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PHOSPHATING TECHNOLOGY AND PHOSPHATING FILM PROPERTY AT ROOM TEMPERATURE BEFORE ELECTROPHORETIC COATING |
CHEN Zemin1;ZHANG Qiaoyun2;LI Zhilin2 |
1.College of Chemistry and Materials Science; Langfang Teachers College; Langfang 065000
2.College of Chemistry and Environmental Science; Hebei University; Baoding 071002 |
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Abstract A novel phosphating processing that nickel salt, manganese salt, nitro acenaphthene and carboxyl group polymer were contained in self-made Zn system phosphating, was developed for electrophoretic coating. Compared low Zn-Mn phosphating film with common phosphating film, the former in corrosion resistance and alkali resistance is better than the latter. The investigation and analysis of composition and structure of the low Zn-Mn phosphating film and common phosphating film are conducted by means of XPS and SEM. The experiment results demonstrated that by applying this phosphating process, a complete,alkaliproof and firm crystal film made up of Zn3(PO4)2、FeZn2(PO4)2 and Mn Zn2(PO4)2 sphere phosphide formed on metal surface in less than ten minutes at room temperature.
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Received: 26 March 2007
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Corresponding Authors:
CHEN Zemin
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