咪唑啉衍生物与硫脲对X65钢在惰性沉积物垢下腐蚀的缓蚀机理研究
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盖明月, 张静, 王崇坤, 李秀美
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Corrosion Inhibition Performance of Imidazoline Derivatives and Thiourea on X65 Steel Under Inert Deposits Scale in an Artificial CO2 Saturated Oilfield Produced Water
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GAI Mingyue, ZHANG Jing, WANG Chongkun, LI Xiumei
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表4 SiO2沉积物覆盖下的电极在空白溶液及缓蚀溶液中浸泡不同时间的EIS谱拟合结果
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Table 4 Fitting results of EIS of X65 electrode covered with SiO2 after immersion for different time in blank solution and various corrosion inhibition solutions
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| Inhibitor | t / h | Rs / Ω·cm2 | Cdl / μF·cm-2 | ndl | Rct / Ω·cm2 | L / H·cm-2 |
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| Blank | 12 | 92.69 | 135 | 0.67 | 1584 | 706 | | 24 | 47.21 | 251 | 0.66 | 1339 | 600 | | 36 | 41.22 | 250 | 0.71 | 1661 | - | | 48 | 34.68 | 245 | 0.73 | 2227 | - | | 60 | 32.04 | 237 | 0.74 | 2415 | - | | 72 | 23.69 | 238 | 0.77 | 4420 | - | | IM | 12 | 18.34 | 284 | 0.68 | 1055 | 716 | | 24 | 18.47 | 276 | 0.69 | 1092 | 551 | | 36 | 11.68 | 289 | 0.71 | 1678 | - | | 48 | 21.32 | 305 | 0.69 | 2544 | - | | 60 | 11.15 | 279 | 0.73 | 2920 | - | | 72 | 27.14 | 280 | 0.76 | 2940 | - | | TU | 12 | 27.83 | 256 | 0.76 | 8554 | 501 | | 24 | 21.57 | 166 | 0.85 | 6972 | - | | 36 | 21.60 | 161 | 0.87 | 10830 | - | | 48 | 20.48 | 157 | 0.87 | 17212 | - | | 60 | 19.46 | 63 | 0.88 | 21170 | - | | 72 | 19.18 | 59 | 0.89 | 37745 | - | | TU/IM | 12 | 62.23 | 173 | 0.83 | 1629 | - | | 24 | 57.86 | 182 | 0.85 | 11888 | - | | 36 | 47.48 | 167 | 0.86 | 24370 | - | | 48 | 39.72 | 146 | 0.87 | 65057 | - | | 60 | 36.81 | 143 | 0.87 | 88136 | - | | 72 | 32.27 | 130 | 0.88 | 100720 | - |
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