NH+4浓度对N80钢在饱和CO2 的3%NaCl溶液中腐蚀行为的影响

doi:10.11902/1005.4537.2023.173

中国腐蚀与防护学报

2024, Vol. 44

Issue (3): 745-754 CSTR: 32134.14.1005.4537.2023.173 DOI: 10.11902/1005.4537.2023.173

研究报告

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NH⁺₄浓度对N80钢在饱和CO₂ 的3%NaCl溶液中腐蚀行为的影响

解辉¹^,²^,³, 于超¹^,²^,³, 花靖¹^,²^,³, 蒋秀¹^,²^,³(

)

1.化学品安全全国重点实验室青岛 266100
2.中石化安全工程研究院有限公司青岛 266110
3.应急管理部化学品登记中心青岛 266100

Effect of NH⁺₄ Concentration on Corrosion Behavior of N80 Steel in CO₂-saturated 3%NaCl Solutions

XIE Hui¹^,²^,³, YU Chao¹^,²^,³, HUA Jing¹^,²^,³, JIANG Xiu¹^,²^,³(

)

1. State Key Laboratory of Chemical Safety, Qingdao 266100, China
2. SINOPEC Research Institute of Safety Engineering Co., Ltd., Qingdao 266100, China
3. Registration Center for Chemicals, Ministry of Emergency Management, Qingdao 266100, China

引用本文:

解辉, 于超, 花靖, 蒋秀. NH⁺₄浓度对N80钢在饱和CO₂ 的3%NaCl溶液中腐蚀行为的影响[J]. 中国腐蚀与防护学报, 2024, 44(3): 745-754.
Hui XIE, Chao YU, Jing HUA, Xiu JIANG. Effect of NH⁺₄ Concentration on Corrosion Behavior of N80 Steel in CO₂-saturated 3%NaCl Solutions[J]. Journal of Chinese Society for Corrosion and protection, 2024, 44(3): 745-754.

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摘要:

利用失重法和电化学方法研究了N80钢在不同NH⁺₄浓度下饱和CO₂的3%NaCl溶液中的腐蚀行为，通过SEM、3D轮廓仪、XRD和XPS对腐蚀形貌和腐蚀产物进行表征，阐释了腐蚀机理。结果表明，NH⁺₄浓度对N80钢的腐蚀速率产生促进和抑制双重效果。当NH⁺₄浓度为0~500 mg/L时，N80钢的均匀腐蚀速率随NH⁺₄浓度增加而增加；当NH⁺₄浓度增加至1000~2000 mg/L时，N80钢的均匀腐蚀速率随NH⁺₄浓度增加而降低，且点蚀速率随NH⁺₄浓度的变化规律与均匀腐蚀基本相同；当NH⁺₄浓度为500 mg/L时，均匀腐蚀速率和小孔腐蚀速率最大。当NH⁺₄浓度≤500 mg/L时，NH⁺₄和Cl^-在金属表面发生了竞争吸附；当NH⁺₄浓度大于500 mg/L时，NH⁺₄在金属表面发生吸附对腐蚀起抑制作用。

关键词 ： N80钢, 饱和CO₂环境, NH⁺₄腐蚀, NH⁺₄吸附

Abstract：

NH₄Cl was one of the important factors causing corrosion of tubing steel in shale oil environment. Herewith, the effect of NH⁺₄ concentration on the corrosion behavior of N80 steel in 3%NaCl solution saturated with CO₂ was studied by means of mass loss method, electrochemical methods, scanning electron microscope (SEM), 3D profilometer, X-ray diffraction(XRD), and X-ray photoelectron spectroscopy (XPS). The results showed that NH⁺₄ concentration had a dual effect on the corrosion rate of N80 steel, i.e. promoting and inhibiting the corrosion rate. When the NH⁺₄ concentration was 0~500 mg/L, the uniform corrosion rate of N80 steel increased with the increasing NH⁺₄ concentration, while in the NH⁺₄ concentration range of 1000~2000 mg/L, the uniform corrosion rate of N80 steel decreased with the increasing NH⁺₄ concentration, however, the pitting corrosion rate showed a similar trend as the uniform corrosion. When the NH⁺₄ concentration was 500 mg/L, the uniform corrosion rate and pitting corrosion rate of N80 steel were the highest. Competition adsorption occurred between NH⁺₄ and Cl^- on the metal surface at NH⁺₄ concentrations ≤ 500 mg/L, while NH⁺₄ adsorption inhibited corrosion when NH⁺₄ concentration exceeded 500 mg/L.

Key words： N80 steel saturated CO₂ environment NH⁺₄ corrosion NH⁺₄ absorption

收稿日期: 2023-05-22 32134.14.1005.4537.2023.173

ZTFLH:

TG174

基金资助:中国石油化工股份有限公司科技攻关项目(320144)

通讯作者: 蒋秀，E-mail：jiangx.qday@sinopec.com，研究方向为油气系统及CO2储运系统的设备腐蚀防护与安全

Corresponding author: JIANG Xiu, E-mail: jiangx.qday@sinopec.com

作者简介: 解辉，男，1996年生，硕士，助理工程师

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图1 N80钢金相显微组织

图2 不同NH+4浓度的3%NaCl溶液中N80钢的腐蚀速率

图3 不同NH+4浓度的3%NaCl溶液中N80钢的自腐蚀电位

图4 不同NH+4浓度的3%NaCl溶液中N80钢的线性极化电阻和腐蚀速率

图5 不同NH+4浓度的3%NaCl溶液中N80钢的动电位极化曲线

图6 不同NH+4浓度的3%NaCl溶液中N80钢的电化学阻抗图

图7 符合EIS数据的等效电路图

表1 N80钢的EIS拟合数据

图8 不同NH+4浓度的3%NaCl溶液中N80钢的(Rm + Rct)值的变化

图9 在不同NH+4浓度的3%NaCl溶液中N80钢的腐蚀形貌、3D轮廓图和腐蚀产物元素组成

图10 在不同NH+4浓度的3%NaCl溶液中N80钢腐蚀产物的XRD谱图

图11 在不同NH+4浓度3%NaCl溶液中N80钢腐蚀产物的XPS谱图

图12 N原子在N80钢表面吸附机理示意图

1	Sun B Z, Zhou X C, Li X R, et al. Stress corrosion cracking behavior of 316L stainless steel with varying microstructure in ammonium chloride environment [J]. J. Chin. Soc. Corros. Prot., 2021, 41: 811
1	孙宝壮, 周霄骋, 李晓荣等. 不同组织的316L不锈钢在NH₄Cl环境下应力腐蚀行为与机理 [J]. 中国腐蚀与防护学报, 2021, 41: 811 doi: 10.11902/1005.4537.2020.172
2	Huang J H, Yuan X, Chen W, et al. Effect of temperature on corrosion behavior of pipeline steels N80 and TP125V in artificial CO₂-saturated fracturing fluid of shale gas [J]. J. Chin. Soc. Corros. Prot., 2023, 43: 251
2	黄家和, 袁曦, 陈文等. 温度对CO₂饱和页岩气压裂液环境中N80和TP125V钢腐蚀行为影响研究 [J]. 中国腐蚀与防护学报, 2023, 43: 251 doi: 10.11902/1005.4537.2022.076
3	An D P, Feng Y J. Prospective prospect of shale oil exploration and development [N]. China Electric Power News, 2022-09-05(003)
3	安栋平, 冯义军. 页岩油勘探开发前景可期 [N]. 中国电力报, 2022-09-05(003)
4	Qiao R W, Li F X, Zhang S C, et al. CO₂ mass transfer and oil replacement capacity in fractured shale oil reservoirs: from laboratory to field [J]. Front. Earth Sci., 2021, 9: 794534 doi: 10.3389/feart.2021.794534
5	Lan Y, Yang Z Q, Wang P, et al. A review of microscopic seepage mechanism for shale gas extracted by supercritical CO₂ flooding [J]. Fuel, 2019, 238: 412 doi: 10.1016/j.fuel.2018.10.130
6	Zhang Y X, He J M, Li X, et al. Experimental study on the supercritical CO₂ fracturing of shale considering anisotropic effects [J]. J. Petrol. Sci. Eng., 2019, 173: 932 doi: 10.1016/j.petrol.2018.10.092
7	Xiong Q, Hu J Y, Gu C R, et al. The study of under deposit corrosion of carbon steel in the flowback water during shale gas production [J]. Appl. Surf. Sci., 2020, 523: 146534 doi: 10.1016/j.apsusc.2020.146534
8	Zhao G X, Wang Y C, Zhang S Q, et al. Influence mechanism of H₂S/CO₂-charging on corrosion of J55 steel in an artificial solution [J]. J. Chin. Soc. Corros. Prot., 2022, 42: 785
8	赵国仙, 王映超, 张思琦等. H₂S/CO₂对J55钢腐蚀的影响机制 [J]. 中国腐蚀与防护学报, 2022, 42: 785 doi: 10.11902/1005.4537.2021.262
9	Wu G Y, Zhao W W, Wang Y R, et al. Analysis on corrosion-induced failure of shale gas gathering pipelines in the southern Sichuan Basin of China [J]. Eng. Fail. Anal., 2021, 130: 105796 doi: 10.1016/j.engfailanal.2021.105796
10	Li D G, Feng Y R, Bai Z Q, et al. Characteristics of CO₂ corrosion scale formed on N80 steel in stratum water with saturated CO₂ [J]. Appl. Surf. Sci., 2007, 253: 8371 doi: 10.1016/j.apsusc.2007.04.011
11	Xing X S, Fan B T, Zhu X Y, et al. Corrosion characteristics of P110SS casing steel for ultra-deep well in artificial formation water with low H₂S and high CO₂ content [J]. J. Chin. Soc. Corros. Prot., 2023, 43: 611
11	幸雪松, 范白涛, 朱新宇等. 低H₂S和高CO₂分压下超深井用P110SS油套管钢腐蚀特征研究 [J]. 中国腐蚀与防护学报, 2023, 43: 611 doi: 10.11902/1005.4537.2022.225
12	Cheng Y P, Bai Y, Li Z L, et al. The corrosion behavior of X65 steel in CO₂/oil/water environment of gathering pipeline [J]. Anti-Corros. Methods Mater., 2019, 66: 174 doi: 10.1108/ACMM-07-2018-1969
13	Alaba P A, Adedigba S A, Olupinla S F, et al. Unveiling corrosion behavior of pipeline steels in CO₂-containing oilfield produced water: towards combating the corrosion curse [J]. Crit. Rev. Solid State Mater. Sci., 2020, 45: 239 doi: 10.1080/10408436.2019.1588706
14	Ni Y Y, Yao L M, Sui J L, et al. Isotopic geochemical characteristics and identification indexes of shale gas hydraulic fracturing flowback water/produced water [J]. Nat. Gas Geosci., 2022, 33: 78
14	倪云燕, 姚立邈, 隋建立等. 页岩气压裂返排液/采出水同位素地球化学特征与鉴别指标 [J]. 天然气地球科学, 2022, 33: 78
15	Zhang Y L, Han L, Liu X H. Corrosion behavior of several kinds of steel in NH₄Cl environment [J]. Corros. Prot., 2014, 35: 711
15	张艳玲, 韩磊, 刘小辉. 几种钢材在NH₄Cl环境中的腐蚀行为 [J]. 腐蚀与防护, 2014, 35: 711
16	Li R D, Huang H, Wang X D, et al. Effect of ammonium salt on corrosion of pipelines and components in a crude oil distillation column: Electrochemical and AIMD studies [J]. Corros. Sci., 2022, 203: 110362 doi: 10.1016/j.corsci.2022.110362
17	Wang H B, Yu J P, Lu C S. Investigation of the corrosion behavior of mild steel in the NH₄Cl/CO₂ corrosive medium [J]. Trans. Indian Inst. Met., 2021, 74: 2631 doi: 10.1007/s12666-021-02303-9
18	Duan Y F, Zhao X Y, Li C F, et al. Study on corrosion of carbon steel and alloy steel in ammonium chloride solution [J]. Corros. Prot. Petrochem. Ind., 2017, 34(1): 8
18	段永锋, 赵小燕, 李朝法等. 碳钢及合金钢在氯化铵溶液中腐蚀规律研究 [J]. 石油化工腐蚀与防护, 2017, 34(1): 8
19	Toba K, Ueyama M, Kawano K, et al. Corrosion of carbon steel and alloys in concentrated ammonium chloride solutions [J]. Corrosion, 2012, 68: 1049 doi: 10.5006/0587
20	Gu Y. Research on the corrosion behavior and corrosion resistance mechanism of low C medium Cr steel in CO₂ EOR gathering & transportation environment [D]. Beijing: University of Science and Technology Beijing, 2020
20	顾洋. 低C中Cr钢在CO₂驱集输环境中的腐蚀行为及耐蚀机制研究 [D]. 北京: 北京科技大学, 2022
21	Human A M, Exner H E. Electrochemical behaviour of tungsten-carbide hardmetals [J]. Mater. Sci. Eng., 1996, 209A: 180
22	Kahyarian A, Brown B, Nesic S. Electrochemistry of CO₂ corrosion of mild steel: Effect of CO₂ on iron dissolution reaction [J]. Corros. Sci., 2017, 129: 146 doi: 10.1016/j.corsci.2017.10.005
23	Linter B R, Burstein G T. Reactions of pipeline steels in carbon dioxide solutions [J]. Corros. Sci., 1999, 41: 117 doi: 10.1016/S0010-938X(98)00104-8
24	Mora-Mendoza J L, Turgoose S. Fe₃C influence on the corrosion rate of mild steel in aqueous CO₂ systems under turbulent flow conditions [J]. Corros. Sci., 2002, 44: 1223 doi: 10.1016/S0010-938X(01)00141-X
25	Campbell S A, Radford G J W, Tuck C D S, et al. Corrosion and galvanic compatibility studies of a high-strength copper-nickel alloy [J]. Corrosion, 2002, 58: 57 doi: 10.5006/1.3277305
26	Wang H B, Li Y, Cheng G X, et al. Electrochemical investigation of corrosion of mild steel in NH₄Cl solution [J]. Int. J. Electrochem. Sci., 2018, 13: 5268 doi: 10.20964/2018.06.05
27	Jiang X. Corrosion behaviors and inhibition mechanisms for CO₂ corrosion of N80 steel under flowing conditions [D]. Shenyang: Institute of Metals, Chinese Academy of Sciences, 2005
27	蒋秀. 流动条件下N80钢的CO₂腐蚀行为及缓蚀机理研究 [D]. 沈阳: 中国科学院金属研究所, 2005

[1]	黄家和, 袁曦, 陈文, 闫文静, 金正宇, 柳海宪, 刘宏芳, 刘宏伟. 温度对CO₂饱和页岩气压裂液环境中N80和TP125V钢腐蚀行为影响研究[J]. 中国腐蚀与防护学报, 2023, 43(2): 251-260.
[2]	韩帅豪,岑宏宇,陈振宇,邱于兵,郭兴蓬. 原油与高压CO₂共存条件下咪唑啉缓蚀剂的作用行为研究[J]. 中国腐蚀与防护学报, 2017, 37(3): 221-226.
[3]	鲁照玲,郭兴蓬. 月桂酸在CO₂饱和盐水溶液中缓蚀行为和机理研究[J]. 中国腐蚀与防护学报, 2010, 30(6): 475-480.
[4]	李党国 . 温度对N80钢饱和CO2地层水中腐蚀电化学性能影响[J]. 中国腐蚀与防护学报, 2008, 28(2): 104-107 .
[5]	马文海; 裴晓含; 高飞; 高纯良 . N80钢在模拟深层气井水溶液中的CO2腐蚀行为[J]. 中国腐蚀与防护学报, 2007, 27(1): 8-13 .
[6]	陈长风; 路民旭; 赵国仙 . 含1%Cr的N80钢CO2腐蚀产物膜特征[J]. 中国腐蚀与防护学报, 2003, 23(6): 330-334 .
[7]	陈长风; 路民旭; 赵国仙 . N80油管钢CO2腐蚀点蚀行为[J]. 中国腐蚀与防护学报, 2003, 23(1): 21-25 .
[8]	陈长风; 赵国仙; 严密林 . 含Cr油套管钢CO2腐蚀产物膜特征[J]. 中国腐蚀与防护学报, 2002, 22(6): 335-338 .
[9]	陈长风; 赵国仙; 路民旭 . N80钢CO2腐蚀产物膜研究[J]. 中国腐蚀与防护学报, 2002, 22(3): 143-147 .

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