Please wait a minute...
中国腐蚀与防护学报  2017, Vol. 37 Issue (3): 207-215    DOI: 10.11902/1005.4537.2016.037
  本期目录 | 过刊浏览 |
电化学测试技术在垢下腐蚀中的应用
陈洁净,鞠虹(),孙灿,李霞,刘雲飞
中国石油大学 (华东) 机电工程学院 青岛 266580
Application of Electrochemical Testing Technology for Corrosion Under-deposits
Jiejing CHEN,Hong JU(),Can SUN,Xia LI,Yunfei LIU
College of Mechanical and Electronic Engineering, China University of Petroleum, Qingdao 266580, China
全文: PDF(809 KB)   HTML
摘要: 

针对垢下腐蚀进行了简要分析,着重介绍了电化学测试技术在垢下腐蚀研究领域中的应用现状,并进一步展望了垢下腐蚀研究中电化学测试技术今后的发展方向。目前,线性极化、电化学阻抗谱 (EIS) 、电化学噪声分析 (EN) 与丝束电极 (WBE) 技术是研究垢下腐蚀行为的最优选择。为了弥补采用单一电化学测试技术的不足,两种及以上电化学测试技术联合运用将会成为垢下腐蚀电化学测试技术的主流方向。

关键词 垢下腐蚀丝束电极电化学噪声电化学技术    
Abstract

Corrosion under-deposits is briefly introduced, and then the application status of electrochemical testing technologies in this field is highlighted. Meanwhile, the future prospect related with the development and application of electrochemical testing technologies is put forward. At present, linear polarization, electrochemical impedance spectroscopy (EIS), electrochemical noise (EN), and the wire beam electrode (WBE) technology are the optimal choice in the study of under-deposit corrosion. To make up for the inadequacy of using a single electrochemical testing technology, the combination of two or more electrochemical testing technologies will become the main stream in this field.

Key wordsunder-deposit corrosion    wire beam electrode (WBE)    electrochemical noise (EN)    electrochemical technique
收稿日期: 2016-03-23     
基金资助:国家自然科学基金 (41206063) 及中央高校基本科研业务费专项资金 (15CX05023A和14CX02201A)

引用本文:

陈洁净,鞠虹,孙灿,李霞,刘雲飞. 电化学测试技术在垢下腐蚀中的应用[J]. 中国腐蚀与防护学报, 2017, 37(3): 207-215.
Jiejing CHEN, Hong JU, Can SUN, Xia LI, Yunfei LIU. Application of Electrochemical Testing Technology for Corrosion Under-deposits. Journal of Chinese Society for Corrosion and protection, 2017, 37(3): 207-215.

链接本文:

https://www.jcscp.org/CN/10.11902/1005.4537.2016.037      或      https://www.jcscp.org/CN/Y2017/V37/I3/207

图1  局部腐蚀闭塞电池 (OCC) 模型[12]
[1] Xu Z M, Qiu Z B, Zhang Z B.Experimental study of CaCO3 fouling characteristics of titanium tubes[J]. J. Eng. Therm. Energy Power, 2008, 23: 523
[1] (徐志明, 邱振波, 张仲彬. 钛管CaCO3污垢特性的实验研究[J]. 热能动力工程, 2008, 23: 523)
[2] Zhang Z B.Study on the fouling characteristic of heat transfer surface [D]. Baoding: North China Electric Power University, 2009
[2] (张仲彬. 换热表面污垢特性的研究 [D]. 保定: 华北电力大学, 2009)
[3] Chen X W, Zhang Z X, Chen E F.Research progresses of the monitoring and prediction of fouling of heat transfer equipment[J]. Chem. Eng. Mach., 2005, 32: 60
[3] (陈晓文, 张早校, 陈二锋. 换热设备污垢监测及预测研究进展[J]. 化工机械, 2005, 32: 60)
[4] Wang Z H, Cao Y M, Wu G.Research on corrosion leakage and scaling of heat exchange tubes in LT-MED seawater desalination evaporator[J]. Metall. Power, 2017, (2): 37
[4] (王志宏, 曹云明, 吴刚. 水电联产低温多效海水淡化换热管腐蚀泄漏与结垢研究[J]. 冶金动力, 2017, (2): 37)
[5] Wang X, Melchers R E.Corrosion of carbon steel in presence of mixed deposits under stagnant seawater conditions[J]. J. Loss Prev. Process Ind., 2017, 45: 29
[6] Sun Q L, Wang Z G, Cai Y X.Material Corrosion and Protection [M]. Beijing: Chemical Industry Press, 2015
[6] (孙齐磊, 王志刚, 蔡元兴. 材料腐蚀与防护 [M]. 北京: 化学工业出版社, 2015)
[7] Melchers R E.Effect on marine immersion corrosion of carbon content of low alloy steels[J]. Corros. Sci., 2003, 45: 2609
[8] Zhang Z T.Development and treatment of water wall leakage caused by under-deposit corrosion[J]. Power Equip., 2013, 27: 343
[8] (张宗棠. 水冷壁垢下腐蚀的泄漏形态演变及处理方案[J]. 发电设备, 2013, 27: 343)
[9] Zhu Y L, Chen H L, Qiu Y B, et al.Effect of sodium laurate on characters of deposits on surface of N80 steel in NaCl solutions[J]. Corrs. Sci. Technol. Prot., 2010, 22: 427
[9] (朱元良, 陈海玲, 邱于兵等. 月桂酸根离子吸附对碳钢表面垢层性质的影响[J]. 腐蚀科学与防护技术, 2010, 22: 427)
[10] Huang X D, Fu L.Study on the corrosive effect of sediment on carbon steel[J]. J. Xinyang Normal Univ.(Nat. Sci. Ed.), 1997, 10(3): 78
[10] (黄雪丹, 付琳. 垢层对碳钢腐蚀影响探究[J]. 信阳师范学院学报 (自然科学版) , 1997, 10(3): 78)
[11] Jiang W B.An electromagnetic anti-scaling system based on the changing electromagnetic field [D]. Hangzhou: China Jiliang University, 2012
[11] (蒋文斌. 基于变化电磁场的电磁除垢系统 [D]. 杭州: 中国计量学院, 2012)
[12] Gan Y, Li Y, Lin H C.Experimental studies on the local corrosion of low alloy steels in 3.5% NaCl[J]. Corros. Sci., 2001, 43: 397
[13] Luo F W, Weng Y J.Comparision of corrosion behavior of X70 steel and 16Mn steel in soil II: Pitting corrosion and crevice attack[J]. Corros. Sci. Prot. Technol., 2005, 17(3): 151
[13] (罗方伟, 翁永基. X70和16Mn钢土壤腐蚀行为比较II: 点蚀和缝隙腐蚀[J]. 腐蚀科学与防护技术, 2005, 17(3): 151)
[14] Tan Y J, Fwu Y, Bhardwaj K.Electrochemical evaluation of under-deposit corrosion and its inhibition using the wire beam electrode method[J]. Corros. Sci., 2011, 53: 1254
[15] Sun B L, Cao J, Si T Z, et al.Electrochemical corrosion behavior of NSB steel with rust layer simulated seawater[J]. J. Anhui Univ. Technol.(Nat. Sci.), 2013, 30: 124
[15] (孙宝龙, 曹荐, 斯庭智等. 带锈层NSB钢在模拟海水中的电化学腐蚀行为[J]. 安徽工业大学学报 (自然科学版), 2013, 30: 124)
[16] Zhu Y L, Qiu Y B, Guo X P.Effect of MoO42- on underscale local corrosion of N80 steel in neutral solution[J]. J. Chem. Ind. Eng.(China), 2008, 59: 1228
[16] (朱元良, 邱于兵, 郭兴蓬. 中性体系中MoO42-对碳钢垢下局部腐蚀的抑制作用[J]. 化工学报, 2008, 59: 1228)
[17] Wang L W, Li X G, Du C W, et al.Recent advances in local electrochemical measurement techniques and applications in corrosion research[J]. J. Chin. Soc. Corros. Prot., 2010, 30(6): 498
[17] (王力伟, 李晓刚, 杜翠薇等. 微区电化学测量技术进展在腐蚀领域的应用[J]. 中国腐蚀与防护学报, 2010, 30(6): 498)
[18] Editorial Board of 'Metal Corrosion Handbook'. Metal Corrosion Handbook[M]. Shanghai: Shanghai Scientific and Technical Publishers, 1987
[18] (《金属腐蚀手册》编辑委员会. 金属腐蚀手册 [M]. 上海: 上海科学技术出版社, 1987)
[19] Zhu Y L, Guo X P.Electrochemical behaviors of rusted N80 steel in NaCl solution[J]. Corros. Prot., 2011, 32: 521
[19] (朱元良, 郭兴蓬. NaCl溶液中N80钢锈垢形成过程的电化学行为[J]. 腐蚀与防护, 2011, 32: 521)
[20] Zhu Y L, Ji E Y, Qiu Y B, et al.Under-deposit occluded cell corrosion inhibition mechanism of N80 steel in NaCl solution added with sodium laurate[J]. Corros. Prot., 2010, 31: 111
[20] (朱元良, 姬鄂豫, 邱于兵等. 用闭塞电池研究月桂酸根离子抑制碳钢垢下腐蚀的机理[J]. 腐蚀与防护, 2010, 31: 111)
[21] Huo D X, Liang J L, Li H, et al.Research progress of application of electrochemical corrosion technology[J]. Hot Work. Technol., 2017, 46(10): 18
[21] (霍东兴, 梁精龙, 李慧等. 腐蚀电化学技术应用研究进展[J]. 热加工工艺,, 2017, 46(10): 18)
[22] Tan Y J, Bailey S, Kinsella B.An investigation of the formation and destruction of corrosion inhibitor films using electrochemical impedance spectroscopy (EIS)[J]. Corros. Sci., 1996, 38: 1545
[23] Park J R, Macdonald D D.Impedance studies of the growth of porous magnetite films on carbon steel in high temperature aqueous systems[J]. Corros. Sci., 1983, 23: 295
[24] Wu S L, Cui Z D, Zhao G X, et al.EIS study of the surface film on the surface of carbon steel from supercritical carbon dioxide corrosion[J]. Appl. Surf. Sci., 2004, 228: 17
[25] Xin S S, Li M C.Electrochemical corrosion characteristics of type 316L stainless steel in hot concentrated seawater[J]. Corros. Sci., 2014, 81: 96
[26] Ding J H, Lu M X, Yang P, et al.Corrosion behavior of 316L stainless steel under high H2S-Cl- environment[J]. Corros. Prot., 2012, 33(suppl.2): 96
[26] (丁金慧, 路民旭, 杨萍等. 316L奥氏体不锈钢在高浓度H2S-Cl-环境中的腐蚀行为[J]. 腐蚀与防护, 2012, 33(增刊2): 96)
[27] Dong C F, Luo H, Xiao H, et al.Evaluation of corrosion behaviour of 316L stainless steel exposed in marine atmosphere of Xisha lslands[J]. J. Sichuan Univ.(Eng. Sci. Ed.) , 2012, 44(3): 179
[27] (董超芳, 骆鸿, 肖葵等. 316L不锈钢在西沙海洋大气环境下的腐蚀行为评估[J]. 四川大学学报 (工程科学版), 2012, 44(3): 179)
[28] Qin L Y, Song S Z, Lu Y Z.EIS characteristics of 304 stainless steel during intergranular corrosion[J]. J. Chin. Soc. Corros. Prot., 2007, 27: 74
[28] (秦丽雁, 宋诗哲, 卢玉琢. 304不锈钢晶间腐蚀过程中的电化学阻抗谱特征[J]. 中国腐蚀与防护学报, 2007, 27: 74)
[29] Bousselmi L, Fiaud C, Tribollet B, et al.Impedance spectroscopic study of a steel electrode in condition of scaling and corrosion interphase model[J]. Electrochim. Acta, 1999, 44: 4357
[30] Bousselmi L, Fiaud C, Tribollet B, et al.The characterisation of the coated layer at the interface carbon steel-natural salt water by impedance spectroscopy[J]. Corros. Sci., 1997, 39: 1711
[31] Zhang G A, Yu N, Yang L Y, et al.Galvanic corrosion behavior of deposit-covered and uncovered carbon steel[J]. Corros. Sci., 2014,86: 202
[32] Zhu Y L, Zhao Y N.Study on the influential factors of underscale local corrosion fo N80 steel[J]. J. Nanyang Inst. Technol., 2009, 1(6): 46
[32] (朱元良, 赵艳娜. N80钢沉积物下闭塞电池腐蚀影响因素研究[J]. 南阳理工学院学报, 2009, 1(6): 46)
[33] Xu C C, Wu X M, Liu Y P.Investigation on inhibiting mechanism of SDS for localized corrosion fo stainless steel by stimulated occluded cell[J]. J. Chin. Soc. Corros. Prot., 2002, 22(3): 129
[33] (许淳淳, 吴小梅, 刘幼平. 用模拟闭塞电池方法研究十二烷基硫酸根对不锈钢局部腐蚀的影响[J]. 中国腐蚀与防护学报, 2002, 22(3): 129)
[34] Xu C C, Liu Y P, Jin Z Q, et al.A study of inhibition effect and its mechanism of NO32- on 0Cr18Ni9Ti steel occluded cell in 0.5M NaCl solution[J]. J. Chin. Soc. Corros. Prot., 1991, 11: 225
[34] (许淳淳, 刘幼平, 金志强等. NO32-对0Cr18Ni9Ti钢在NaCl溶液中闭塞区腐蚀的抑制作用及其机理[J]. 中国腐蚀与防护学报, 1991, 11: 225)
[35] Liu Y P, Zhou P J, Zhang J, et al.Effect of external potential on corrosion behaviour within propagating pits or cracks[J]. J. Chin. Soc. Corros. Prot., 1995, 15: 43
[35] (刘幼平, 周培君, 张洁等. 外部电位对蚀孔或裂缝扩展阶段闭塞区腐蚀行为的影响[J]. 中国腐蚀与防护学报, 1995, 15: 43)
[36] Zhu Y L, Guo X P.The study on the underscales localized corrosion behavior of carbon steel in neutral solution[J]. J. Chin. Soc. Corros. Prot., 2008, 28: 271
[36] (朱元良, 郭兴蓬. 中性介质中碳钢腐蚀沉积膜下局部腐蚀行为[J]. 中国腐蚀与防护学报, 2008, 28: 271)
[37] Tan Y J.Wire beam electrode: A new tool for studying localised corrosion and other heterogeneous electrochemical processes[J]. Corros. Sci., 1998, 41: 229
[38] Zhang P H, Wang Y H, Peng X, et al.Study of corrosion behavior of copper beneath a droplet by means of wire beam electrode technology[J]. J. Chin. Soc. Corros. Prot., 2014, 34: 459
[38] (张彭辉, 王燕华, 彭欣等. 采用丝束电极技术研究液滴下Cu腐蚀行为[J]. 中国腐蚀与防护学报, 2014, 34: 459)
[39] Liu Z J, Wang W, Wang J, et al.Study of corrosion behavior of carbon steel under seawater film using the wire beam electrode method[J]. Corros. Sci., 2014, 80: 523
[40] Weng Y J, Zhao H Y.Evaluation of pitting sensitivity of stainless steel in NaCl soultions by means of wire beam electrodes (WBE)[J]. J. Chin. Soc. Corros. Prot., 2003, 23: 326
[40] (翁永基, 赵海燕. 用丝束电极 (WBE) 评价不锈钢在NaCl溶液中点蚀敏感性[J]. 中国腐蚀与防护学报, 2003, 23: 326)
[41] Niu X B.Study corrosion of metal/coating by the mean of wine beam electrode [A]. 2012 Academic Essays of Electrical Engineering Institute of Shandong[C]. Ji'nan: Shandong Association for Science And Technology, 2012: 145
[41] (钮晓博. 采用丝束电极研究金属/涂层的腐蚀 [A]. 山东电机工程学会2012年度学术年会论文集[C]. 济南: 山东省科学技术协会, 2012: 145)
[42] Gao Q Y, Zhang J J, Yang Z G, et al.Effects of sediments on the corrosion behavior of 20# carbon steel pipe[J]. Sci. Technol. Rev., 2014, 32(24): 35
[42] (高秋英, 张江江, 杨祖国等. 20#碳钢管道内沉积物对腐蚀行为的影响[J]. 科技导报, 2014, 32(24): 35)
[43] Yu X, Yu J L, Chen C F.Corrosion research of carbon steel in naphthenic acid at high temperature on electrochemical noise[J]. Appl. Chem. Ind., 2017, 46: 227
[43] (于湘, 余俊良, 陈长风. 电化学噪声研究碳钢在高温环烷酸中的腐蚀行为[J]. 应用化工, 2017, 46: 227)
[44] Hu H L, Li N, Cheng J N.A review on progress of application of electrochemical noise in corrosion study[J]. Corros. Sci. Prot. Technol., 2007, 27: 114
[44] (胡会利, 李宁, 程瑾宁. 电化学噪声在腐蚀领域中的研究进展[J]. 腐蚀科学与防护技术, 2007, 27: 114)
[45] Dong Z H, Guo X P, Zheng J S.Review on electrochemical noise analysis methods[J]. Mater. Prot., 2001, 34(7): 20
[45] (董泽华, 郭兴蓬, 郑家燊. 电化学噪声的分析方法[J]. 材料保护, 2001, 34(7): 20)
[46] Iverson W P.Transient voltage changes produced in corroding metals and alloys[J]. J. Electrochem. Soc., 1968, 115: 617
[47] Jia Z J, Du C W, Li X G.Detection of pitting corrosion of 316L stainless steel in FeCl3 solution by electrochemical noise[J]. Corros. Prot., 2011, 32: 497
[47] (贾志军, 杜翠薇, 李晓刚. 316L不锈钢在FeC13溶液中点蚀行为的电化学噪声检测[J]. 腐蚀与防护, 2011, 32: 497)
[48] Padilla-Viveros A, Garcia-Ochoa E, Alazard D.Comparative electrochemical noise study of the corrosion process of carbon steel by the sulfate-reducing bacterium Desulfovibrio alaskensis under nutritionally rich and oligotrophic culture conditions[J]. Electrochim. Acta, 2006, 51: 3841
[49] Ungaro M L, Carranza R M, Rodriguez M A.Crevice corrosion study on alloy 22 by electrochemical noise technique[J]. Procedia Mater. Sci., 2012, 1: 222
[50] Mojica J, Garc??a E, Rodr??guez F J, et al. Evaluation of the protection against corrosion of a thick polyurethane film by electrochemical noise[J]. Prog. Org. Coat., 2001, 42: 218
[51] Cai C, Wu C S, Li J M, et al.Electrochemical noise of AZ3L magnesium alloy in NaCl solution[J]. Corros. Sci. Prot. Technol., 2009, 21: 104
[51] (蔡超, 吴昌胜, 李建梅等. AZ31镁合金在中性NaCl溶液中的电化学噪声研究[J]. 腐蚀科学与防护技术, 2009, 21: 104)
[52] Skerry B S, Eden D A.Characterisation of coatings performance using electrochemical noise analysis[J]. Prog. Org. Coat., 1991, 19: 379
[53] Yan M C, Weng Y J.High pH environment under debonded coating on cathodic protected pipelines[J]. J. Chin. Soc. Corros. Prot., 2004, 24: 95
[53] (闫茂成, 翁永基. 阴极保护管线破损涂层下高pH环境形成规律[J]. 中国腐蚀与防护学报, 2004, 24: 95)
[54] Kuang Y F, Xu Y.Correlation of corrosion protection of porous membrane on metal surface with electrolytes in solution[J]. J. Chin. Soc. Corros. Prot., 2000, 20(2): 54
[54] (旷亚非, 许岩. 金属表面多孔膜的保护作用与介质组分的关系[J]. 中国腐蚀与防护学报, 2000, 20(2): 54)
[55] Kong D Y.Study on the degradation of organic coatings and substrate metal corrosion by combined WEB and EIS techniques [D]. Qingdao: Ocean University of China, 2011
[55] (孔德艳. 联合丝束电极技术和电化学阻抗技术研究有机涂层劣化过程 [D]. 青岛: 中国海洋大学, 2011)
[56] Dong Z H, Guo X P, Zheng J S, et al.Electrochemistry characteristic of carbon steel under biofilm and sulfide film[J]. Electrochemistry, 2001, 7: 173
[56] (董泽华, 郭兴蓬, 郑家燊等. 碳钢在生物膜和硫化物膜下的电化学腐蚀行为[J]. 电化学, 2001, 7: 173)
[57] Dong Z H, Guo X P, Zheng J S, et al.Electrochemical noise characteristics of metastable piting of 16Mn mild steel[J]. Corros. Sci. Prot. Technol., 2001, 13: 195
[57] (董泽华, 郭兴蓬, 郑家燊等. 用电化学噪声研究16Mn钢的亚稳态孔蚀特征[J]. 腐蚀科学与防护技术, 2001, 13: 195)
[58] Liu J H, Shao Y W, Meng G Z, et al.Analysis of corrosion process of thin organic coatings using EIS and EN Methods[J]. Paint Coat. Ind., 2008, 38(6): 62
[58] (刘继慧, 邵亚薇, 孟国哲等. 利用电化学阻抗谱和电化学噪声分析薄有机涂层的腐蚀过程[J]. 涂料工业, 2008, 38(6): 62)
[59] Cao J, Shao Y W, Zhang T, et al.Roles of zinc phosphate on the corrosion of the scratched epoxy coating[J]. J. Chin. Soc. Corros. Prot., 2009, 29: 437
[59] (曹佳, 邵亚薇, 张涛等. 磷酸锌对环氧涂层破损处金属的缓蚀作用[J]. 中国腐蚀与防护学报, 2009, 29: 437)
[60] Tian Z Q, Kong X D, Wang C B, et al.Electrochemical analysis outer rust layer effect on corrosion behavior of low carbon steel[J]. Corros. Sci. Prot. Technol., 2012, 24: 411
[60] (田志强, 孔小东, 王崇碧等. 外锈层对低碳钢腐蚀影响的电化学分析[J]. 腐蚀科学与防护技术, 2012, 24: 411)
[61] Fan G Y, Zeng W M, Ma Y L.Study and application of an on-line corrosion monitoring system of circulating cooling water[J]. Chem. Equip. Technol., 2006, 27(4): 49
[61] (范国义, 曾为民, 马玉录. 循环冷却水腐蚀在线监测系统的研究与应用[J]. 化工装备技术, 2006, 27(4): 49)
[1] 张震, 吴欣强, 谭季波. 电化学噪声原位监测应力腐蚀开裂的研究现状与进展[J]. 中国腐蚀与防护学报, 2020, 40(3): 223-229.
[2] 陈云翔, 冯丽娟, 蔡建宾, 王璇, 洪毅成, 林德源, 庄建煌, 杨怀玉. 新型复配阻锈剂在混凝土模拟液和试块中对钢筋锈蚀的抑制[J]. 中国腐蚀与防护学报, 2018, 38(4): 343-350.
[3] 安朋亮, 梁平, 任建民, 史艳华, 刘峰, 陈思瑶. 高氮奥氏体不锈钢点蚀行为的电化学噪声特征[J]. 中国腐蚀与防护学报, 2018, 38(1): 26-32.
[4] 程庆利,陶彬,刘栓,刘全桢,张卫华,田松柏,王立平. 原油沉积水对Q235B碳钢的腐蚀影响[J]. 中国腐蚀与防护学报, 2017, 37(2): 126-134.
[5] 刘雨薇, 王振尧, 王军, 胡波涛. 输电塔杆用热浸镀锌钢在模拟酸雨大气环境中的腐蚀行为[J]. 中国腐蚀与防护学报, 2014, 34(5): 426-432.
[6] 张彭辉, 王燕华, 彭欣, 刘在健, 周媛媛, 王佳. 采用丝束电极技术研究液滴下Cu腐蚀行为[J]. 中国腐蚀与防护学报, 2014, 34(5): 459-464.
[7] 刘士强, 王立达, 宗秋凤, 张成, 刘贵昌. 纯Al表面局部孔蚀的电化学噪声特征分析[J]. 中国腐蚀与防护学报, 2014, 34(2): 160-164.
[8] 石维, 董泽华, 郭兴蓬. 基于Hilbert-Huang变换的电化学噪声解析及其应用[J]. 中国腐蚀与防护学报, 2014, 34(2): 138-146.
[9] 张涛, 杨延格, 邵亚薇, 孟国哲, 王福会. 电化学噪声分析方法的研究进展[J]. 中国腐蚀与防护学报, 2014, 34(1): 1-18.
[10] 袁玮, 黄峰, 胡骞, 刘静, 侯震宇. 外加拉应力对X80管线钢点蚀电化学行为的影响[J]. 中国腐蚀与防护学报, 2013, 33(4): 277-282.
[11] 常安乐,宋诗哲. 模拟海洋环境浪花飞溅区的金属构筑物腐蚀监检测[J]. 中国腐蚀与防护学报, 2012, 32(3): 247-250.
[12] 李季,赵林,李博文,郑丽群,韩恩厚. 304不锈钢点蚀的电化学噪声特征[J]. 中国腐蚀与防护学报, 2012, 32(3): 235-240.
[13] 刘圆圆,王伟,王燕华,王佳. NaCl液滴下304不锈钢表面电化学性质研究[J]. 中国腐蚀与防护学报, 2012, 32(1): 28-33.
[14] 石秋梅,邵亚薇,张涛,孟国哲,陈琪昊. 磷酸锌对环氧涂层划痕的保护尺寸研究[J]. 中国腐蚀与防护学报, 2011, 31(5): 389-394.
[15] 徐效陵,黄宝华,刘军,刘春英,潘湛昌,张焜. 盐酸溶液中吡咯烷酮离子液体对碳钢的缓蚀性能[J]. 中国腐蚀与防护学报, 2011, 31(5): 336-340.