Preparation and Anticorrosion Performance of M-phenylenediamine-graphene Oxide/Organic Coating

doi:10.11902/1005.4537.2020.272

Journal of Chinese Society for Corrosion and protection

2021, Vol. 41

Issue (2): 161-168 DOI: 10.11902/1005.4537.2020.272

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Preparation and Anticorrosion Performance of M-phenylenediamine-graphene Oxide/Organic Coating

LUAN Hao¹, MENG Fandi¹(

), LIU Li¹(

), CUI Yu², LIU Rui³, ZHENG Hongpeng¹, WANG Fuhui¹

^1.Shenyang National Laboratory for Materials Science, Northeastern University, Shenyang 110819, China
^2.Shi -changxu Innovation Center for Advanced Materials, Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016, China
^3.Shenyang National Laboratory for Materials Science, Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016, China

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Abstract

In order to solve the problems of poor dispersion of graphene oxide (GO) in organic coatings and poor compatibility with resins, m-phenylenediamine, taking as the so called "bridge" material, was grafted on the surface of graphene oxide (GO) via a chemical means to obtain M-GO composite materials. Then the M-GO/epoxy resin E-44 composite anticorrosion coatings were also prepared. The results of FTIR, Raman and TGA showed that amine groups of m-phenylenediamine were successfully bonded with the epoxy group. A few layers of the M-GO composite particulates of lamellar morphology can be observed by transmission electron microscope (TEM), indicating that the dispersibility of GO was improved through m-phenylenediamine-grafting. On the other hand, the cross-sectional morphology of the coating showed that the M-GO composite material also has good compatibility with epoxy resin. In comparison with the epoxy resin coating GO/EP with the inherent graphene oxide GO, the M-GO/EP coating shows far more better anti-corrosion performance, namely, after 1000 h of immersion in 3.5% (mass fraction) NaCl solution, the impedance modulus (|Z^{|_{0.01 Hz}) value of EP/M-GO stayed at 1.0×10⁹ Ω·cm², and after salt spray test for 12 d, the M-GO/EP coating could still provide effective protection for the metal substrate. The results show that the m-phenylenediamine modified graphene oxide/organic coatings present significantly enhanced anti-corrosion performance.}

Key words: graphene oxide organic coating anti-corrosion performance

Received: 24 December 2020

ZTFLH:

TQ323.5

Fund: National Natural Science Foundation of China(51901040);China Postdoctoral Science Foundation;Liao Ning Revitalization Talents Program(XLYC1807076)

Corresponding Authors: MENG Fandi,LIU Li E-mail: fandimeng@mail.neu.edu.cn;liuli@mail.neu.edu.cn

About author: LIU Li, E-mail: liuli@mail.neu.edu.cn
MENG Fandi, E-mail: fandimeng@mail.neu.edu.cn

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	Hao LUAN
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Cite this article:

LUAN Hao, MENG Fandi, LIU Li, CUI Yu, LIU Rui, ZHENG Hongpeng, WANG Fuhui. Preparation and Anticorrosion Performance of M-phenylenediamine-graphene Oxide/Organic Coating. Journal of Chinese Society for Corrosion and protection, 2021, 41(2): 161-168.

URL:

https://www.jcscp.org/EN/10.11902/1005.4537.2020.272 OR https://www.jcscp.org/EN/Y2021/V41/I2/161

Fig.1 Schematic diagram of the surface modification of GO by m-phenylenediamine

Fig.2 FT-IR spectra of GO and M-GO

Fig.3 TGA curves of GO and M-GO

Fig.4 Raman spectra of GO and M-GO

Fig.5 Photos showing the contact angles of water drops on GO (a) and M-GO (b)

Fig.6 Visual illustrations of GO (a) and M-GO (b) dispersed in epoxy resin for different time

Fig.7 TEM images of GO (a) and M-GO (b)

Fig.8 SEM images of cross-sectional microstructures of EP/GO (a) and EP/M-GO (b) coatings

Fig.9 Water absorption curves of EP/GO and EP/M-GO coatings

Fig.10 Nyquist (a~d) and Bode (e, f) plots of EP/GO (a, b, e) and EP/M-GO (c, d, f) coatings after immersion in 3.5%NaCl solution for different time

Fig.11 Equivalent electrical circuits of EIS of EP/GO and EP/M-GO coatings: (a) the first stage (0~2 h), (b) the second starge (100~1000 h)

Fig.12 Variations of coating resistance R_c of two coatings with immersion time

Fig.13 Stress-strain curves of EP/GO and EP/M-GO coatings

Fig.14 Visual performances of EP/GO (a) and EP/M-GO (b) coatings on steel substrates to salt spray test for different time

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