Please wait a minute...
Journal of Chinese Society for Corrosion and protection  2025, Vol. 45 Issue (3): 780-786    DOI: 10.11902/1005.4537.2024.119
Current Issue | Archive | Adv Search |
Corrosion Behavior and Distribution of Corrosion Inhibitors in Inclined Section for Natural Gas Gathering and Transportation Pipelines
HOU Xiaoben1, LIU Ning2,3, HU Junying2()
1.Southwest Oil and Gas Branch of China Petroleum and Chemical Corporation, Deyang 610041, China
2.School of Petroleum and Natural Gas Engineering, Southwest Petroleum University, Chengdu 610500, China, 3 PipeChina Hunan Branch, Changsha 410016, China
3.PipeChina Hunan Branch, Changsha 410016, China
Cite this article: 

HOU Xiaoben, LIU Ning, HU Junying. Corrosion Behavior and Distribution of Corrosion Inhibitors in Inclined Section for Natural Gas Gathering and Transportation Pipelines. Journal of Chinese Society for Corrosion and protection, 2025, 45(3): 780-786.

Download:  HTML  PDF(4717KB) 
Export:  BibTeX | EndNote (RIS)      
Abstract  

The corrosion behavior of a pipeline with an inclination of 30° in gas-liquid two-phase flow, the distribution and the inhibition efficiency of corrosion inhibitors were studied by experiment and CFD simulation. The results indicate that in case of the gas phase flow rate of 3 m/s while carrying 7.5vol.% liquid, the gas-liquid two-phase flow in the bent and inclined sections transforms into slug flow, thereby, where become the main areas subjected to corrosion, which is consistent with the detected locations of pipeline leakage at the gas field site. Results of electrochemical test and the fluent simulation indicate that the concentration distribution of corrosion inhibitors at the top and bottom of the pipeline shows a trend of first increasing and then decreasing along the pipeline axis, the concentration at the bottom of the pipeline is higher than the corresponding concentration at the top of the corresponding part. The corrosion rate of the electrode in the inclined section is the highest, indicating the minimum coverage of the corrosion inhibitor at the inclined section.

Key words:  inclined pipeline      gas-liquid two-phase flow      continuous injection type corrosion inhibitor      CFD simulations     
Received:  10 April 2024      32134.14.1005.4537.2024.119
ZTFLH:  TE257  
Corresponding Authors:  Hu Junying, E-mail: hujunying01@yeah.net

URL: 

https://www.jcscp.org/EN/10.11902/1005.4537.2024.119     OR     https://www.jcscp.org/EN/Y2025/V45/I3/780

Fig.1  Cloud maps of distributions of gas and liquid phases in the pipeline with 30° inclination angle
Fig.2  Cloud maps of pressure distribution and velocity distribution in the pipeline with 30° inclination angle
Fig.3  Flows of liquid phase at the different cross-sectional positions of the pipeline with 30°inclination angle: (a) horizontal section, (b) bend section, (c) inclined section
Fig.4  Nyquist diagrams of the electrodes at the different positions inside the pipeline (a) and corresponding equivalent circuit model (b)
Electrode positionRs / Ω·cm2Y0 / 10-4 Ω-1·s-n ·cm-2n1Rct / Ω·cm2
Horizontal section43.721.920.93525.0
Bend section26.782.850.90357.0
Inclined section48.333.180.79229.2
Table 1  Fitting data of electrochemical impedance spectroscopies of the electrodes at the different positions of the pipeline with 30° inclination angle
Fig.5  SEM images of the electrodes at the different positions of the pipeline with 30° inclination angle: (a) horizontal section, (b) bend section, (c) inclined section
Fig.6  Concentration distribution of corrosion inhibitor in the pipeline with 30° inclination angle
Fig.7  Maps of concentration distribution of corrosion inhibitor on the cross sections with 0.1 m (a), 0.3 m (b), 0.5 m (c), 1.9 m (d) and 2.1 m (e) from the inlet of 30° inclined pipeline
Fig.8  Nyquist plots of the electrodes at the different locations of 30° inclined pipeline
ElectrodeRs / Ω·cm2CPE1Rf / Ω·cm2CPE2Rct / Ω·cm2
Y0 / 10-4 Ω-1·s-n ·cm-2nY0 / 10-4 Ω-1·s-n ·cm-2n
15.380.1511.033.010.73533.8
25.254.970.644.060.310.94288.6
36.220.64119.013.210.75129.2
42.952.390.432.842.130.81741.1
55.253.440.6134.770.280.901024
65.483.100.7610.360.180.97454.8
75.653.380.803.251.470.86314.4
Table 2  Fitting results of EIS of the electrodes No.1-7 in 30 inclined pipeline
Fig.9  AFM surface images of three typical electrodes No.3 (a), No.5 (b) and No.7 (c)
Fig.10  Concentration distributions of the inhibitor at the top (a) and bottom (b) of the pipeline under the condition of different inlet velocities
[1] Hou B S, Zhang Q H, Li Y Y, et al. A pyrimidine derivative as a high efficiency inhibitor for the corrosion of carbon steel in oilfield produced water under supercritical CO2 conditions [J]. Corros. Sci., 2020, 164: 108334
[2] Zeng D Z, Dong B J, Zeng F, et al. Analysis of corrosion failure and materials selection for CO2-H2S gas well [J]. J. Nat. Gas Sci. Eng., 2021, 86: 103734
[3] Sun H, Blumer D, Swidzinski M, et al. Evaluating corrosion inhibitors for sour gas subsea pipelines [A]. IPTC 2009: International Petroleum Technology Conference [C]. Doha, 2009: cp-151-00060
[4] Si X D. The influence of flow field on single-phase flow-accelerated corrosion at high temperture [D]. Nanjing: Southeast University, 2020
司晓东. 高温单相流管内流场对流动加速腐蚀影响研究 [D]. 南京: 东南大学, 2020
[5] Wu G Y, Yan J, Lan Q, et al. Corrosion and inhibition of low-velocity pipelines for sour gas field in foreign countries [A]. The 18th National Symposium on Corrosion Inhibitors [C]. Chengdu, 2014: 23
吴贵阳, 闫 静, 蓝 琼 等. 国外高酸性气田低流速管线腐蚀现状与防腐蚀措施 [A]. 第十八届全国缓蚀剂学术讨论会论文集 [C]. 成都, 2014: 23
[6] Qing S Z, Zhang X L, Wen Z, et al. Research on causes of corrosion perforation in Changning shale gas gathering pipelines [J]. Mater. Prot., 2021, 54(6): 166
青松铸, 张晓琳, 文 崭 等. 长宁页岩气集气管道内腐蚀穿孔原因探究 [J]. 材料保护, 2021, 54(6): 166
[7] Jiang A G, Zhang J W, Xin Y N, et al. Numerical simulation of multiphase erosion-corrosion of tubes bundles of hydrocracking air cooler [J]. J. Chin. Soc. Corros. Prot., 2019, 39: 192
姜爱国, 张建文, 辛亚男 等. 加氢裂化空冷器管束多相流冲刷腐蚀数值模拟 [J]. 中国腐蚀与防护学报, 2019, 39: 192
doi: 10.11902/1005.4537.2018.003
[8] Huang X S, An S T, Chen C F. Corrosion evaluation on tubular goods for linepipes and optimization of corrosion inhibitor injection in the Puguang gas field [J]. Nat. Gas Ind., 2011, 31(9): 120
黄学松, 安思彤, 陈长风. 普光气田集输管材腐蚀评价及缓蚀剂加药工艺优化 [J]. 天然气工业, 2011, 31(9): 120
[9] Bai Y L, Shen G L, Qin Q Y, et al. Effect of thiourea imidazoline quaternary ammonium salt corrosion inhibitor on corrosion of X80 pipeline steel [J]. J. Chin. Soc. Corros. Prot., 2021, 41: 60
白云龙, 沈国良, 覃清钰 等. 硫脲基咪唑啉季铵盐缓蚀剂对X80管线钢腐蚀的影响 [J]. 中国腐蚀与防护学报, 2021, 41: 60
doi: 10.11902/1005.4537.2020.015
[10] Lv X H, Zhang Y, Yan Y L, et al. Performance evaluation and adsorption behavior of two new mannich base corrosion inhibitors [J]. J. Chin. Soc. Corros. Prot., 2020, 40: 31
吕祥鸿, 张 晔, 闫亚丽 等. 两种新型曼尼希碱缓蚀剂的性能及吸附行为研究 [J]. 中国腐蚀与防护学报, 2020, 40: 31
doi: 10.11902/1005.4537.2019.220
[11] Chen Y M, Dong M, Wang B, et al. Flow-assisted corrosion simulation of natural gas pipeline flow containing sour dissolved gas [J]. Surf. Technol., 2022, 51(8): 298
陈一鸣, 董 美, 王 博 等. 含酸性溶解气的气液两相流管道流致腐蚀模拟 [J]. 表面技术, 2022, 51(8): 298
[12] Fu Z X. The corrosion of slug flow with dissolved CO2 on X60 steel [J]. Oil-Gasfield Surf. Eng., 2009, 28(7): 27
符中欣. 含CO2段塞流对X60钢的腐蚀 [J]. 油气田地面工程, 2009, 28(7): 27
[13] Yang Y, Li J B, Wang S L, et al. Understanding the formation process of the liquid slug in a hilly-terrain wet natural gas pipeline [J]. J. Environ. Chem. Eng., 2017, 5: 4220
[14] Yang Y, Li J B, Wang S L, et al. Gas-liquid two-phase flow behavior in terrain-inclined pipelines for gathering transport system of wet natural gas [J]. Int. J. Pressure Vessels Piping, 2018, 162: 52
[15] Zhang H, Lan H Q, Lin N. A numerical simulation of water distribution associated with internal corrosion induced by water wetting in upward inclined oil pipes [J]. J. Pet. Sci. Eng., 2019, 173: 351
[16] Tang P, Yang J, Zheng J Y, et al. Predicting erosion-corrosion induced by the interactions between multiphase flow and structure in piping system [J]. J. Pressure Vessel Technol., 2009, 131: 061301
[17] Wang Y C, Bierwagen G P. A new acceleration factor for the testing of corrosion protective coatings: flow-induced coating degradation [J]. J. Coat. Technol. Res., 2009, 6: 429
[18] Guan X R, Zhao Y L, Wang J J, et al. Numerical analysis of quasi-steady flow characteristics in large diameter pipes with low liquid loading under high pressure [J]. J. Nat. Gas Sci. Eng., 2015, 26: 907
[19] Liu E B, Tang H, Zhang Y H, et al. Experiment and numerical simulation of distribution law of water-based corrosion inhibitor in natural gas gathering and transportation pipeline [J]. Petrol. Sci., 2023, 20: 1857
[20] Hong T, Sun Y H, Jepson W P. Study on corrosion inhibitor in large pipelines under multiphase flow using EIS [J]. Corros. Sci., 2002, 44: 101
[21] Zeng L, Zhang G A, Guo X P, et al. Inhibition effect of thioureidoimidazoline inhibitor for the flow accelerated corrosion of an elbow [J]. Corros. Sci., 2015, 90: 202
[22] Liao K X, Qin M, He G X, et al. Study on corrosion mechanism and the risk of the shale gas gathering pipelines [J]. Eng. Fail. Anal., 2021, 128: 105622
[23] Ye N, Liao K X, He G X, et al. Research on the corrosion cause analysis and protective measures of shale gas surface gathering pipelines [J]. Mater. Prot., 2021, 54(9) 142
叶 男, 廖柯熹, 何国玺 等. 页岩气地面集输管道腐蚀原因分析及防护措施研究 [J]. 材料保护, 2021, 54(9) 142
[1] GAO Qiuying, ZENG Wenguang, WANG Heng, LIU Yuancong, HU Junying. Effect of Fluid Scouring on Sulfate Reducting Bacteria Induced Corrosion of Pipeline Steel[J]. 中国腐蚀与防护学报, 2023, 43(5): 1087-1093.
No Suggested Reading articles found!