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中国腐蚀与防护学报  2012, Vol. 32 Issue (3): 173-182    
  综合评审 本期目录 | 过刊浏览 |
NiAl相的化学互扩散系数表征
韦华,金涛,孙晓峰
中国科学院金属研究所 沈阳 110016
CHEMICAL INTERDIFFUSION COEFFICIENTS OF NiAl PHASE
WEI Hua, JIN Tao, SUN Xiaofeng
Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016
全文: PDF(3303 KB)  
摘要: 综述了Ni-Al二元系、Ni-Cr-Al三元系、Ni-Co-Cr-Al四元系NiAl相的化学互扩散系数,并在此基础上,借助DICTRA软件的PARROT模块,构建了NiAl相的扩散迁移率数据库,以计算多元系NiAl相的化学互扩散系数。
关键词 NiAl相扩散系数Mobility数据库    
Abstract:NiAl phase is a typical Hume-Rothery compound with excellent oxidation-resistant property so this phase is often used as master phase of aluminide coatings. Because diffusion phenomena is extremely important for formation and degradation of aluminide coatings, it is possible to understand the natural characteristics of the diffusion phenomena controlling the degradation of aluminide coatings through chemical diffusion coefficients of NiAl phase obtained. This work reviews chemical diffusion coefficients of NiAl phase in the Ni-Al binary system, the Ni-Cr-Al ternary system, and the Ni-Co-Cr-Al quaternary system. Based on the obtained chemical diffusion coefficients of NiAl phase, the mobility database of NiAl phase is set up using the PARRAT module in the commercial DICTRA software for determining chemical diffusion coefficients of NiAl phase in the multiphase systems.
Key wordsNiAl phase    diffusion coefficient    mobility database
收稿日期: 2011-04-26     
ZTFLH: 

TG146

 
基金资助:

国家重点基础研究发展规划项目(2010CB631200,2010CB631206)和国家自然科学基金项目(509310 04,51071164,
U1037601和50671102)资助

通讯作者: 韦华     E-mail: hwei@imr.ac.cn
Corresponding author: WEI Hua     E-mail: hwei@imr.ac.cn
作者简介: 韦华,男,1974年生,博士,研究员,研究方向为高温合金及腐蚀防护

引用本文:

韦华,金涛,孙晓峰. NiAl相的化学互扩散系数表征[J]. 中国腐蚀与防护学报, 2012, 32(3): 173-182.
WEI Hua. CHEMICAL INTERDIFFUSION COEFFICIENTS OF NiAl PHASE. J Chin Soc Corr Pro, 2012, 32(3): 173-182.

链接本文:

https://www.jcscp.org/CN/      或      https://www.jcscp.org/CN/Y2012/V32/I3/173

[1] Van A T.Method of manufacturing thin-walled corrosion resistant metallic objects[P].US Patent,No.1155974.1915
[2] Li M S.High Temperature Oxidation of Metals [M].Beijing:Metallugical Industry Press,2001
(李美栓.金属的高温腐蚀[M].北京:冶金工业出版社,2001)
[3] Padture N P,Maurice G,Jordan E H.Thermal barriercoatings for gas-turbine engine applications [J].Science,2002,296:280-284
[4] Walston W S,Darolia R.Baker I ed.High temperature ordered intermetallic alloys V[M].MRS,Symp.Proc.,1993,288:237
[5] Nagraj S K,Kyung T H.Superheating behavior of NiAl [J].Metall.Trans.,1998,29A:2221-2225
[6] Noebe R D,Bowman R R,Nathal M V.Physical and mechanical properties of the B2 compound NiAl [J].Int.Mater.Rev.,1993,38:193-232
[7] Hening E T,Lukas H L.Enthalpies of formation of AlNi:Experiment versus theory [J].Z.Metallk.,1975,66:98-103
[8] Fox A G,Tabbernor M A.High Temperature Intermetallic [M].London:The Institute of Metals,1991:219
[9] Cooper M J.The electron distribution in the phases CoAl and NiAl [J].Philos.Mag.,1963,8:811-821
[10] Fox A G.Tatlokc G J,ed.Electron Microscopy and Analysis [C].Inst.Phys.Conf.Ser.,Briston,Adam Hilger,1985:379
[11] Fox A G,Tabbernor M A.The bonding charge density of β'NiAl [J].Acta Metall.Mater.,1991,39; 669-678
[12] Fu C L,Yoo M H.Johnson L,et al.High Temperature Ordered Intermetallics Alloys IV [C].MRS.Symp.Porc.,1991,667
[13] Fu C L.Izumi O.In Proc.Int.Symp.on intermetallic Compounds Structure and Mechanical Properties [C].Sendai:Japanese Institute of Metals,1991,387
[14] Hughes T,Lautenschlager E P,Cohen J B,et al.X-Ray diffraction investigation of β'-NiAl Alloys [J].J.Appl.Phys.,1971,42:3705-3716
[15] Taylor A,Doyle N J.Further studies on the nickel-aluminium system.I.β-NiAl and β-Ni2Al3 phase fields [J].J.Appl.Cryst.,1972,5:201-209
[16] Bradley A J,Taylor A.Electric and magnetic properties of B2 structure compounds:NiAl,CoAl [J].Proc.Royal Soc.,1937,159A; 56
[17] Georgopoulos P,Cohen J B.The defect structure and Debye Waller factors vs.composition in βNi1±xAl1±x [J].Scr.Metall.,1977,11:147-150
[18] Noebe R D,Bowman R R,Nathal M V.Electronic structure of ordered and disordered transition metal aluminides [J].NASA Technical Paper.,1994,4:3398
[19] Ayushina G D,Levin E S,Geld P V.Ni self-diffusion in refractory Al-Ni melts [J].Russ.J.Phys.Chem.,1971,45:1719
[20] Rusovic N,Warlimont H.The Elastic Behavior of B2NiAI Alloys [J].Phys.State.Sol.,1977,44A:609-619
[21] Kogachi M,Tanahashi T,Shirai Y,et al.Determination of vacancy concentration and defect structure in the B2 type NiAl β-phase alloys [J].Scr.Mater.,1996,34:243-248
[22] Pike L M,Anderson I M,Liu C T,et al.Site occupancies,point defect concentrations,and solid solution hardening in B2 (Ni,Fe)Al [J].Acta Mater.,2002,50:3859-3879
[23] Bornsen N,Bester G.,Meyer B,et al.Analysis of the electronic structure of intermetallic compounds,and application to structural defects in B2 phases[J].J.Alloy.Compd.,2000,308:1-14
[24] Kogachi M,Tanahashi T.Point defect behavior in the B2 type intermetallic compounds CoAl [J].Scr.Mater.,1996,35:849-854
[25] Kim S M,Chang Y A.An interdiffusion study of a NiAl alloy using single-phase diffusion couples [J].Metall.Mater.Trans.,1999,31A:1519-1524
[26] Hancock G F,McDonnell B R.Diffusion in the intermetallic compound NiAl [J].Phys.State.Sol.1971,4(A):143-150
[27] Shankar S,Seigle L L.Interdiffusion and intrinsic diffusion in the Ni AI (β) phase of the Al-Ni system [J].Metall.Trans.,1978,9A:1467-1476
[28] Chang Y A,Neumann J P.Phase stability investigations of the palladium-cadmium system:part ii.structural studies [J].Prog.Solid State Chem.,1982,14:221-302
[29] Nakamura R,Takasawa K,Yamazaki Y,et al.Single-phase interdiffusion in the B2 type intermetallic compounds NiAl,CoAl and FeAl [J].Intermetallics,2002,10:195-204
[30] Ansara I,Dupin N,Lukas H L,et al.Thermodynamic assessment of the Al-Ni system [J].J.Alloy.Comp.,1997,247:20-30
[31] Temkin M.Calculation and representation of phase equilibria in NiAl [J].Acta Phys.Chemd.,1945,20:411-420
[32] Sundman B,Jansson B,Andersson J O.The Thermo-Calc databank system [J].CALPHAD.1985,9:153-190
[33] Helander T.Some application of CALPHAD techniques to diffusion reactions in gradient materials [D].Dept.of Materials Science and Engineering,Div.of Physical Metallurgy.Royal Institute of Technology.Stockholm,Sweden.1999
[34] Helander L,Agren J.A phenomenological treatment of diffusion in Al-Fe and Al-Ni alloys having B2-b.c.c.ordered structure [J].Acta Mater.,1999,47:1141-1152
[35] Dey G K.Physical metallurgy of nickel aluminides [J].S adhand a,2003,28:247-262
[36] Matthew O Z,Gary S C.Diffusion Mechanisms in Crystalline Materials[A],Mishin Y M,Cowan N E B,Catlow C R A,eds.Mater.Res.Soc.Symp.Proc[C].1998:203
[37] Svoboda J,Fischer F D,Fratzl P,et al.Diffusion in multi-component systems with no or dense sources and sinks for vacancies [J].Acta Mater.,2002,50:1369-1381
[38] Bornsen N,Bester G,Meyer B,et al.Analysis of the electronic structure of intermetallic compounds,and application to structural defects in B2 phases [J].J.Alloy.Compd.,2000,308:1-14
[39] Wei H,Sun X F,Zheng Q,et al.Estimation of interdiffusivity of the NiAl phase in Ni-Al binary system [J].Acta Mater.,2004,52:2645-2651
[40] Wei H,Sun X F,Zheng Q,et al.Calculation of interdiflusion coefficients of Ni and Al atoms in β-NiAl phase as aluminide coatings[J].Acta Metall.Sin.,2004,40(1):51-56
    (韦华,孙晓峰,郑启等.铝化物涂层中β-NiAl相Ni,Al互扩散系数计算 [J].金属学报,2004,40(1):51-56)
[41] Wei H,Sun X F.Reply to comments on interdiffusion in the β phase region of the Ni-Al-Cr system [J].Scr.Mater.,2010,62:632-634
[42] Hou G C,Wei H,Zhao N R,et al.Interdiffusion in the β phase region of the Ni-Al-Cr system [J].Scr Mater.,2008,58:57-60
[43] Thompson M S,Mortal J E.Applications of the square root diffusivity to diffusion in Ni-Al-Cr alloys [J].Acta Metall.,1986,34:2201-2203
[44] Wei H,Zhang H Y,Sun X F,et al.Interdiffusion within theβ-phase region of the Ni-Co-Cr-Al quaternary system [J].J.Alloys Compd.,2010,493:507-512
[45] Wei H,Zhang H Y,Hou G C,et al.On interdiffusion in the multicomponent β-NiAl phase [J].J.Alloys Compd.,2009,481:326-335
[46] Wei H,Guan H R,Sun X F,et al.Calculation of interdiffusivity of Ni and Al in aluminide coating formed on K465superalloy[J].J.Chin.Soc.Corros.Prot.,2004,24(5):257-261
    (韦华,管恒荣,孙晓峰等.K465高温合金铝化物层Ni/Al互扩散系数计算 [J].中国腐蚀与防护学报,2004,24(5):257-261)
[47] Wei H,Sun X F,Zheng Q,et al.Estimation of interdiffusivities of the pseudo NiAl binary phase formed in a nickel-based superalloy by pack cementation [J].J.Mater.Res.,2005,9:2340-2347
[48] Wei H,Sun X F,Zheng Q,et al.A finite difference met-hod for determining interdiffusivity of aluminide coating formed on superalloy [J].J.Mater.Sci.Technol.,2004,20:595-598
[49] Wei H,Sun X F,Zheng Q,et al.Effect of substrate characteristics on interdiffusion coefficients of Ni and Al atoms in β-NiAl phase of aluminide coatings [J].J.Mater.Sci.Technol.,2004,20:196-200
[50] Kirkaldy J S,Young D J.Diffusion in the Condensed State [M].London:The Institute of Materials,1987
[51] Jonsson B.Assessment of the mobility of carbon in fcc C-Cr-Fe-Ni alloys [J].Z.Metallkd.,1994,85:502
[52] Andersson J O,Hoglund L,Jonsson B,et al.In:Purdy G R,ed.Fundamentals and Applications of Ternary Diffusion[M].New York:Pergamon Press,1990,153-163
[53] Sundman B,Jansson B,Andersson J O.The Thermo-Calc databank system [J].CALPHAD,1985,9:153-190
 
 
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