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Study on Corrosion inhibition by N-Sulfonic Amino-Dimethylenephosphonic Acid |
Wenzhong Yang; |
南京化工大学 |
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Abstract The corrosion inhibition by SADP(N-sulfonic amino-dimethylene phosphonic acid) on 0Cr13 stainless steel was studied by linear polarization and anodic polarization curve methods in 0.10mol/L H2SO4 solutions, compared with HEDP(1-hydroxyethylidene-1, 1-diphosphonic acid) and ATMP(aminotrimethylenephosphonic acid).It was found that these three phosphonic acids have remarkable inhibition effect on the corrosion of 0Cr13 stainless steel in H2SO4 solutions. The corrosion inhibiton mechanism by SADP、HEDP、ATMP on 0Cr13 was found to be the geometric blocking effect. Results showed that the adsorption of all these three phosphonic acids follows the Langmuir adsorption isotherm. The order in the corrosion inhibition effciency may be arranged as follows:ηSADP>ηATMP>ηHEDP.
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Received: 02 April 1999
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Corresponding Authors:
Wenzhong Yang
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[1 ]徐寿昌等 .工业冷却水处理技术 [M].北京 :化学工业出版社 ,1 986 .2 2 7. [2 ]周本省 .工业冷却水系统中金属的腐蚀与防护 [M] 北京 :化学工业出版社 ,1 993.6 7. [3]曹楚南 .关于缓蚀剂研究的电化学方法 [A],第六届全国缓蚀剂学术讨论会论文集 (上 ) [C] 沈阳 :中国腐蚀与防护学会缓蚀剂专业委员会 ,中国科学院金属腐蚀与防护研究所 ,1 989.1 . [4 ]查全性等 .电极过程动力学导论 (第二版 ) [M],北京 :科学出版社 ,1 987.74. |
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