薄层防锈油膜的透水和透氧行为

中国腐蚀与防护学报

1992, Vol. 12

Issue (1): 41-48

研究报告

本期目录 | 过刊浏览

薄层防锈油膜的透水和透氧行为

徐乃欣;张承典;陆菊芳;王志杰

中国科学院上海冶金研究所;中国科学院上海冶金研究所;中国科学院上海冶金研究所;中国科学院上海冶金研究所

PERMEATION BEHAVIOUR OF WATER AND OXYGEN THROUGH THIN LAYER RUST PREVENTIVE OIL

Xu Naixin; Zhang Chengdian; Lu Jufang; and Wang Zhijie (Shanghai Institute of Metallurgy; Academia Sinica)

全文: PDF(558 KB)

摘要: 本文利用吸油滤纸形成的薄层油膜开展了实验研究。研究结果表明,受试验的两种防锈油的透水和透氧行为与它们的基础油基本相同,同时,透过薄层防锈油的水和氧远远超过了通常条件下金属发生大气腐蚀时所需的数量。这说明防锈油不是依靠阻碍水和氧的扩散而起作用的。

Abstract：There are two possible concepts on mechanism of inhibition of thin layer rust preventive oils (RPO). The first explanation is the chemisorption of inhibitors present in RPO on metallic substrate. Another is the lower permeability of water and oxygen through RPO. The main purpose of this work is to evaluate the contribution due to the second mechanism. For experimental investigation, the oil films were prepared by soaking filter paper with the oil under study. The permeability of the oil film to water was determined in terms of the weight loss of water from a container covered with oiled filter paper. Oxygen diffusion tests were conducted on the basis of the change of oxygen concentration in a chamber as a result of passage of oxygen through oil film measured by coulometric oxygen sensor. Two RPOs showing satisfactory rust prevention performance were tested. No difference is observed in water and oxygen permeation behaviour between the two RPOs and their uninhibited base oil. It means that the presence of thinhibitors in RPO has little effect on permeability. The data on water and oxygen permeation rate obtained also show that RPO films are so permeable to water and oxygen that they cannot inhibit corrosion by impeding diffusion of these two corrodents. It could be concluded that the inhibitive action of RPO is not dependent on the prevention of water and oxygen permeation.

收稿日期: 1992-02-25

基金资助:中国科学院腐蚀科学开放实验室课题

	服务

	把本文推荐给朋友
	加入引用管理器
	E-mail Alert
	RSS
	作者相关文章
	徐乃欣
	张承典
	陆菊芳
	王志杰
44.8K

引用本文:

徐乃欣;张承典;陆菊芳;王志杰. 薄层防锈油膜的透水和透氧行为[J]. 中国腐蚀与防护学报, 1992, 12(1): 41-48.
. PERMEATION BEHAVIOUR OF WATER AND OXYGEN THROUGH THIN LAYER RUST PREVENTIVE OIL. J Chin Soc Corr Pro, 1992, 12(1): 41-48.

链接本文:

https://www.jcscp.org/CN/ 或 https://www.jcscp.org/CN/Y1992/V12/I1/41

[1] Szauer, T..Klenowicz. Z. and Szklarska-Smialowska, Z. , Corrosion, 36(8) ,400(1980)
[2] Szauer, T., Klenowiez, Z. and Szklarska-Smialowska, Z. ,Corrosion,36(9) ,482(1980)
[3] Helwig.L. E., Materials Performance, 25(5) , 26(1986)
[4] 陈有义、朱百善译,防锈油,中国工业出版社(1966) 。转引自朱韶勇,材料保护,22(10) ,4(1989) 参考文献[12]
[5] 周静好编著,防锈技术,化学工业出版社,P41(1988)
[6] ASTM D3985-81 Test Method for Oxygen Gas Transmission Rate Through Plastic Film and Sheeting Using a Coulometric Sensor
[7] 傅献彩,陈瑞华编,物理化学(下册),高等教育出版社,(1980)
[8] 查全性等著,电极过程动力学导论(第二版),科学出版社,P96(1987)

No related articles found!

Viewed

Full text

Abstract

Cited

Shared

Discussed