|
|
STUDY ON THE DIFFUSING BEHAVIOROF WATER THROUGH EPOXY COATINGS BY EIS |
Bin Liu;Ying Li;Haichao Lin |
中科院沈阳金属研究所;金属腐蚀与防护国家重点实验室 |
|
|
Abstract The diffusing behavior of water through epoxy coati ngs with different pigment volume concentration(PVC) has been studied by electro chemical impedance spectroscopy(EIS).The corresponding diffusion coefficients we re calculated and the effect of PVC on the diffusing behavior were studied.The e xperiment results showed that,in 0.5 mol/L NaCl solution,the diffusion process o f water through epoxy coatings with different PVC followed the second Fick di ffusion law in the initial period.Within the PVC value concerned(35%~50%),the d iffusion coefficients decreased with increasing PVC.When PVC was less than critical pigment volume concentration(CPVC),the obstruction effect by the pigme nt plates was the main factor influencing the diffusing process of water through epoxy coatings.
|
Received: 15 March 2001
|
|
Corresponding Authors:
Bin Liu
|
[1]LIUBin,LIYing,LINHaichao,CAOChu′nan.EffectofPVConthediffusingbehaviorofwaterthroughalkydcoatings[J].ActaPhysico-ChimicaSinica,2001,17(3):241(刘斌,李瑛,林海潮,曹楚南.颜料体积浓度对水在醇酸涂层中传输行为的影响[J].物理化学学报,2001,17(3):241) [2]LindqvistSA .Theoryofdielectricpropertiesofheterogeneoussub stancesappliedtowaterinapaintfilm[J].Corrosion,1985,41(2):69 [3]WalterGW .Applicationofimpedancemethodstostudytheeffectsofwateruptakeandchlorideionconcentrationonthedegradationofpaintfilms-Ⅱ.Freefilmsandattached/freefilmcomparisons[J].Corros.Sci.,1991,32(10):1085 [4]ThomasNL .Thebarrierpropertiesofpaintcoatings[J].ProgressinOrganicCoatings,1991,19(2):101 [5]MiskovicStankovicVB ,DrazicDM ,TeodorovicMJ.Electrolytepenetrationthroughepoxycoatingselectrodepositedonsteel[J].Corros.Sci.,1995,37(2):241 [6]WindMM ,LendrinkHJW .Acapacitancestudyofpseudo-fick iandiffusioninglassypolymercoatings[J].ProgressinOrganicCoatings,1996,28(4):239 [7]PerezC ,CollazoA ,IzquierdoM ,MerinoP ,NovoaXR .Characteri zationofthebarrierpropertiesofdifferentpaintsystemsPartⅠ.Experimentset-upandidealfickiandiffusion[J].ProgressinOr ganicCoatings,1999,36(2):102 [8]PerezC ,CollazoA ,IzquierdoM ,MerinoP ,NovoaXR .Characteri zationofthebarrierpropertiesofdifferentpaintsystemsPartⅡ.Non-idealdiffusionandwateruptakekinetics[J].ProgressinOr ganicCoatings,1999,37(2):169 [9]CastelaASL ,SimoesAM ,FerreiraMGS .EISevaluationofat tachedandfreepolymerfilms[J].ProgressinOrganicCoatings,2000,38(1):1 [10]HuldenM ,HansenCM .Waterpermeationincoatings[J].ProgressinOrganicCoatings,1985,13(3):171 [11]AmirudinA ,ThierryD .Applicationofelectrochemicalimpedancespectroscopytostudyefficiencyofanticorrosivepigmentsinepoxy-polyamideresin[J].Br.Corros.J.,1995,30(2):128 |
No Suggested Reading articles found! |
|
|
Viewed |
|
|
|
Full text
|
|
|
|
|
Abstract
|
|
|
|
|
Cited |
|
|
|
|
|
Shared |
|
|
|
|
|
Discussed |
|
|
|
|