Effect of Vacuum Heat Treatment on Oxidation Behavior of Arc Ion Plated NiCoCrAlY Coatings

doi:10.11902/1005.4537.2021.108

Journal of Chinese Society for Corrosion and protection

2022, Vol. 42

Issue (2): 243-248 DOI: 10.11902/1005.4537.2021.108

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Effect of Vacuum Heat Treatment on Oxidation Behavior of Arc Ion Plated NiCoCrAlY Coatings

LI Ling¹, DU Xiran¹, QU Pinquan¹, LI Jiancheng¹, WANG Jinlong¹(

), GU Yan², ZHANG Jia³, CHEN Minghui¹, WANG Fuhui¹

^1.Shenyang National Key Laboratory for Materials Science, Northeastern University, Shenyang 110819, China
^2.Aero Engine Corporation of China Shenyang Liming aero-engine Co. Ltd. , Shenyang 110043, China
^3.Institute of Metal Research, The Chinese Academy of Sciences, Shenyang 110819, China

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Abstract

MCrAlY coatings are widely used for various parts of high-temperature alloy to enhance their corrosion resistance at high temperatures. However, there still exist unavoidable defects within the as-prepared coating, as well as at the interface coating/substrate, which promotes the initiation of cracking and failure of the coating during service at high temperature, and ultimately limits the service life of the alloy components. In this study, NiCoCrAlY coating was deposited on K417G high temperature alloy by arc ion plating, and the coated alloy samples was vacuum heat treated at 950, 1000 and 1050 ℃ respectively for 4 h. Further, the oxidation behavior of the heat-treated samples were assessed isothermally at 1000 ℃ in air for a long term so that to examine the effectiveness of vacuum heat treatment. Finally, the surface and cross-sectional morphology and phase composition of the oxidized coating/alloy were characterized by means of XRD, SEM with EDS. The results show that after vacuum heat treatment the plated NiCoCrAlY coating is tightly bonded to the substrate alloy, the oxidation mass gain of the coatings is relatively slow, and a uniform and dense oxide scale can form on their surface. Among others, the sample after heat-treated at 1000°C provides the best performance, which exhibits better resistance to scale spallation with lower mass gain.

Key words: MCrAlY coating high temperature oxidation vacuum heat treatment arc ion plating high temperature protective coating

Received: 14 May 2021

ZTFLH:

TG172

Fund: National Natural Science Foundation of China(51801021);the Fundamental Research Funds for the Central Universities(N2102015);the Ministry of Industry and Information Technology Project(MJ-2017-J-99)

Corresponding Authors: WANG Jinlong E-mail: Wangjinlong@mail.neu.edu.cn

About author: WANG Jinlong, E-mail: Wangjinlong@mail.neu.edu.cn

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	Ling LI
	Xiran DU
	Pinquan QU
	Jiancheng LI
	Jinlong WANG
	Yan GU
	Jia ZHANG
	Minghui CHEN
	Fuhui WANG

Cite this article:

LI Ling, DU Xiran, QU Pinquan, LI Jiancheng, WANG Jinlong, GU Yan, ZHANG Jia, CHEN Minghui, WANG Fuhui. Effect of Vacuum Heat Treatment on Oxidation Behavior of Arc Ion Plated NiCoCrAlY Coatings. Journal of Chinese Society for Corrosion and protection, 2022, 42(2): 243-248.

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https://www.jcscp.org/EN/10.11902/1005.4537.2021.108 OR https://www.jcscp.org/EN/Y2022/V42/I2/243

Fig.1 Surface (a~c) and cross-sectional (d~f) morphologies of the coating samples annealed at 950 ℃ (a, d), 1000 ℃ (b,e) and 1050 ℃ (c, f)

Fig.2 XRD patterns of the as-prepared and vacuum annealed NiCoCrAlY coatings

Fig.3 Oxidation kinetics (a) and parabolic constants K_p fitting of the kinetic curves (b) of the annealed samples at 1000 ℃ in air for 100 h

Fig.4 XRD patterns of the samples oxidized at 1000 ℃ for 100 h

Fig.5 Surface (a~d) and cross-sectional (e~h) morphologies of the coating samples oxidized at 1000 ℃ for 100 h of as-prepared (a, e), 950 ℃ (b, f), 1000 ℃ (c, g) and 1050 ℃ (d, h)

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