电泳涂装常温磷化工艺及磷化膜性能

中国腐蚀与防护学报

2008, Vol. 28

Issue (6期): 351-354

研究报告

本期目录 | 过刊浏览

电泳涂装常温磷化工艺及磷化膜性能

陈泽民¹;张巧云²;李志林²

1.廊坊师范学院化学与材料科学学院廊坊 065000
2.河北大学化学与环境科学学院保定 071002

PHOSPHATING TECHNOLOGY AND PHOSPHATING FILM PROPERTY AT ROOM TEMPERATURE BEFORE ELECTROPHORETIC COATING

CHEN Zemin¹;ZHANG Qiaoyun²;LI Zhilin²

1.College of Chemistry and Materials Science; Langfang Teachers College; Langfang 065000
2.College of Chemistry and Environmental Science; Hebei University; Baoding 071002

全文: PDF(935 KB)

摘要:

在自制的低温锌系磷化液基础上，通过加入镍盐、锰盐和羧基聚合物，并以硝基苊为促进剂，研制出了一种适用于电泳涂装的低锌锰改性常温磷化工艺。用扫描电镜和能谱仪对低锌锰改性磷化膜与普通锌系磷化膜的形貌和组成进行对比分析。结果表明，该工艺制备出的磷化膜耐蚀性和耐碱性均优于普通锌系磷化膜；该磷化工艺可在常温下10 min内在金属表面形成完整、致密、耐碱性好的磷化膜，它是由Zn3(PO4)2、FeZn2(PO4)2、Mn Zn2(PO4)2组成的椭球状磷酸盐晶体薄膜。

关键词 ：电泳涂装, 常温磷化, 性能测试

Abstract：

A novel phosphating processing that nickel salt, manganese salt, nitro acenaphthene and carboxyl group polymer were contained in self-made Zn system phosphating, was developed for electrophoretic coating. Compared low Zn-Mn phosphating film with common phosphating film, the former in corrosion resistance and alkali resistance is better than the latter. The investigation and analysis of composition and structure of the low Zn-Mn phosphating film and common phosphating film are conducted by means of XPS and SEM. The experiment results demonstrated that by applying this phosphating process, a complete,alkaliproof and firm crystal film made up of Zn3（PO4）2、FeZn2（PO4）2 and Mn Zn2（PO4）2 sphere phosphide formed on metal surface in less than ten minutes at room temperature.

Key words： electrophoretic coating phosphating technology at room temperature performance test

收稿日期: 2007-03-26

ZTFLH:

TG174

通讯作者: 陈泽民 zhangqy810@sina.com

Corresponding author: CHEN Zemin

	服务

	把本文推荐给朋友
	加入引用管理器
	E-mail Alert
	RSS
	作者相关文章
	陈泽民
44.8K

引用本文:

陈泽民张巧云李志林. 电泳涂装常温磷化工艺及磷化膜性能[J]. 中国腐蚀与防护学报, 2008, 28(6期): 351-354.
CHEN Ze-Min. PHOSPHATING TECHNOLOGY AND PHOSPHATING FILM PROPERTY AT ROOM TEMPERATURE BEFORE ELECTROPHORETIC COATING. J Chin Soc Corr Pro, 2008, 28(6期): 351-354.

链接本文:

https://www.jcscp.org/CN/ 或 https://www.jcscp.org/CN/Y2008/V28/I6期/351

[1]Gong M,Zhang Y S,Zeng Y.Middle temperature phosphating process on steel[J].Mater.Prot.,1999,32(4):27-28(龚敏,张远声,曾毅.钢铁的中温磷化工艺[J].材料保护,1999,32(4):27-28)
[2]Wang Q S,Tang Y S.A study of monocomponent,environment-friendly and medium temperature phosphating solution[J].Elec-troplat.Poll.Control,2002,22(2):19-22(王秋实,唐耀胜.单组分环保型中温锌钙系磷化液的研究[J].电镀与环保,2002,22(2):19-22)
[3]Huang N S,Guo L S.A new low phophating solution used at room temperature[J].Corros.Prot.,2001,22(2):61-63(黄霓裳,郭良生.新型常温低渣磷化液[J].腐蚀与防护,2001,22(2):61-63)
[4]Wichelhaws J,Yasutare M,Tamotsu S,et al.U.S Pat.,5328526,1994
[5]Liang G.Quick organic phosphating at room temperature[J].Met.Finish.,1997,(9):54-60
[6]Tang C H.Application of light Fe-Zn series colorful phosphating agents in finishing pretreatment[J].Modern Paint Finish.,2003,28(3):30-32(唐春华.轻铁锌系磷化剂在涂装前处理中的应用[J].现代涂料与涂装,2003,28(3):30-32)
[7]Tang C H,Tang B.Discussion on color film phosphating process[J].Electroplat.Finish.,2006,25(9):30-31(唐春华,唐彬.彩膜磷化工艺探讨[J].电镀与涂饰,2006,25(9):30-31)
[8]Meng W J.Colorific ambient temperature Zn-Fe system phosphat-ing technology and its application[J].Surf.Technol.,2001,30(1):41-43(蒙文坚.常温锌铁系彩色磷化工艺的应用[J].表面技术,2001,30(1):41-43)
[9]Gabriele B,Mathiao K,Klausjoepg K,et al.U.S Pat.,5773090,1995

[1]	岳增武,傅敏,李辛庚,田学雷. 内壁喷丸处理对TP304H耐热钢锅炉管抗水蒸汽氧化性能的影响[J]. 中国腐蚀与防护学报, 2012, 32(2): 137-140.
[2]	丁杰,张本革,闫明珍,刘佳. 添加稀土元素对Ni-P/PVDF化学复合镀层耐蚀性的影响[J]. 中国腐蚀与防护学报, 2012, 32(2): 123-126.
[3]	张勇,覃作祥,许鸿吉,常凯,陆兴,佟维. 经济型铁素体不锈钢与耐候钢异种金属接头的耐蚀性能[J]. 中国腐蚀与防护学报, 2012, 32(2): 115-122.
[4]	闫瑞霞,杜翠薇,刘智勇,李晓刚. 敏化态00Cr12Ti的动电位电化学阻抗谱特征研究[J]. 中国腐蚀与防护学报, 2011, 31(6): 419-425.
[5]	陆晓峰,朱晓磊,凌祥. 一种预测异径管流动加速腐蚀速率的新模型[J]. 中国腐蚀与防护学报, 2011, 31(6): 431-435.
[6]	饶思贤,万章,宋光雄,张铮,钟群鹏. 基于规则的晶间腐蚀和氢致开裂的失效模式诊断[J]. 中国腐蚀与防护学报, 2011, 31(4): 260-264.
[7]	郏义征，王俭秋,韩恩厚,柯伟. X100管线钢在恒载荷作用下的应力腐蚀开裂[J]. 中国腐蚀与防护学报, 2011, 31(3): 184-189.
[8]	刘存,赵卫民,艾华,王勇,董立先. 电弧喷涂铝涂层的腐蚀电化学行为[J]. 中国腐蚀与防护学报, 2011, 31(1): 62-67.
[9]	鲁照玲,郭兴蓬. 月桂酸在CO₂饱和盐水溶液中缓蚀行为和机理研究[J]. 中国腐蚀与防护学报, 2010, 30(6): 475-480.
[10]	刘薇,王佳. 海洋浪溅区环境对材料腐蚀行为影响的研究进展[J]. 中国腐蚀与防护学报, 2010, 30(6): 504-512.
[11]	丁毅, 赵骏,师红旗,马立群. 高压加氢换热器Ω环开裂失效分析[J]. 中国腐蚀与防护学报, 2010, 30(5): 413-415.
[12]	王朋飞;李春福;邓洪达;崔士华;陈功剑;申文竹. H₂S/CO₂共存体系中钢界面反应的暂态研究[J]. 中国腐蚀与防护学报, 2010, 30(2): 97-1000.
[13]	韦华;黄粮;梁静静;孙晓峰;管恒荣;胡壮麒. Re对NiCrAlY涂层热腐蚀行为的影响[J]. 中国腐蚀与防护学报, 2010, 30(2): 150-154.
[14]	顾宝珊;刘建华. 电化学阻抗谱研究pH值对铝合金表面铈盐转化膜形成过程的影响[J]. 中国腐蚀与防护学报, 2010, 30(2): 124-128.
[15]	唐子龙;刘哲. LY12铝合金NaOH介质电解着色膜耐蚀性的电化学评价[J]. 中国腐蚀与防护学报, 2010, 30(1): 25-28.

Viewed

Full text

Abstract

Cited

Shared

Discussed