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J Chin Soc Corr Pro  1987, Vol. 7 Issue (1): 1-7    DOI:
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SOLUBILITIES OF α-Fe_2O_3, Fe_3O_4 AND Cr_2O_3 IN FUSED Na_2SO_4 AT 1200K
Zhang Yunshu (Shanghai Institute of Metallurgy;Academia Sinica) Robert A. Rapp (The Ohio State University;U.S.A.)
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Abstract  The solubilities of α-Fe_2O_3, Fe_3O_4 and Cr_2O_3 in fused Na_2SO_4 have been measured as a function of Na_2SO_4 melt basicity at 1200K and at 1 arm and lower oxygen pressures. Results are in agreement with the thermodynamic expectations. From the solubility measurements, the basic and acidic solutes of the oxides in molten Na_2SO_4 have been derived and their activity coefficients have also been determined. The solubility studies may be of assistance in understanding fluxing and electrochemical mechanisms of hot corrosion.
Received:  25 February 1987     
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Zhang Yunshu (Shanghai Institute of Metallurgy;Academia Sinica) Robert A. Rapp (The Ohio State University;U.S.A.). SOLUBILITIES OF α-Fe_2O_3, Fe_3O_4 AND Cr_2O_3 IN FUSED Na_2SO_4 AT 1200K. J Chin Soc Corr Pro, 1987, 7(1): 1-7.

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https://www.jcscp.org/EN/     OR     https://www.jcscp.org/EN/Y1987/V7/I1/1

[1] Gupta, D. K.; Rapp, R. A. J. Electrochem. Soc., 127, 2194, 2656(1980)
[2] Jose, P. D.; Gupta, D. K; Rapp, R. A., ibid., 132, 735 (1985)
[3] Zhang, Y. S.; Rapp, R. A.,ibid., 132 , 734 , 2498(1935)
[4] Zhang, Y. S., ibid., 133, 655 (1986)
[5] Deanhardt, M. L.; Stern, K. H, ibid., 128 , 2577(1981)
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