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INFLUENCE OF SOME ANIONS ON METASTABLE PITTING BEHAVIOR |
Yu Zuo;; |
北京化工大学 材料科学与工程学院 |
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Abstract The influence of Cl-,SO42-,PO43- and Cro42- anions on the nucleation,growth and repassivation rates of metastable pitting of an amorphous alloy was studied using potentiostatic polarization method.During the repassivation period of metastable pits,the relation between current and time followed Imax I=R(t-tmax),with the repassivation rate parameter R following a lognormal distribution.Increased Cl- concentration resulted in faster nucleation and growth rates for metastable pits.The presence of SO42-,PO43- and CrO42- anions decreased both the nucleation rate and the growth rate of metastable pits.The inhibitive effects of these three anions on nucleation and growth of metastable pits decrease in the order:CrO42->PO43->SO42-.The anions affected the R values only in a very small extent.
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Received: 15 July 2005
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Corresponding Authors:
Yu Zuo
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1Williams D E, Westcott C, Fleischmann M J.J.Electrochem. Soc, 1985, 132: 1796 2Frankel G S, Stockert L, Hunkeler F; Boehni H. Corrosion, 1987, 43: 429 3Pistorius P C, Burstein G T. Phil. Thans. Roy. Soc.; 1992, A341: 531 4Pistorius P C, Burstein G T. Corros. Scui., 1992, 33: 1855 5Leckie H P, Uhlig H H.J. Electrochem. Soc., 1996, 113: 1262 6左禹,符适.中国腐蚀与防护学报,1997,17:161 7Issacs G S. Corros. Sci., 1989; 29: 313 |
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