 or Cl- contamination of the atmosphere, and lowest in Beijing atmosphere because of lower average RH. Before exfoliation corrosion occurred, the mass loss data with exposure time obeyed well with power function C=KTn. The main exfoliation corrosion products are γ-Al(OH)3 and α-Al2O3.3H2O.

Key words:  long-term atmospheric corrosion      LY12      exfoliation corrosion      mass loss      mechanical property     
Received:  08 September 2008     
ZTFLH: 

TG172.3

 
Corresponding Authors:  ZHENG Qifei     E-mail:  zhengqf@grinm.com

Cite this article: 

SUN Shuangqing ZHENG Qifei LI Defu CHEN Jie WEN Junguo. LONG-TERM ATMOSPHERIC CORROSION BEHAVIOR OF LY12 ALUMINIUM ALLOY. J Chin Soc Corr Pro, 2009, 29(6): 442-446.

URL: 

https://www.jcscp.org/EN/     OR     https://www.jcscp.org/EN/Y2009/V29/I6/442

[1] Xiao Y Q, Xie S S, Liu J A, et al. Practical Directory of Aluminium Alloys Technology [M]. Beijing: Metallurgical Industry Press, 2005
    (肖亚庆, 谢水生, 刘静安等. 铝加工技术实用手册[M]. 北京: 冶金工业出版社, 2005)
[2] Guillaumin V, Mankowski G. Localized corrosion of 2024 T351 aluminium alloy in chloride media [J]. Corros. Sci., 1998, 41(3): 421-438
[3] Schmidt W, Stratmann M. Scanning kelvinprobe investigations of filiform corrosion on aluminum alloy 2024-T3 [J].Corros. Sci., 1998, 40(8): 1441-1443
[4] Zhang Z, Song S Z, Lu Y Z, et al. Corrosion behaviors of LY12CZ and LC4CS alumnium alloys in simulated atmosphere [J]. J. Chin. Soc. Corros. Prot., 2007, 27(3): 129-133
    (张正,宋诗哲,卢玉琢等. 模拟污染潮湿大气环境下LY12CZ、 LC4CS铝合金腐蚀行为研究 [J]. 中国腐蚀与防护学报,2007, 27(3): 129-133)
[5] An B G, Zhang X Y, Song S Z, et al. A study of electrochemical impedance spectrum for corrrosion behavior of LY12 aluminium alloy in simulated acid rain [J]. J. Chin. Soc. Corros. Prot., 2003, 23(3): 167-170
    (安百刚,张学元,宋诗哲等. LY12铝合金在模拟酸雨溶液中的阻抗谱研究 [J]. 中国腐蚀与防护学报,2003, 23(3): 167-170)
[6] Mikhailovsky Y N, Strekalov P V. Atmospheric corrosion testing in USSR. In: Ailor W H ed. Atmospheric Corrosion [M]. New York: John Wiley and Sons. 1982: 923-942
[7] Southwell C R, Bultman J D. Atmospheric Corrosion Testing in Tropics. Ailor W H. Atmospheric Corrosion [M]. New York: John Wiley and Sons, 1982: 943-967
[8] Fukushima T, Sato N, Hisamatsu Y,et al. Atmospheric Corrosion Testing in Japan.Ailor W H. Atmospheric Corrosion [M]. New York: John Wiley and Sons,1982: 841-872
[9] Sowinski G, Sprowls D O. Weathering of Aluminium Alloys. Ailor W H. Atmospheric Corrosion [M]. New York: John Wiley and Sons, 1982: 297-328
[10] Han D S, Li D. Correlation study ofaccelerated corrosion testing and outfield testing of aluminum alloy [J]. Corros. Prot, 2008, 29(3): 119-132
     (韩德盛, 李荻. LY12铝合金在海洋大气环境下加速腐蚀试验和外场暴露试验的相关性[J]. 腐蚀与防护, 2008, 29(3): 119-132
[11] Gan Z, Wang Y. Influence of microstructure on exfoliation corrosion of 2024 aluminium alloy[J]. Corros. Sci. Prot. Technol. 1995, 7(3):208-209
(甘株, 王云. 微观结构对LY12铝合金剥蚀的影响 [J]. 腐蚀科学与防护技术, 1995, 7(3): 208-209)
[12] Pourbaix M. The Linear Bilogarithmic Law for Atmospheric Corrosion. In: Ailor W H ed. Atmospheric Corrosion [M]. New York: John Wiley and Sons, 1982: 107-122
[13] Fuente D de la, Otero-Huerta E,Morcillo M. Studies of long-term weathering of aluminium in the atmosphere [J]. Corros. Sci., 2007, 49(7): 3134-3148
[14] Robinson M J, Role of wedging stresses in the exfoliation corrosion of high strength aluminium alloys [J]. Corros. Sci., 1983,23(8): 887-899
[15] Kelly D J, Robinson M J. Influence of heat treatment and grain shape on exfoliation corrosion of Al-Li alloy 8090 [J]. Corrosion. 1993, 49(10): 787-795
[16] Su J X, Zhang Z, Cao F H, et al. Review on the intergranular corrosion and exfoliation corrosion of aluminium alloys [J]. J. Chin. Soc. Corros. Prot., 2005, 25(3): 197-192
     (苏景新, 张昭, 曹发和等. 铝合金的晶间腐蚀与剥蚀 [J]. 中国腐蚀与防护学报, 2005, 25(3): 197-192)

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