690 MPa级耐候桥梁钢在模拟工业大气环境下的腐蚀行为研究

doi:10.11902/1005.4537.2021.143

中国腐蚀与防护学报

2022, Vol. 42

Issue (4): 563-572 DOI: 10.11902/1005.4537.2021.143

研究报告

本期目录 | 过刊浏览

690 MPa级耐候桥梁钢在模拟工业大气环境下的腐蚀行为研究

程鹏¹^,², 刘静¹(

), 黄峰¹, 黄先球², 庞涛²

^1.武汉科技大学省部共建耐火材料与冶金国家重点实验室/湖北省海洋工程材料及服役安全工程技术研究中心武汉 430081
^2.宝钢股份中央研究院武汉 430081

Corrosion Behavior of 690 MPa Weathering Bridge Steel in Simulated Industrial Atmosphere

CHENG Peng¹^,², LIU Jing¹(

), HUANG Feng¹, HUANG Xianqiu², PANG Tao²

^1.Hubei Engineering Technology Research Center of Marine Materials and Service Safety, The State Key Laboratory of Refractories and Metallurgy, Wuhan University of Science and Technology, Wuhan 430081, China
^2.Central Research Institute, BaoShan Iron&Steel Co. Ltd., Wuhan 430081, China

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摘要:

采用周期浸润加速腐蚀实验和电化学方法,结合场发射扫描电镜 (FE-SEM)、X射线衍射 (XRD)、电子探针 (EPMA) 等表面测试技术研究了690 MPa高性能耐候桥梁钢在模拟工业大气环境中的腐蚀行为。结果表明,在腐蚀初期,以贝氏体为主的Q690qENH钢的耐蚀性优于含有铁素体和珠光体组织的Q235钢；在腐蚀后期,Q690qENH钢腐蚀速率逐渐减小且远低于Q235钢,Q690qENH钢锈层中Cu、Cr、Ni合金元素的富集提高了锈层的致密性和稳定性,对腐蚀性介质的抵抗作用更强,锈层保护性参数α/γ*更大。电化学结果也表明,Q690qENH钢的锈层电阻及线性极化电阻更大,保护作用更强,因此在模拟工业大气环境中耐蚀性明显优于Q235钢。

关键词 ： 690, MPa级桥梁钢, 耐候性, 工业大气环境

Abstract：

The corrosion behavior of 690 MPa high performance weathering bridge steel in a laboratory simulated industrial atmosphere was investigated by means of cyclically alternative immersion-drying accelerated corrosion test, electrochemical test, scanning electron microscopy (SEM), X-ray diffractometer (XRD), electron probe (EPMA) and other surface testing techniques. The results show that the corrosion resistance of Q690qENH steel composed mainly of bainite is better than that of Q235 steel composed of ferrite and pearlite at the early stage of corrosion. At the later stage of corrosion, the corrosion rate of Q690qENH steel decreases gradually and which is much lower than that of Q235 steel. The enrichment of alloying elements Cu, Cr and Ni in the rust layer of Q690qENH steel improves the denseness and stability of the rust layer, which has stronger resistance to corrosive medium, and higher α/γ* ratio of the so-called rust layer protectiveness. The electrochemical test results also show that the rust resistance and linear polarization resistance of Q690qENH steel are larger and the protective effect is stronger. Therefore, the corrosion resistance of Q690qENH steel is obviously better than that of Q235 steel in simulated industrial atmospheric environment.

Key words： 690 MPa bridge steel weathering resistance industrial atmospheric

收稿日期: 2021-06-23

ZTFLH:

TG174

基金资助:国家重点研发计划(2017YFB030480)

通讯作者: 刘静 E-mail: liujing@wust.edu.cn

Corresponding author: LIU Jing E-mail: liujing@wust.edu.cn

作者简介: 程鹏,男,1986年生,硕士,高级工程师

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引用本文:

程鹏, 刘静, 黄峰, 黄先球, 庞涛. 690 MPa级耐候桥梁钢在模拟工业大气环境下的腐蚀行为研究[J]. 中国腐蚀与防护学报, 2022, 42(4): 563-572.
Peng CHENG, Jing LIU, Feng HUANG, Xianqiu HUANG, Tao PANG. Corrosion Behavior of 690 MPa Weathering Bridge Steel in Simulated Industrial Atmosphere. Journal of Chinese Society for Corrosion and protection, 2022, 42(4): 563-572.

链接本文:

https://www.jcscp.org/CN/10.11902/1005.4537.2021.143 或 https://www.jcscp.org/CN/Y2022/V42/I4/563

表1 实验钢的化学成分 (mass fraction / %)

图1 Q690qENH钢和Q235钢的显微组织

图2 实验钢腐蚀失重和腐蚀速率随时间的变化曲线

图3 周浸腐蚀不同时间后的实验钢表面宏观形貌

图4 周浸腐蚀不同时间后的实验钢表面锈层微观形貌

图5 周浸腐蚀不同时间后的实验钢截面锈层微观形貌

图6 Q235钢和Q690qENH钢腐蚀384 h形成的锈层的截面形貌及元素分布图

图7 Q235钢和Q690qENH钢腐蚀不同时间后表面的XRD图谱

表2 不同腐蚀时间后的XRD半定量分析

图8 Q235钢和Q690qENH钢在模拟工业大气环境下表面的SVET图

图9 Q235钢和Q690qENH钢腐蚀不同时间后的电化学阻抗谱图及其等效电路图

表3 经不同时间腐蚀的试样EIS拟合参数

图10 两种钢经不同时间腐蚀后的|Z|0.01 Hz值

图11 Q235钢和Q690qENH钢腐蚀不同时间后的线性极化图和极化电阻值

表4 两种钢腐蚀动力学拟合结果

1	Zheng K F, Zhang Y, Heng J L, et al. High strength weathering steel and its application and prospect in bridge engineering [J]. J. Harbin Inst. Technol., 2020, 52(3): 1
1	郑凯锋, 张宇, 衡俊霖等. 高强度耐候钢及其在桥梁中的应用与前景 [J]. 哈尔滨工业大学学报, 2020, 52(3): 1
2	Tian Z Q, Sun L, Liu J L, et al. Development status of weathering bridge steel at home and abroad [J]. Hebei Metall., 2019, (2): 11
2	田志强, 孙力, 刘建磊等. 国内外耐候桥梁钢的发展现状 [J]. 河北冶金, 2019, (2): 11
3	Wang C S, Zhang J W, Duan L, et al. Research progress and engineering application of long lasting high performance weathering steel bridges [J]. J. Traffic Transp. Eng., 2020, 20(1): 1
3	王春生, 张静雯, 段兰等. 长寿命高性能耐候钢桥研究进展与工程应用 [J]. 交通运输工程学报, 2020, 20(1): 1
4	Zhu J S, Guo X Y, Kang J F, et al. Research on corrosion behavior, mechanical property, and application of weathering steel in bridges [J]. China J. Highw. Transp., 2019, 32(5): 1
4	朱劲松, 郭晓宇, 亢景付等. 耐候桥梁钢腐蚀力学行为研究及其应用进展 [J]. 中国公路学报, 2019, 32(5): 1 doi: 10.19721/j.cnki.1001-7372.2019.05.001
5	Morcillo M, Díaz I, Chico B, et al. Weathering steels: from empirical development to scientific design. A review [J]. Corros. Sci., 2014, 83: 6 doi: 10.1016/j.corsci.2014.03.006
6	Guo M X, Pan C, Wang Z Y, et al. A study on the initial corrosion behavior of carbon steel exposed to a simulated coastal-industrial atmosphere [J]. Acta Metall. Sin., 2018, 54: 65
6	郭明晓, 潘晨, 王振尧等. 碳钢在模拟海洋工业大气环境中初期腐蚀行为研究 [J]. 金属学报, 2018, 54: 65 doi: 10.11900/0412.1961.2017.00142
7	Guo T M, Zhang Y W, Qin J S, et al. Corrosion behavior of Q345q bridge steel in three simulated atmospheres [J]. J. Chin. Soc. Corros. Prot., 2019, 39: 319
7	郭铁明, 张延文, 秦俊山等. 桥梁钢Q345q在3种模拟大气环境中的腐蚀行为研究 [J]. 中国腐蚀与防护学报, 2019, 39: 319
8	Zhang Y, Liu J, Huang F, et al. Comparative study of corrosion resistance of three weathering steels for bridges in simulated marine atmospheric environment [J]. J. Wuhan Univ. Sci. Technol., 2018, 41: 401
8	张宇, 刘静, 黄峰等. 三种桥梁耐候钢在模拟海洋大气环境中的耐蚀性能比较 [J]. 武汉科技大学学报, 2018, 41: 401
9	Liu H X, Huang F, Yuan W, et al. Corrosion behavior of 690 MPa grade high strength Bainite steel in a simulated rural atmosphere [J]. J. Chin. Soc. Corros. Prot., 2020, 40: 416
9	刘海霞, 黄峰, 袁玮等. 690 MPa级高强贝氏体钢在模拟乡村大气中的腐蚀行为 [J]. 中国腐蚀与防护学报, 2020, 40: 416
10	Sun Y W, Zhong Y P, Wang L S, et al. Corrosion behavior of low-alloy high strength steels in a simulated common SO₂-containing atmosphere [J]. J. Chin. Soc. Corros. Prot., 2019, 39: 274
10	孙永伟, 钟玉平, 王灵水等. 低合金高强度钢的耐模拟工业大气腐蚀行为研究 [J]. 中国腐蚀与防护学报, 2019, 39: 274
11	Zhang X, Yang S W, Zhang W H, et al. Influence of outer rust layers on corrosion of carbon steel and weathering steel during wet-dry cycles [J]. Corros. Sci., 2014, 82: 165 doi: 10.1016/j.corsci.2014.01.016
12	Yamashita M, Miyuki H, Matsuda Y, et al. The long term growth of the protective rust layer formed on weathering steel by atmospheric corrosion during a quarter of a century [J]. Corros. Sci., 1994, 36: 283 doi: 10.1016/0010-938X(94)90158-9
13	Huang T, Chen X P, Wang X D, et al. A study on the rust characteristics and corrosion resistance of high strength weathering steels in NaCl solution [J]. J. Mech. Eng., 2017, 53(20): 45
13	黄涛, 陈小平, 王向东等. 高强耐候钢在NaCl溶液中的腐蚀锈层特征和耐腐蚀性研究 [J]. 机械工程学报, 2017, 53(20): 45
14	Nishimura T, Kodama T. Clarification of chemical state for alloying elements in iron rust using a binary-phase potential-pH diagram and physical analyses [J]. Corros. Sci., 2003, 45: 1073 doi: 10.1016/S0010-938X(02)00186-5
15	Long H, Zhang S X, Dong J H, et al. A study of the evolution of rust on Mo-Cu-bearing fire-resistant steel submitted to simulated atmospheric corrosion [J]. Corros. Sci., 2012, 54: 244 doi: 10.1016/j.corsci.2011.09.023
16	De La Fuente D, Alcántara J, Chico B, et al. Characterisation of rust surfaces formed on mild steel exposed to marine atmospheres using XRD and SEM/Micro-Raman techniques [J]. Corros. Sci., 2016, 110: 253 doi: 10.1016/j.corsci.2016.04.034
17	Kamimura T, Hara S, Miyuki H, et al. Composition and protective ability of rust layer formed on weathering steel exposed to various environments [J]. Corros. Sci., 2006, 48: 2799 doi: 10.1016/j.corsci.2005.10.004
18	Tanaka H, Mishima R, Hatanaka N, et al. Formation of magnetite rust particles by reacting iron powder with artificial α-, β- and γ-FeOOH in aqueous media [J]. Corros. Sci., 2014, 78: 384 doi: 10.1016/j.corsci.2013.08.023
19	Li Z Y, Wang G, Luo S W, et al. Early corrosion behavior of EH36 ship plate steel in tropical marine atmosphere [J]. J. Chin. Soc. Corros. Prot., 2020, 40: 463
19	李子运, 王贵, 罗思维等. 热带海洋大气环境中EH36船板钢早期腐蚀行为研究 [J]. 中国腐蚀与防护学报, 2020, 40: 463
20	Luo H, Dong C F, Li X G, et al. The electrochemical behaviour of 2205 duplex stainless steel in alkaline solutions with different pH in the presence of chloride [J]. Electrochim. Acta, 2012, 64: 211 doi: 10.1016/j.electacta.2012.01.025
21	Gui J, Devine T M. The influence of sulfate ions on the surface enhanced Raman spectra of passive films formed on iron [J]. Corros. Sci., 1994, 36: 441 doi: 10.1016/0010-938X(94)90036-1
22	Cao X K, Huang F, Huang C, et al. Preparation of graphene nanoplate added zinc-rich epoxy coatings for enhanced sacrificial anode-based corrosion protection [J]. Corros. Sci., 2019, 159: 108120 doi: 10.1016/j.corsci.2019.108120
23	Nishikata A, Zhu Q J, Tada E. Long-term monitoring of atmospheric corrosion at weathering steel bridges by an electrochemical impedance method [J]. Corros. Sci., 2014, 87: 80 doi: 10.1016/j.corsci.2014.06.007
24	Xiao K, Dong C F, Li X G, et al. Atmospheric corrosion behavior of weathering steels in initial stage [J]. J. Iron Steel Res., 2008, 20(10): 53
24	肖葵, 董超芳, 李晓刚等. 大气腐蚀下耐候钢的初期行为规律 [J]. 钢铁研究学报, 2008, 20(10): 53
25	Ke W, Dong J H. Study on the rusting evolution and the performance of resisting to atmospheric corrosion for Mn-Cu steel [J]. Acta Metal. Sin., 2010, 46: 1365
25	柯伟, 董俊华. Mn-Cu钢大气腐蚀锈层演化规律及其耐候性的研究 [J]. 金属学报, 2010, 46: 1365 doi: 10.3724/SP.J.1037.2010.00489
26	Zou Y, Wang J, Zheng Y Y. Electrochemical techniques for determining corrosion rate of rusted steel in seawater [J]. Corros. Sci., 2011, 53: 208 doi: 10.1016/j.corsci.2010.09.011
27	Luo R, Wu J, Liu X L, et al. Evolution of rust layers formed on Q235 and 09CuPCrNi-a steels during initial stage of field exposure in two sites of different environment [J]. J. Chin. Soc. Corros. Prot., 2014, 34: 566
27	罗睿, 吴军, 柳鑫龙等. Q235和09CuPCrNi-A钢在两种不同大气环境中腐蚀早期锈层演化研究 [J]. 中国腐蚀与防护学报, 2014, 34: 566
28	Li Q X, Wang Z Y, Han W, et al. Characterization of the rust formed on weathering steel exposed to Qinghai salt lake atmosphere [J]. Corros. Sci., 2008, 50: 365 doi: 10.1016/j.corsci.2007.06.020
29	Wu W, Cheng X Q, Zhao J B, et al. Benefit of the corrosion product film formed on a new weathering steel containing 3% nickel under marine atmosphere in Maldives [J]. Corros. Sci., 2020, 165: 108416 doi: 10.1016/j.corsci.2019.108416
30	Chao Y L, Zhou Y L, Di Q K, et al. Effect of micro-alloying elements on corrosion resistance of low carbon steels [J]. J. Chin. Soc. Corros. Prot., 2014, 34: 70
30	晁月林, 周玉丽, 邸全康等. Cu, P, Cr和Ni对低碳钢耐蚀性的影响 [J]. 中国腐蚀与防护学报, 2014, 34: 70
31	Zhang T Y, Liu W, Fan Y M, et al. Effect of synergistic action of Cu/Ni on corrosion resistance of low alloy steel in a simulated tropical marine atmosphere [J]. J. Chin. Soc. Corros. Prot., 2019, 39: 511
31	张天翼, 柳伟, 范玥铭等. 海洋大气环境Cu/Ni协同作用对低合金钢耐蚀性影响 [J]. 中国腐蚀与防护学报, 2019, 39: 511
32	Nishimura T, Katayama H, Noda K, et al. Effect of Co and Ni on the corrosion behavior of low alloy steels in wet/dry environments [J]. Corros. Sci., 2000, 42: 1611 doi: 10.1016/S0010-938X(00)00018-4

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