金属材料在高温碳气氛中的结焦与溶碳行为

中国腐蚀与防护学报

2004, Vol. 24

Issue (3): 188-192

综述

本期目录 | 过刊浏览

金属材料在高温碳气氛中的结焦与溶碳行为

李处森;杨院生

Coking and Carburizing Behaviors of Metal Materials in High Temperature Carbon-Containing Atmosphere

;

全文: PDF(227 KB)

摘要: 叙述了碳气氛温度、金属材料种类及表面状态、构成碳源的气体种类、比例及流速等因素对金属材料结焦行为的影响，介绍了催化结焦的引发机理及其应用。然后以FeCrNi合金为例，分别介绍了内部渗碳和金属粉化这两种渗碳行为，并叙述了温度、碳气氛、合金材料晶体结构及成分构成的影响。最后分析了结焦和渗碳的关系，并介绍了添加结焦抑制剂、调整金属材料结构及成分构成、表面涂层化3种防护对策。

关键词 ：金属材料, 结焦, 渗碳, 金属粉化

Abstract：This paper reviews some factors affecting the coking behaviors of metal materials,which are the temperature of the carbon-containing atmosphere, the kinds and the surface state of metal materials, and the kinds and ratio and flowing velocit of the gases forming the carbon-containing atmosphere,and then introduces the initiating mechanism of catalytic coking and its applications. Taking the Fe-Cr-Ni alloy as an example, the paper also respectively introduces two kinds of carburizing behaviors, i.e. inner carburizing and metal dusting , and then reviews the effects of temperature, carbon-containing atmosphere, as well as crystal structure and element constitution of the alloy on the inner carburizing and metal dusting . Finally the relations between coking and carburizing are analyzed, and three kinds of protective methods including adding coking inhibitor,adjusting structure and element constitution of metal materials, and preparing coating are introduced.

Key words： metallic materials coking carburizing metal dusting

收稿日期: 2002-05-25

ZTFLH:

O621.25+4.2

	服务

	把本文推荐给朋友
	加入引用管理器
	E-mail Alert
	RSS
	作者相关文章
	李处森
	杨院生
44.8K

引用本文:

李处森; 杨院生 . 金属材料在高温碳气氛中的结焦与溶碳行为[J]. 中国腐蚀与防护学报, 2004, 24(3): 188-192 .
. Coking and Carburizing Behaviors of Metal Materials in High Temperature Carbon-Containing Atmosphere. J Chin Soc Corr Pro, 2004, 24(3): 188-192 .

链接本文:

https://www.jcscp.org/CN/ 或 https://www.jcscp.org/CN/Y2004/V24/I3/188

[1]BakerRTK ,YatesDJC ,DumesicJA .Mechanismofcarbonfor mationduringsteamcrackingofhydrocarbon[A].The182 ndMeet ingoftheAmericanChemicalSociety[C].NewYork,1981,1-5
[2]GrabkeHJ .Carburization(Ahightemperaturecorrosion phe nomenon)[M ].MTIPublications,1998,No.52,1-4
[3]ZhouSu.Thedevelopmentoftechnology producingethylenebycrackingtube[A].TheResearchInstituteofYangziPetrochemicalCorporationLtd.1998,October,1-8.(周素.管式裂解炉制乙烯技术的进展[A].扬子石油化工股份有限公司研究院,1998年10月,1-8)
[4]LahayeJ,BadieP ,DucretJ .Mechanismofcarbonformationduringsteamcrackingofhydrocarbons[J].Carbon,1977,15:87-93.
[5]TomaszewiczP ,JacksonPRS ,TrimmDL ,YoungDJ .Morpho logicalstudiesofcokingonheat-resistantalloy[J].J .Mater.Sci.,1985,20:4035-4044
[6]JacksonPRS ,TrimmDL ,YoungDJ.Thecokingkineticsofheatresistantausteniticsteelinhydrogen-propyleneatmospheres[J].J .Mater.Sci.,1986,21:3125-3134
[7]MitchellDRG ,YoungDJ.Akineticandmorphologicstudyofthecokingofsomeheat-resistantsteels[J].J .Mater.Sci.,1994,29:4357-4370
[8]ChenGR ,ShiJ,etal.EncyclopediaofChemicalEngineering(Chi na)(Vol.18)[M ].Beijing:ChemicalIndustryPress,1993,856-858(陈冠荣,时钧等编,化工百科全书(18)[M ].北京:化学工业出版社,1993,856-858)
[9]WuXQ ,YangYS ,ZhanQ ,HuZQ .Surfacecokingbehavioron25Cr35Niheat-resistantalloy[J].Corros.Sci.Prot.Technol.,1999,11(5):274-278(吴欣强,杨院生,詹倩,胡壮麒.25Cr35Ni耐热合金表面结焦机制[J].腐蚀科学与防护技术,1999,11(5):274-278)
[10]BoehmHP .Carbonfromcarbonmonoxidedisproportiononnickelandironcatalyst:morphologicalstudiesandpossiblegrowthmech anisms[J].Carbon,1973,11:583-590
[11]AlstrupI.Anewmodelexplainingcarbonfilamentgrowthonnick el,ironandNi-Cualloycatalysts[J].J .Catalysis,1988,109:247-251
[12]WuXQ .Studyondesignandfabricationandpropertiesofnewtypeofcoking-resistanttubematerials,PH .Ddissertation[D].Shenyang:InstituteofMetalResearch,TheChineseAcademyofSciences,1999,43-57(吴欣强博士学位论文:新型抗结焦裂解炉管材料的设计、制备与性能[D].沈阳:中国科学院金属研究所,1999,43-57)
[13]ZhouSu.Thedevelopmentoftechnologyproducingethylenebycrackingtube[A].TheResearchInstituteofYangziPetrochemicalCorporationLtd.,1998,October,16-19(周素.管式裂解炉制乙烯技术的进展[A].扬子石油化工股份有限公司研究院,1998年10月,16-19)
[14]LiCS ,YuL ,YangYS .Cokingbehaviorsofthreekindsofmetalsandtheiroxidefilmsduringthermalcrackingreactionofhydrocar bons[J].J.Chin.Soc.Corros.Prot.,2001,21(3):158-166(李处森,于力,杨院生.三种金属及其氧化物膜在碳氢化合物热裂解反应中结焦行为的研究[J].中国腐蚀与防护学报,2001,21(3):158-166)
[15]BakerRTK .Catalyticgrowthofcarbonfilaments[J].Carbon,1989,27(3):315-323
[16]SnoeckJW ,FromentGF ,FowlesM .Filamentouscarbonforma tionandgasification:thermodynamicsdrivingforce,nucleationandsteady-stategrowth[J].J.Catalysis,1997,169:240-249
[17]SnoeckJW ,FromentGF ,FowlesM .Kineticstudyofcarbonfila mentformationbymethanecrackingonanickelcatalyst[J].J .Catalysis,1997,169:250-262
[18]DongGX ,ZhangL .InvestigationonthecokinganddecokingmechanismonNicatalystsforsteamreformingofheptane[J].ChineseJ .Catalysis,1995,16(3):183-189(董国兴,张鎏.Ni系水蒸气转化催化剂积碳和消碳机理探讨[J].催化学报,1995,16(3):183-189)
[19]JacksonPRS ,YoungDJ,TrimmDL .Cokedepositiononandre movalfrommetalsandheat-resistantalloyundersteam-crackingconditions[J].J.Mater.Sci.,1986,21:4376-4384
[20]YangZQ ,ShenZM ,ChenXH ,ZhaXF .PreparationofcurvedcarbonnanotubesusingCo-catalyzedpyrolysis[J].NewCarbonMaterials,2000,15(2):34-38(杨子芹,沈曾民,陈晓红,查旭峰.Co催化热分解制备弯曲状碳纳米管的研究[J].新型碳材料,2000,15(2):34-38)
[21]ErmakvaMA ,ErmakvDYu,KuvshinovGG ,PlyasovaIM .Newnickelcatalystsfortheformationoffilamentouscarboninthereac tionofmethanedecomposition[J].J .Catalysis,1999,187:77-84
[22]GrabkeHJ,WolfI.Carburizationandoxidation[J].Mater.Sci.Eng.,1987,87:23-33
[23]LiuJY ,ChangSC .TheoxidationandcarburizationofFe-Mn-Alalloysinacarbon-containingatmosphere[J].Corros.Sci.,1997,39(6):1021-1035
[24]GrabkeHJ .Carburization(Ahightemperaturecorrosion phe nomenon)[M ].MTIPublications,1998,52:68-69
[25]MassalskiThaddeusB ,OkamotoHiroaki,SubramansanPR ,etal.BinaryAlloyPhaseDiagrams(secondedition)[M ].WilliamW .Scott.Jr,ASMInternational,USA ,1990,1:866
[26]GrabkeHJ ,KrajakR ,Muller-LorenzEM .Metaldustingofhightemperaturealloys[J].Mater.Corros.,1993,44:89-97
[27]GrabkeHJ,KrajakR ,Muller-LorenzEM .Protectionofhighal loysteelsagainstmetaldustingbyoxidescales[J].Mater.Cor ros.,1998,49:317-320
[28]PippelE ,WoltersdorfJ ,SchneiderR .MicromechanismsofmetaldustingonFe-baseandNi-basealloys[J].Mater.Corros.,1998,49:309-316
[29]StraubS ,GrabkeHJ.Roleofalloyingelementsinsteelsonmetaldusting[J].Mater.Corros.,1998,49:321-327
[30]KlowerJ ,GrabkeHJ .Muller-LorenzEM .Metaldustingofnickel-basealloys[J].Mater.Corros.,1998,49:328-329
[31]MaierM ,NortonJF ,FramptonPD .Metaldustingof9-20%Crsteelsinincreased pressureenvironmentsat560℃[J].Mater.Corros.,1998,49:330-335
[32]LiCS ,YangYS ,YuL .AkindofglasscoatingforenhancingtheanticokingabilityofFeCrNialloys[J].Mater.Prot.,2001,34(5):13-14(李处森,杨院生,于力.一种能提高FeCrNi合金材料抗结焦能力的玻璃涂层[J].材料保护,2001,34(5):13-14)
[33]DavidEmmensonBrown,JohnTrewrKewtClark.Methodofap plyingalayerofsilicaonasubstrate[P].USP 4099990,1978
[34]SemyonKukes,JesseR .Harris.Methodforreducingcarbonfor mationinathermalcrackingprocess[P].USP 4410418,1983.

[1]	周勇, 左禹, 闫福安. 缓蚀性组分对金属小孔腐蚀的缓蚀作用与机制[J]. 中国腐蚀与防护学报, 2017, 37(6): 487-494.
[2]	林翠,赵晓斌,张翼飞. 金属材料的空化腐蚀行为及影响因素研究进展[J]. 中国腐蚀与防护学报, 2016, 36(1): 11-19.
[3]	袁比飞,郑雁军,荆栋,崔立山,卢贵武. Mn-Cr-O和Mn-Al-O尖晶石碳化行为研究[J]. 中国腐蚀与防护学报, 2011, 31(1): 18-22.
[4]	李处森; 杨院生; 吴欣强 . HP耐热钢结焦、渗碳的原因分析[J]. 中国腐蚀与防护学报, 2002, 22(5): 286-289 .
[5]	柳伟; 郑玉贵; 姚治铭 . 金属材料的空蚀研究进展[J]. 中国腐蚀与防护学报, 2001, 21(4): 250-255 .
[6]	李处森; 于力; 杨院生 . 三种金属及其氧化物膜在碳氢化合物热裂解反应中结焦行为的研究[J]. 中国腐蚀与防护学报, 2001, 21(3): 158-166 .
[7]	吴欣强; 郑玉贵; 柯伟 . 纯镍表面结焦形貌及其影响因素研究[J]. 中国腐蚀与防护学报, 2001, 21(1): 10-18 .

Viewed

Full text

Abstract

Cited

Shared

Discussed