K_2SO_4-Na_2SO_4沉积引起的Fe-Cr合金的低温热腐蚀

中国腐蚀与防护学报

1991, Vol. 11

Issue (1): 17-24

研究报告

本期目录 | 过刊浏览

K_2SO_4-Na_2SO_4沉积引起的Fe-Cr合金的低温热腐蚀

张允书;李选明;史良权;石声泰

中国科学院上海冶金研究所;中国科学院上海冶金研究所;中国科学院上海冶金研究所;中国科学院上海冶金研究所

K_2SO_4-Na_2SO_4 INDUCED LOW TEMPERATURE HOT CORROSION OF Fe-Cr ALLOYS

Zhang Yunshu Li Xuauming Shi Liangquan Shih Shengtai (Shanghai Institute of Metallurgy;Academia Sinica)

全文: PDF(1033 KB)

摘要: 研究了 Fe—Cr 合金在有 K2SO_4-Na_2SO_4盐膜存在时的低温热腐蚀行为。测定涂盐的 Fe-Cr合金于 O_2-0.1、0.5和1.0%(SO_2+SO_3)气氛中在560～750℃温度区间腐蚀动力学曲线,并对腐蚀产物进行物理观察和化学分析。结果表明,当有 K_2SO_4-Na2SO_4盐膜存在时,铬含量低于某一临界值的 Fe—Cr 合金会发生低温热腐蚀,这归因于 K—Na—Fe 三元低熔点复合硫酸盐的形成。Fe~(3+)被认为参与了电化学阴极反应,Fe~(3+)/Fe~(2+)在熔盐层中的相对迁移将气相中 O_2和SO_3的主要还原反应移至熔盐/气相交界面进行,从而导致快速热腐蚀。铬是减轻和抑制低温热腐蚀的有效元素。

Abstract：Low temperature hot corrosion (LTHC)behavior of Fe-Cr alloys with 5 to 50 (wt)% of chromium in the presence of a K_2SO_4-Na_2SO_4 salt film was studied in O_2- 0.1,0.5 and 1.0% (SO_2+SO_3) gas environments in the temperature range of 560 to 750℃.Corrosion kinetics were measured gravimetrically,and corrosion product scales were physically examined and chemically analyzed.The experimental results indicate that the alloys with chromium contents below a certain critical value are subject to LTHC.The LTHC is related to the formation of a low melting complex sulfate containing K,Na and Fe.Fe~(3+) is believed to take part in the reduction reaction,and the countertransport of Fe~(3+)/Fe~(3+)carries the reduction reaction of O_2 and SO_3 to the melt/gas interface,which is responsible for the rapid corrosion.It is also indicated that the addition of chromium re- sults in higher LTHC resistance of iron base alloys.

收稿日期: 1991-02-25

基金资助:中国科学院腐蚀科学开放研究实验室课题;;国家基金委资助

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引用本文:

张允书;李选明;史良权;石声泰. K_2SO_4-Na_2SO_4沉积引起的Fe-Cr合金的低温热腐蚀[J]. 中国腐蚀与防护学报, 1991, 11(1): 17-24.
. K_2SO_4-Na_2SO_4 INDUCED LOW TEMPERATURE HOT CORROSION OF Fe-Cr ALLOYS. J Chin Soc Corr Pro, 1991, 11(1): 17-24.

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https://www.jcscp.org/CN/ 或 https://www.jcscp.org/CN/Y1991/V11/I1/17

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