中性水系锌离子电池负极缓蚀剂研究进展
吴浩天, 张天遂, 李广芳, 刘宏芳

Corrosion Inhibitor for Zn Anode of Neutral Aqueous Zinc Ion Batteries
WU Haotian, ZHANG Tiansui, LI Guangfang, LIU Hongfang
表1 缓蚀剂种类及其作用机理
Table 1 Mechanism of different types of corrosion inhibitor
MechanismSubstanceWay of working
Solvation structure

High concentration electrolytes, alcohol, carbohydrate, organic solvents,

complexing agent

Change the solvation structure by replacing water in original solvation structure or form hydrogen bonds

with H2O

Self-healing electrostatic

shield

Metal ion, quaternary ammonium salt

Cations adsorb at electrode surface, preventing

Zn2+ from depositing at the tip to inhibiting

dendrite growth

Adsorption

Polymers, aldehydes, carbohydrate,

surfactant

Optimize the electric field of electrode surface and

adjust the electrical double layer

Artificial solid electrolyte interphaseMetal ion and oxide, phosphorous salts, polymer monomersGeneral a in situ protective layer to prevent the direct contact between electrode and electrolyte