金属晶界在高温氧化中的作用

中国腐蚀与防护学报

2002, Vol. 22

Issue (3): 180-183

综述

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金属晶界在高温氧化中的作用

李铁藩

中科院腐蚀所

THE ROLE OF METALLIC GRAIN BOUNDARY IN HIGH TEMPERATURE OXIDATION

Tiefan Li

中科院腐蚀所

全文: PDF(148 KB)

摘要: 扼要阐述了金属材料晶界在纯金属与合金高温氧化中的作用.指出金属中晶界面积增加(晶粒尺寸减小)有3种效应：改善合金抗氧化性能的有益的正效应，相反为负效应以及双重效应.讨论了金属晶界扩散动力学基本方程的参数，如Tamman 温度及晶粒尺寸对其影响、晶粒形状因子(q)、晶界偏聚因子(s)、晶界夹角(θ)对晶界扩散的影响.最后介绍了晶界作为高速扩散通道对合金晶间内氧化的重要作用.

关键词 ：金属中晶界扩散, 晶粒尺寸, 氧化行为, 晶间内

Abstract：This paper explains the role of metallic materials grain boundary in high temperature oxidation behaviour of pure metals and alloys in brief.There are three effects concerned of increased metallic materials grain boundary area (e.g.decreased grain size):(1) positive (benefici al) effect,improvement on oxidation resistance of metals,(2) in contradiction,ne gative (deleterious) effect,and (3) dual effect.The influences of parameters of fundamental equation of grain boundary diffusion,such as Tammantem perature and influence of grain size on it， factor of grain shape (q)、fact or of GB segregation (s)、grain boundary angle (θ) on the grain boundar y diffusion were discussed,Finally,the importance of grain boundary acted as hig h velocity diffusivity pathways in the intergranular internal oxidation was intr oduced.

Key words： grain boundary diffusion in metals grain size oxidatio n behavior intergranular internal oxidation

收稿日期: 2002-03-14

ZTFLH:

TG172.82

通讯作者: 李铁藩

Corresponding author: Tiefan Li

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引用本文:

李铁藩 . 金属晶界在高温氧化中的作用[J]. 中国腐蚀与防护学报, 2002, 22(3): 180-183 .
Tiefan Li. THE ROLE OF METALLIC GRAIN BOUNDARY IN HIGH TEMPERATURE OXIDATION. J Chin Soc Corr Pro, 2002, 22(3): 180-183 .

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https://www.jcscp.org/CN/ 或 https://www.jcscp.org/CN/Y2002/V22/I3/180

[1]YeChangjiang,LiTiefan,ZhouLongjiang.EffectofgrainsizeontheoxidationbehaviorofNi3AlZrbascalloyatelevatedtemperature[J].ActaMetall.Sin.,1995,31(3):B109(叶长江,李铁藩,周龙江.晶粒尺寸对含Zr的Ni3Al合金氧化行为的影响[J].金属学报,1995,31(3):B109)
[2]CaplanD .EffectofcoldworkonoxidationofFeCralloyinwatervapourat600℃[J].Corros.Sci.,1966,6(11/12):509
[3]HossainMK .EffectofalloymicrostructureonthehightemperatureoxidationofFe10%Cralloy[J].Corros.Sci.,1979,19(12):1031
[4]GigginsCS ,PettitFS .Theeffectofalloygrainsizeandsurfacede formationontheselectionoxidationofchromiuminNiCralloysattemperatureof900℃and1100℃[J].Trans.TMS AIME ,1969,245:2509
[5]GigginsCS ,PettitFS .OxidationofNiCralloysbetween800℃and1200℃[J].Trans.TMS AIME ,1969,245:2495
[6]MerzMD .Theoxidationresistanceoffine grainedsputter deposit ed304stainlesssteel[J].Metall.Trans.,1979,10A :71
[7]WarzeeM ,HennautJ,MauriceM ,SannenandC ,WatyJ .Effectofsurfacetreatmentofthecorrosionofstainlesssteelsinhightempera turewaterandsteam[J].J .Electrochem.Soc.,1965,112(7):670
[8]BasuSN ,YurekGJ .EffectofalloygrainsizeandsiliconcontentontheoxidationofausteniticFeCrNiMnSialloysinpureO2[J].Oxid.Met.,1991,35(1/2):281
[9]BasuSN ,YurerGJ.EffectofalloygrainsizeandsiliconcontentontheoxidationofausteniticFeCrNiMnSialloysinaSO2O2 gasmixture[J].Oxid.Met.,1991,35(5/6):441
[10]GoedjenJG ,ShoresDA .Theeffectofalloygrainsizeonthetran sientoxidationbehaviorofanalumina formingalloy[J].Oxid.Met.,1992,37(3/4):125
[11]HuberP ,GesingerGH .EffectofGrainSixeandY2O3AdditionsontheHotCorrosionBehaviorofIN738,inMaterialsandCoatingstoResistHighTemperatureCorrosion[M].HolmsDR ,RahmelAEd.Beijing:Appl.Sci.Publ.,1978,71
[12]GengShujiang,WangFuhui,ZhuShenglong.Cyclicoxidationbe haviorofasputterednanocrystallinecoatingofIN738superalloy[J].J .ChineseSocietyforCorrosionandProtection,2001,21(6):334(耿树江,王福会,朱圣龙.溅射纳米晶IN738合金涂层的抗循环氧化行为[J].中国腐蚀与防护学报,2001,21(6):334)
[13]LouHanyi,WangFuhui,XiaBangjie,ZhangLixin.Hightempera tureoxidationresistanceofsputteredmicro grainsuperalloyK38G[J].Oxid.Met.,1992,38(3/4):299
[14]LouHanyi,TangYoujun,SunXiaofeng,etal.Oxidationbehaviorofsputteredmicro grainedsuperalloyK17Fathightemperature[J].ActaMetall.Sin.,1994,30:B109(楼翰一,唐幼军,孙晓峰等.K17F高温合金溅射微晶层的抗高温氧化行为[J].金属学报,1994,30:B109)
[15]TakeyamaM ,LiuCT .Effectofperoxidationandgrainsizeonductilityofboron dopedNi3Alatelevatedtemperature[J].ActaMetall.1987,37(10):2681
[16]CaplanD ,CohenM .Effectofcoldworkontheoxidationofironfrom400℃to600℃[J].Corros.Sci.,1966,6(7):321
[17]CaplanD ,GrahamMJ,CohenM .Effectofcoldworkofoxidationofnickelathightemperature[J].J.Electrochem.Soc.,1972,119(9):1205
[18]HusseyRJ,MitchellDF ,GrahamMJ.Thegrowthandstructureofoxidefilmsformedonsinglecuystal(100)andpolycrystallineCrbetween550℃and900℃[J].WerkstoffeundKorrosion,1987,38(10):575
[19]SinghRamanRK ,KhannaAS ,TiwariRK ,GnanamoorttsyJB .In fluenceofgrainsizeontheoxidationresistanceof2.25Cr1Mosteel[J].OxidMet.,1992,37(1/2):1
[20]SinghRamanRK ,GnananroothyJB .Influenceofprior austenitegrainsizeonoxidationbehaviorof9Cr1Mosteel[J].Oxid.Met.,1992,38(5/6):483
[21]SinghRamanRK ,GnanamootloyJB ,RoySK .Synergisticsinflu enceofalloygrainsizeandsiliconcontentonoxidationbehaviorof9Cr1Mosteels[J].Oxid.Met.,1994,42(5/6):335
[22]AbeF ,ArakiH ,YoshidaH ,OkadaM ,WatanabeR .Theeffectofgrainsizeonthecorrosionbehaviorofinconel600inhightempera turesteam[J].Corros.Sci.,1981,21(12):819
[23]MishinY ,HerzigChr,BernodiniJ ,GustW .Grainboundarydiffu tion:fundamentaltorecentdevelopments[J].Inter.Mates.Res.,1997,42(4):155
[24]ShewmonP ,DiffusioninSolid,McGraw-Hill[M ].NewYork,1963
[25]HondrosED ,SeahMP .Segregationtointerfaces[J].Inter.Met.Res.,1977,22(1):262
[26]DumbillS ,BoothlyRM ,WillamsTM .Grainboundarysegrega tioninNimonicPE6[J].Mates.Sci.Technol.,1991,7(5):385
[27]ChenGF ,LouHY .Effectofnanocsystallizationontheoxidefor mationofNi5Cr6ACalloys[J].J.Materl.Sci.Lett.,1999,18:1957
[28]WallworkGR ,HedAZ .Somelimitingfactorsintheuseofalloysathightemperature[J].Oxid.Met.,1971,3:171
[29]ShidaY ,StottFH ,BastowBD ,WiffleDP ,WoodGC .Develop mentofpreferredintergranularoxideinnickel aluminumalloysathightemperature[J].Oxid.Met.,1982,18(3/4):93

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