熔融结合型环氧粉末涂料固化程度的溶剂萃取法研究

中国腐蚀与防护学报

1999, Vol. 19

Issue (3): 151-155

研究报告

本期目录 | 过刊浏览

熔融结合型环氧粉末涂料固化程度的溶剂萃取法研究

鲁自界;李劲;周钟泉

中国科学院金属研究所

STUDY ON CURING DEGREE OF FUSION-BONDED EPOXY BY SOLVENT EXTRACTION

Zijie Lu;;;

全文: PDF(130 KB)

摘要: 以丁酮为萃取溶剂，研究了SEBF-2熔融结合型环氧粉末涂层自由膜在160℃～230℃经不同时间固化后的萃取固化度。用温度-时间重叠技术分析了涂膜固化反应动力学过程，并用扫描电镜观察了萃取形貌。结果表明，在160℃～230℃之间。萃取固化度随温度升高与时间的延长而增加；在230℃经长时间固化，涂膜发生热降解。在研究温度范围内，萃取固化反应呈现单一激活能，表明固化过程主要受单一反应机制所控制。

关键词 ：环氧粉末涂料, 萃取, 固化

Abstract：Solvent extraction method has been set up to evaluate the degree of cure(DOC)of a new type of fusion-bonded epoxy(FBE)coating obtained under different curing conditons.The specimens were extracted in hot 2-butanone.The results showed that the DOC increased with the increase in curd temperature and curd time from 160 to 230℃.Heat decompositon was observed for the coating cured at 230℃.horizontal shifts of the DOC vs In(time)curves at defferent cure temperatures resulted in a master curve.The kinetically controlled reaction yielded a single Arrhenius activation energy (91.4kJ/mol).It implied that there was only one overall reaction mechanism in the temperature range under stuey.The surface morphology observation of the extracted samples was carried out under SEM,which verified the feasibility of solvent extraction method.

Key words： fusion-bonded epoxy(FBE) solvent extraction cure

收稿日期: 2005-07-22

通讯作者: 鲁自界

Corresponding author: Zijie Lu

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引用本文:

鲁自界; 李劲; 周钟泉 . 熔融结合型环氧粉末涂料固化程度的溶剂萃取法研究[J]. 中国腐蚀与防护学报, 1999, 19(3): 151-155 .
Zijie Lu. STUDY ON CURING DEGREE OF FUSION-BONDED EPOXY BY SOLVENT EXTRACTION. J Chin Soc Corr Pro, 1999, 19(3): 151-155 .

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https://www.jcscp.org/CN/ 或 https://www.jcscp.org/CN/Y1999/V19/I3/151

1 Raymond B S.J. Coat. Techn., 1987, 59(745): 49
2 Thomas D. Finishing, 1985, 9(4): 29
3 河本纪熊.日本技报,1982,21(1):4
4 Denms N. Mater. Perfom, 1993, 32(2): 49
5 Dennis N. Mater. Perfom, 1994, 33(11): 26
6 余兰萍.涂料工业,1995,1:3

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