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SOLUBILITIES OF α-Fe_2O_3, Fe_3O_4 AND Cr_2O_3 IN FUSED Na_2SO_4 AT 1200K |
Zhang Yunshu (Shanghai Institute of Metallurgy;Academia Sinica) Robert A. Rapp (The Ohio State University;U.S.A.) |
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Abstract The solubilities of α-Fe_2O_3, Fe_3O_4 and Cr_2O_3 in fused Na_2SO_4 have been measured as a function of Na_2SO_4 melt basicity at 1200K and at 1 arm and lower oxygen pressures. Results are in agreement with the thermodynamic expectations. From the solubility measurements, the basic and acidic solutes of the oxides in molten Na_2SO_4 have been derived and their activity coefficients have also been determined. The solubility studies may be of assistance in understanding fluxing and electrochemical mechanisms of hot corrosion.
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Received: 25 February 1987
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Cite this article:
Zhang Yunshu (Shanghai Institute of Metallurgy;Academia Sinica) Robert A. Rapp (The Ohio State University;U.S.A.). SOLUBILITIES OF α-Fe_2O_3, Fe_3O_4 AND Cr_2O_3 IN FUSED Na_2SO_4 AT 1200K. J Chin Soc Corr Pro, 1987, 7(1): 1-7.
URL:
https://www.jcscp.org/EN/ OR https://www.jcscp.org/EN/Y1987/V7/I1/1
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[1] Gupta, D. K.; Rapp, R. A. J. Electrochem. Soc., 127, 2194, 2656(1980) [2] Jose, P. D.; Gupta, D. K; Rapp, R. A., ibid., 132, 735 (1985) [3] Zhang, Y. S.; Rapp, R. A.,ibid., 132 , 734 , 2498(1935) [4] Zhang, Y. S., ibid., 133, 655 (1986) [5] Deanhardt, M. L.; Stern, K. H, ibid., 128 , 2577(1981) |
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