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J Chin Soc Corr Pro  1999, Vol. 19 Issue (1): 21-26     DOI:
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INFLUENCE OF SOME ANIONS ON METASTABLE PITTING BEHAVIOR
Yu Zuo;;
北京化工大学 材料科学与工程学院
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Abstract  The influence of Cl-,SO42-,PO43- and Cro42- anions on the nucleation,growth and repassivation rates of metastable pitting of an amorphous alloy was studied using potentiostatic polarization method.During the repassivation period of metastable pits,the relation between current and time followed Imax I=R(t-tmax),with the repassivation rate parameter R following a lognormal distribution.Increased Cl- concentration resulted in faster nucleation and growth rates for metastable pits.The presence of SO42-,PO43- and CrO42- anions decreased both the nucleation rate and the growth rate of metastable pits.The inhibitive effects of these three anions on nucleation and growth of metastable pits decrease in the order:CrO42->PO43->SO42-.The anions affected the R values only in a very small extent.
Key words:  metastable pitting      anions      growth rate      
Received:  15 July 2005     
Corresponding Authors:  Yu Zuo   

Cite this article: 

Yu Zuo. INFLUENCE OF SOME ANIONS ON METASTABLE PITTING BEHAVIOR. J Chin Soc Corr Pro, 1999, 19(1): 21-26 .

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https://www.jcscp.org/EN/     OR     https://www.jcscp.org/EN/Y1999/V19/I1/21

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