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Journal of Chinese Society for Corrosion and protection  2015, Vol. 35 Issue (5): 474-478    DOI: 10.11902/1005.4537.2014.186
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Wetting Characteristics and Regularity of AISI4135 Steel in Marine Splash Zone
Yanliang HUANG1(),Xiuming YU1,2,Min ZHENG1,2,Wenjuan QU1,2,Prasad Yadav Amar1,De Marco Roland3
1. Key Laboratory of Marine Environment Corrosion and Marine Fouling, Institute of Oceanology, Chinese Academy of Sciences, Qingdao 266071, China
2. University of Chinese Academy of Sciences, Beijing 100049, China
3. University of the Sunshine Coast, Queensland 4558, Australia
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Abstract  

The corrosion rate of steels in marine splash zone is high, and it is generally considered to be due to the environmental characteristics of this zone. One of the important distinctions between the marine splash zone and the normal atmospheric zone is the wetting condition of steel surfaces. However even in the same splash zone, the corrosion rate of one spot is different to that of the other ones on the surface of one steel pile, thereby on which a corrosion rate peak should exist at a specific spot. In order to reveal the nature of the difference in corrosion rate at different positions of a steel pile, the variations of the wetting condition of steel specimens with tidal movement was monitored, while the specimens located at different positions along a vertical line passing the tide zone. It follows that the wetting degree of the steel specimen in the splash zone is closely related with its location and the tidal movement, and which substantially follows an overall trend that the wetting degree increases with the rising tide level and decrease with the lowering tide level; the wetting degree of the steel specimen increases with the increase of exposure time. But for a specific moment, a certain relationship dose not exist for the wetting degree with the tide movement and the location of steel specimen. Even though by the time of the low tide level the steel specimen located in splash zone is still in a wet condition due to the effect of the high air humidity and flying seawater foam, which correlates also to the high moisture absorption characteristics of corrosion products scale on the carbon steel. The extreme corrosion rate of the steel in splash zone corresponds to a specific wetting degree. Furthermore, on the area below the extreme point, thin water film on the surface of steel specimens can often be observed by naked eyes, which is consistent with the relationship between corrosion rate and thickness of liquid film on the metal surface.

Key words:  iron and steel      splash zone      wetting condition     
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Yanliang HUANG, Xiuming YU, Min ZHENG, Wenjuan QU, Prasad Yadav Amar, De Marco Roland. Wetting Characteristics and Regularity of AISI4135 Steel in Marine Splash Zone. Journal of Chinese Society for Corrosion and protection, 2015, 35(5): 474-478.

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https://www.jcscp.org/EN/10.11902/1005.4537.2014.186     OR     https://www.jcscp.org/EN/Y2015/V35/I5/474

Fig.1  Schematic of the apparatus for the test of wetting condition of steel samples at splash zone: (a) wetting condition test shelf for steel samples, (b) circuit diagram of a steel sample
Fig.2  Variations of wetting degree for specimens at splash zone with tide level
Fig.3  Variation of wetting degree for No.1 specimen at splash zone with tide level in 04.06.2013
Fig.4  Variations of wetting degree for specimens at low

tide level with exposure time

Fig.5  Variations of average wetting degree for specimens at splash zone with exposure time
Fig.6  Variation of average wetting degree for specimens with the location above high tide line
Fig.7  Appearances of seawater droplet on specimens without (a) and with (b) rust
Fig.8  Water vapor absorption on specimens without (a) and with (b) rust
Fig.9  Corrosion rate of carbon steel exposed in splash zone for 3 months in Qingdao sea area[9]
Fig.10  Relationship between corrosion rate and wetting degree for carbon steel in splash zone
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